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Green flexible organic photovoltaics for energy-autonomous electronics

Lead Research Organisation: Imperial College London
Department Name: Chemistry

Abstract

The Internet of Things (IoT) revolution and UK's strategy to reach net zero carbon emissions by 2050 requires establishing efficient energy scavenging technologies that can be utilised to power small electronic devices for sensing, processing and communicating data. The development of such technologies is essential for supporting modern societal needs in ubiquitous computing and AI. At the same time however, it becomes of vital importance that such technologies are built with environmentally friendly (green) approaches, taking into account the entire life cycle of the product - from raw materials and manufacturing to end-of-life. It is thus important to minimise as much as possible the use of toxic materials and chemicals, as well as develop procedures without the need to utilise equipment that consume huge amounts of energy. A key example is the Si photovoltaics industry that employs toxic chemicals in their production that are not easy to be recycled. It has been estimated that by 2050, over 60 million tons of waste will be generated from silicon solar panels alone.

The aim of this fellowship is to develop novel self-powered electronic technologies, without the need to be operated by batteries; all developed with green materials and low-energy manufacturing techniques. Along these lines, I will use organic semiconductors (OSCs) that allow developing high-performance photovoltaic cells without resourcing to toxic materials. When compared to alternative conventional materials used in PVs my approach will allow for easy processing, low-cost manufacturing and attaining high performance. This will entail appropriate device engineering and material's processing strategies for prototyping high performing OPVs on rigid and flexible substrates. In parallel, I will develop low power consuming electronic components such as, sensors and supercapacitors, from green solvents and materials, in order to couple them with OPVs. Operation of such electronics will be mainly attained via light illumination, for outdoor and indoor conditions that will be exploited in a variety of practical applications. The overarching vision of this fellowship is to establish a new pathway in the IoT industry, enabling the use of such technologies in hard-to-reach areas, wearables and disposable biosensing platforms.

Publications

10 25 50

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Aniés F (2023) In Situ Generation of n-Type Dopants by Thermal Decarboxylation in Advanced Functional Materials

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Panca A (2023) Flexible Oxide Thin Film Transistors, Memristors, and Their Integration in Advanced Functional Materials

 
Description This award has enabled me to work with a multidisciplinary team at Imperial College London to develop procedures that we can use very simple techniques to manufacture sustainable organic solar cells.
It helped me establish independence, receive invites to attend the most prestigious international conferences, and continue my career in academia.

I developed solution-processed organic photovoltaics from easy-to-manufacture routes with long-term stability. I also developed methods to enhance the functionalities of thin film detector technologies.
Exploitation Route This award has enabled me to be awarded a UKRI- Impact Acceleration Grant from Imperial College London, where this will support my EPSRC grant as I have a PDRA in my team.
In addition I have received an RSC Sustainable Labs grant, to transform lab practices in clean room and fab labs.

The outcomes of my publication on greener manufacturing of solar cells has received significant attention through the international community and opened the door to new collaborations.
Sectors Chemicals

Electronics

Energy

Environment

Manufacturing

including Industrial Biotechology

URL https://advanced.onlinelibrary.wiley.com/doi/full/10.1002/aenm.202405635
 
Description This award has sparked industrial attention, as I am now collaborating with 5 more companies where they are helping me to transfer my lab practises in their establishments.
First Year Of Impact 2023
Sector Chemicals,Electronics,Energy,Environment,Manufacturing, including Industrial Biotechology
Impact Types Societal

Economic

 
Description Doctor Blade Active Layer 
Organisation Queen Mary University of London
Country United Kingdom 
Sector Academic/University 
PI Contribution I provided new materials, solvents and methods for high performing solar cells.
Collaborator Contribution My collaborators helped me to translate my thin film development methods to techniques that are more suitable for large area thin film development.
Impact The outcomes of this collaboration are summarised in my recently submitted works.
Start Year 2022
 
Description Operando thin film characterisation 
Organisation Chinese University of Hong Kong
Country Hong Kong 
Sector Academic/University 
PI Contribution This collaboration helped me gain information about the morphology of the thin films I ve prepared from renewable solvents for the sustainable development of organic solar cells. This scientific outcomes have been submitted in a high impact factor journal and they are currently under review
Collaborator Contribution My collaborator helped understand the crystallinity of the thin films through a combination of morphological characterisation with GIWAXS and GISAXS techniques.
Impact The scientific contributions of this collaborations are presented in my recently submitted work entitled 'Biorenewable Solvents For High Performing Organic Solar Cells'
Start Year 2022
 
Description Optoelectronic Characterisation of Thin Films 
Organisation Imperial College London
Country United Kingdom 
Sector Academic/University 
PI Contribution Provided thin films developed by biorenewable solvents.
Collaborator Contribution My collaborators characterise the optoelectronic properties of the thin films, and helped me to gain better understanding on the organic solar cells that I ve developed.
Impact The outcomes of this collaboration are presented in my recently submitted work entitled 'Biorenewable Solvents For High Performing Organic Solar Cells'
Start Year 2022
 
Description Optoelectronic Characterisation of Thin Films 
Organisation Imperial College London
Country United Kingdom 
Sector Academic/University 
PI Contribution Provided thin films developed by biorenewable solvents.
Collaborator Contribution My collaborators characterise the optoelectronic properties of the thin films, and helped me to gain better understanding on the organic solar cells that I ve developed.
Impact The outcomes of this collaboration are presented in my recently submitted work entitled 'Biorenewable Solvents For High Performing Organic Solar Cells'
Start Year 2022
 
Description Thin film characterisation 
Organisation University of Sheffield
Country United Kingdom 
Sector Academic/University 
PI Contribution In this collaboration, I provide the material expertise and fabrication methods for the development of uniformly coated active layers.
Collaborator Contribution My collaborator has access to a unique capability in Diamond, where they perform GIWAXS measurements while they deposit the thin film with doctor blade. This will provide a fundamental understanding of the drying kinetics to allow us to tune the morphological properties for high performing sustainable solar cells.
Impact This is a very recent collaboration. We met at a conference in October 2023 and we are still in the planning face of the experimental work. As thus no outputs have been received yet. It is a multi disciplinary collaboration as it combines the experts on spectroscopy, materials processing, and electronic devices.
Start Year 2024
 
Description Thin film characterisation 
Organisation University of Sheffield
Country United Kingdom 
Sector Academic/University 
PI Contribution In this collaboration, I provide the material expertise and fabrication methods for the development of uniformly coated active layers.
Collaborator Contribution My collaborator has access to a unique capability in Diamond, where they perform GIWAXS measurements while they deposit the thin film with doctor blade. This will provide a fundamental understanding of the drying kinetics to allow us to tune the morphological properties for high performing sustainable solar cells.
Impact This is a very recent collaboration. We met at a conference in October 2023 and we are still in the planning face of the experimental work. As thus no outputs have been received yet. It is a multi disciplinary collaboration as it combines the experts on spectroscopy, materials processing, and electronic devices.
Start Year 2024
 
Description Great Exhbition Festival 2023 
Form Of Engagement Activity Participation in an activity, workshop or similar
Part Of Official Scheme? No
Geographic Reach Regional
Primary Audience Public/other audiences
Results and Impact I was the team leader for the CPE stand at the Great Exhibition Road Festival organised by Imperial College London showcasing how we can print electronics in 2023 and new technologies that we are developing in 2024 festival.
Year(s) Of Engagement Activity 2023,2024
URL https://www.imperial.ac.uk/processable-electronics/about-us/outreach-activities/
 
Description School visit (Marylebone School in London) as part of International Women's Day 
Form Of Engagement Activity Participation in an activity, workshop or similar
Part Of Official Scheme? No
Geographic Reach Local
Primary Audience Schools
Results and Impact I was invited to participate in the International Women's Day event that they organised. I gave a short presentation about my career and through a Q&A panel session I promote STEM to young (year 17-18) students.
Year(s) Of Engagement Activity 2023
 
Description Visited the Greek School of London organised by Native Scientists and RSC 
Form Of Engagement Activity Participation in an activity, workshop or similar
Part Of Official Scheme? No
Geographic Reach Regional
Primary Audience Schools
Results and Impact This activity was part of the Native Scientists act, where they identify native speakers and they are visiting their respective schools. The aim was to demonstrate them our research via activities and demos in groups of 4 students. The students were very engaging with us. My session was to discuss about Climate Change. I got support from Grantham Institute at ICL with some informative leaflets that I gave them and via the support of RSC I purchased solar power games.
Year(s) Of Engagement Activity 2023
URL https://x.com/JuliannaPanidi/status/1730571710934491329?s=20
 
Description Volunteer Participation at the Great Exhibition Road Festival 2022 
Form Of Engagement Activity Participation in an activity, workshop or similar
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Public/other audiences
Results and Impact I was affiliated with the Centre of Processable Electronics and we participated in this Festival that is organised every year from researchers across Imperial College London, Natural History Museum, Science Museum and Victoria and Albert Museum.
We discussed about different types of materials we are using in our research focusing on Energy. As an activity the public was replicating the molecular structure of the materials via origami.
Year(s) Of Engagement Activity 2022
URL https://www.imperial.ac.uk/news/238233/perovskite-origami-gerf/