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A durable and scalable anti-soiling coating for solar modules

Lead Research Organisation: Loughborough University
Department Name: CREST

Abstract

The UK is committed to achieve net zero carbon emissions by 2050. This will require a massive shift in the way electricity is generated, away from burning fossil fuels and towards the use of renewable sources such as wind and solar. The cost of solar modules has reduced dramatically over the past few years and subsidy-free deployment is expanding rapidly, especially at utility scale. It is forecast that more than 40GW will be in use in the UK by 2030. Solar assets are financed by professional managers who are concerned by the ongoing operational costs of maintenance that affect power output and the return on investment. In particular, attention is being drawn to the problem of cover glass soiling that attenuates the light into the module. Soiling can reduce power output by up to 5% in the UK and is a far more serious problem (up to 50%) in arid sunbelt regions such as occur in India and the Middle East. Polymer-based hydrophobic anti-soiling coatings have been shown to work in principle, but their durability is not sufficient to withstand 24/7 exposure to environmental stresses or to abrasion damage caused by regular cleaning. The objective of this research is to develop and test a thin inorganic rare-earth oxide coating for application to solar cover glass. The hydrophobic coating will be low surface energy to reduce the adhesion to soiling. Its application will reduce the frequency of costly cleaning cycles. The coating will be capable of being applied at industrial scale using an Atmospheric Chemical Vapour Deposition process that is compatible with glass manufacturing. Use of the coating will significantly improve the practical power output of solar modules and will have worldwide impact.
 
Description We have discovered the mechanism by which rare earth oxides become hydrophobic. We have also discovered that these oxides hydrolyse and degrade in outdoor tests. We have invented a polymer/glass laminate that is low reflection and hydrophobic for anti-soiling. We have also developed a multilayer AR coating combined with a durable anti-soiling coating A patent application has been filed. We are engaging with glass and solar module manufacturers.
Exploitation Route We are engaging with glass and solar module manufacturers.
Sectors Electronics

Energy

Environment

 
Description A patent has been filed to protect the invention of a polymer/glass laminate. The laminate is low reflection and anti-soiling.
Sector Electronics,Energy,Environment
Impact Types Economic

 
Description Glass coatings 
Organisation Pilkington Glass
Department Pilkington Technology Centre
Country United Kingdom 
Sector Private 
PI Contribution Development of anti-reflection and anti-soiling coatings. Thin film CdSeTE/CdTe devices
Collaborator Contribution Provision of coated glass.
Impact Record efficiency for CdSeTe PV devices. Development of durable AR and AS coatings
Start Year 2019
 
Description NSF Industry/University Co-operative Research Center for Next Generation Photovoltaics 
Organisation Colorado State University
Country United States 
Sector Academic/University 
PI Contribution The consortium is engaged in increasing the efficiency and lowering the cost of thin film CdTe photovoltaics. We are producing thin films, complete devices and characterisation using HRTEM.
Collaborator Contribution The other partners are Colorado State University, University of Texas at Austin, First Solar Inc, 5N Plus, Direct Solar LLC, Ion Edge Corporation, NREL and MBI corporation. ECh partner is engaged in developing materials or devices.
Impact 8 Publications
Start Year 2010
 
Description National Renewable Energy Laboratory 
Organisation U.S. Department of Energy
Department National Renewable Energy Laboratory (NREL)
Country United States 
Sector Public 
PI Contribution National Renewable Energy Laboratory (NREL): NREL is a world leading Research Institution for Renewable Energy. NREL has hosted Nayia Arnou, Sona Ulcina and Luis Infante-Ortego (research students) from CREST for 3 month secondments. The visit by Sona Ulcina led to the development a 17.2% efficient perovskite solar cell using an atmospheric spray process. Several joint publications.
Collaborator Contribution Dr Tim Silverman, a senior scientist at NREL is currently on secondment to CREST for 1 year working on degradation mechanisms in silicon modules.
Impact Publications
Start Year 2014
 
Title 'low reflection coating' 
Description A polymer/glass laminate that is low reflection and hydrophobic anti-soiling for solar modules. 
IP Reference UK patent application 'low reflection coating' 2311474.7, filing date of 26 July 2023. 
Protection Patent / Patent application
Year Protection Granted 2023
Licensed No
Impact Discussions have started with glass and solar module manufacturers.
 
Title COVER SHEET FOR PHOTOVOLTAIC PANEL 
Description A cover sheet (7) for a photovoltaic panel (4), the cover sheet (7) comprising a transparent substrate (8) and a coating (9) on the substrate (8), the coating (9) being such that the cover sheet (8) is more reflective to light of a first range of wavelengths in the infrared spectrum than to a second range of wavelengths in the visible spectrum; in which the coating (9) comprises alternating layers of first (11, 13) and second (12, 14) materials, with the first material (11, 13) having a higher refractive index than the second material (12, 14) and being a transparent conducting oxide such as indium tin oxide (ITO). Methods of manufacture including annealing the first material and/or depositing it at elevated temperatures are also discussed. 
IP Reference US2022077337 
Protection Patent / Patent application
Year Protection Granted 2022
Licensed No
Impact Discussions on licensing progressing
 
Description Visiting Professor Colorado State University 
Form Of Engagement Activity A formal working group, expert panel or dialogue
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Professional Practitioners
Results and Impact Collaboration between Loughborough University and Colorado State University
Year(s) Of Engagement Activity 2020,2021,2022,2023