Anion exchange membrane water electrolysis for low-cost green hydrogen production (AEM-H2)

Lead Research Organisation: Imperial College London
Department Name: Chemistry

Abstract

The UK Hydrogen Strategy has set out an ambitious plan to develop GW-scale low-carbon hydrogen production by 2030, which is a crucial step to support the transition to net zero by 2050. Future development of GW-scale green hydrogen production requires substantial cost reduction of electrolysis technology. Existing proton exchange membrane (PEM) electrolysers have technical drawbacks and are limited by the expensive Nafion membranes and electrocatalysts. Anion exchange membrane water electrolysis is one of the most promising electrolysis technologies. However, fundamental research is required to advance AEM technology, particularly in the development of hydrocarbon membranes and electrocatalysts which can catalyse the performance of the systems.

The overall objective of this project is to develop a high-performance, cost-effective and durable anion exchange membrane (AEM) water electrolysis technology. One key challenge is to fabricate membranes with high hydroxide conductivity, good mechanical stability and resistance to chemical deterioration at high temperatures. The lack of effective hydroxide exchange membranes is one of the major obstacles to the development of anion exchange membrane water electrolyser. We will synthesise new generation of polymer membranes to achieve high ionic conductivity and stability. At the same time, although inexpensive and ubiquitous non-precious metal catalysts can be used in AEM electrolysers, currently the activity of these catalysts could be improved. Hence, new electrocatalysts with high reactivity and durability will also be synthesized and paired with newly developed membranes and ionomer binders to form structured membrane electrode assemblies.

Our ambition is to advance the development of cost-effective hydrogen generation technologies and ultimately will contribute to UK's plan to achieve net zero emissions by 2050.

Publications

10 25 50
 
Description Materials and operating conditions for an alkaline electrolyser have been established. New testing protocols have been developed, and it has been shown that a system can be operated continuously for several hundred hours.
Exploitation Route Results have been used as a basis for funding request from both UKRI and also the European commission (the latter has been successful). The work has lead to a consultancy with another company in this area
Sectors Energy

 
Description HORIZON-JTI-CLEANH2-2023-01-01
Amount € 3,005,851 (EUR)
Organisation European Commission H2020 
Sector Public
Country Belgium
Start 01/2024 
End 12/2027
 
Description Collaboration with Bramble Energy on alkaline membrane electrolyser 
Organisation Bramble Energy Ltd
Country United Kingdom 
Sector Private 
PI Contribution We provided material and discussed results associated with alkaline membrane electrolysers with Bramble energy which is interested in commercialising the technology
Collaborator Contribution Testing of materials
Impact We are exploring avenues for further funding to progress this research through the Hydrogen Hub
Start Year 2023
 
Description Collaboration with RFC Power on development of electrode technology 
Organisation RFC Power
Country United Kingdom 
Sector Private 
PI Contribution Development of electrodes and methodlogies to characterise materials provided by RFC Power
Collaborator Contribution Technical analysis of results
Impact Understanding associated with development of improved battery materials
Start Year 2023