Design, Program, Evolve: Engineering efficient electrochemical devices for a net-zero world
Lead Research Organisation:
University of Manchester
Department Name: Chem Eng and Analytical Science
Abstract
Electro-chemical devices (fuel cells, electrolysers etc) are at the forefront of the drive to a 'net-zero world' with hydrogen as an important energy storage medium and fuel for the application of sustainably derived electricity. Even with the projected development of the energy system towards a largely fossil-fuel free system, CO2 separation will continue to be required for chemical processes. The work proposed builds on the collaboration between the Universities on Manchester, Newcastle and UCL which has flourished over the past five years, to develop more efficient and robust technologies to achieve a carbon negative industrial landscape.
The ability to operate fuel cells at higher temperatures without humidification means that the amount of equipment needed and hence cost is reduced. It also means that potentially cheaper catalysts can be used, and the purity of the fuel does not need to be rigorously controlled, all of which leads to cheaper and more efficient systems. The overlap between fuel cells and electrolysers is very significant as an electrolyser is simply a fuel cell in reverse; as such similar problems are manifest. In addition, an exciting electrochemical process for gas separation (CO2 removal) is under development, again with significant overlap in terms of developmental challenges.
This proposal builds a team of researchers with complimentary skills to tackle the challenges highlighted. The synergies between the very high-level characterisation expertise to examine the processes taking place in the systems, coupled with the electro-chemical developments which are on-going, mean that development and optimisation can take place quickly with understanding being shared to tackle the overlapping nature of the obstacles to implementation of these vital technologies.
The ability to operate fuel cells at higher temperatures without humidification means that the amount of equipment needed and hence cost is reduced. It also means that potentially cheaper catalysts can be used, and the purity of the fuel does not need to be rigorously controlled, all of which leads to cheaper and more efficient systems. The overlap between fuel cells and electrolysers is very significant as an electrolyser is simply a fuel cell in reverse; as such similar problems are manifest. In addition, an exciting electrochemical process for gas separation (CO2 removal) is under development, again with significant overlap in terms of developmental challenges.
This proposal builds a team of researchers with complimentary skills to tackle the challenges highlighted. The synergies between the very high-level characterisation expertise to examine the processes taking place in the systems, coupled with the electro-chemical developments which are on-going, mean that development and optimisation can take place quickly with understanding being shared to tackle the overlapping nature of the obstacles to implementation of these vital technologies.
Publications
Gadipelli S
(2023)
Understanding and Optimizing Capacitance Performance in Reduced Graphene-Oxide Based Supercapacitors.
in Small methods
Gadipelli S
(2023)
Structure-guided Capacitance Relationships in Oxidized Graphene Porous Materials Based Supercapacitors
in ENERGY & ENVIRONMENTAL MATERIALS
Guo Z
(2022)
Insights into the performance and degradation of polybenzimidazole/muscovite composite membranes in high-temperature proton exchange membrane fuel cells
in Journal of Membrane Science
Ji Z
(2022)
Doped graphene/carbon black hybrid catalyst giving enhanced oxygen reduction reaction activity with high resistance to corrosion in proton exchange membrane fuel cells
in Journal of Energy Chemistry
Smith K
(2023)
Nafion Matrix and Ionic Domain Tuning for High-Performance Composite Proton Exchange Membranes
in Advanced Functional Materials
Zhang Z
(2024)
The Influence of Cathode Degradation Products on the Anode Interface in Lithium-Ion Batteries.
in ACS nano
Zucconi A
(2024)
Challenges and opportunities for characterisation of high-temperature polymer electrolyte membrane fuel cells: a review
in Journal of Materials Chemistry A
Description | EPSRC Tomorrow's Engineering Research Challenges: Visions from the UK Community |
Geographic Reach | National |
Policy Influence Type | Contribution to a national consultation/review |
URL | https://www.ukri.org/publications/tomorrows-engineering-research-challenges/ |
Description | Membranes characterisation collaboration - Fabrizia Foglia (UCL) |
Organisation | University College London |
Department | Department of Chemistry |
Country | United Kingdom |
Sector | Academic/University |
PI Contribution | Use of neutron scattering techniques to analyse ion dynamics in fuel cell and electrolyser membranes in- and ex-situ. Benefited from the awarding of numerous neutron beamtime experiments |
Collaborator Contribution | UCL Chem Eng - Fuel cell/electrolyser testing and ex-situ characterisation UCL Chemistry - Neutron scattering |
Impact | None yet - ongoing |
Start Year | 2023 |
Description | Membranes collaboration - Qilei Song (Imperial) |
Organisation | Imperial College London |
Country | United Kingdom |
Sector | Academic/University |
PI Contribution | Collaboration on the testing and characterisation of next-generation fuel cell and electrolyser membranes (PEM and AEM) in full systems. |
Collaborator Contribution | UCL - Membrane testing and analysis Imperial - Membrane manufacture and synthesis |
Impact | None yet - ongoing |
Start Year | 2023 |
Description | 16th International Conference on Materials Chemistry (MC16) |
Form Of Engagement Activity | A talk or presentation |
Part Of Official Scheme? | No |
Geographic Reach | International |
Primary Audience | Professional Practitioners |
Results and Impact | A talk given to an international conference |
Year(s) Of Engagement Activity | 2022 |
Description | Guardian Article |
Form Of Engagement Activity | A press release, press conference or response to a media enquiry/interview |
Part Of Official Scheme? | No |
Geographic Reach | International |
Primary Audience | Public/other audiences |
Results and Impact | Media interview and article |
Year(s) Of Engagement Activity | 2023 |
URL | https://www.theguardian.com/environment/2023/jul/30/radical-ways-to-fix-the-earth-are-they-magic-bul... |
Description | Igniting Earth's Essential Transformation with Chemical Engineering |
Form Of Engagement Activity | A talk or presentation |
Part Of Official Scheme? | No |
Geographic Reach | International |
Primary Audience | Schools |
Results and Impact | I delivered the lecture "Igniting Earth's Essential Transformation with Chemical Engineering" as part of the "Futureproof Your Planet" series organized by University of Manchester marketing team to support recruitment activities in the Department. The event targeted potential home and overseas applicants, with the aim of explaining to students how Chemical Engineers are helping to address some of the most important challenges in the 21st century, such as Energy and Water scarcity. |
Year(s) Of Engagement Activity | 2023 |
Description | International Conference on Carbon Capture Science and Technology 2022 (CCST2022) |
Form Of Engagement Activity | A talk or presentation |
Part Of Official Scheme? | No |
Geographic Reach | International |
Primary Audience | Professional Practitioners |
Results and Impact | Talk delivered to international conference |
Year(s) Of Engagement Activity | 2022 |
Description | International Materials Research Congress 2022 |
Form Of Engagement Activity | A talk or presentation |
Part Of Official Scheme? | No |
Geographic Reach | International |
Primary Audience | Professional Practitioners |
Results and Impact | A keynote talk delivered to an international conference. |
Year(s) Of Engagement Activity | 2022 |
Description | International Seminar on Chemistry (ISOCV) |
Form Of Engagement Activity | A talk or presentation |
Part Of Official Scheme? | No |
Geographic Reach | International |
Primary Audience | Professional Practitioners |
Results and Impact | A keynote talk delivered to an international conference. |
Year(s) Of Engagement Activity | 2022 |
Description | New Scientist article |
Form Of Engagement Activity | A press release, press conference or response to a media enquiry/interview |
Part Of Official Scheme? | No |
Geographic Reach | International |
Primary Audience | Professional Practitioners |
Results and Impact | Interview and article |
Year(s) Of Engagement Activity | 2023 |
URL | https://www.newscientist.com/article/2414758-light-sensitive-molecules-could-make-carbon-capture-mor... |
Description | Outreach activity during the open days at University of Manchester |
Form Of Engagement Activity | Participation in an open day or visit at my research institution |
Part Of Official Scheme? | No |
Geographic Reach | Local |
Primary Audience | Schools |
Results and Impact | Remote H2 car for Chemical Engineering open days. This outreach activity, based on the electrochemical energy system and hydrogen as an energy vector, consists of a remote hydrogen car, with which student candidates can play with it, feeding the car with the hydrogen produced by an electrolyser. This activity was launch as part of the Chemical Engineering open days to show the students how this discipline can address energy challenges of this century. The feedback from this activity was very positive as it was one of the most popular activity along others organised for different disciplines within the University. |
Year(s) Of Engagement Activity | 2023 |
Description | STFC Annual Batteries & Electrochemical Energy Devices Meeting 2022 |
Form Of Engagement Activity | A talk or presentation |
Part Of Official Scheme? | No |
Geographic Reach | International |
Primary Audience | Professional Practitioners |
Results and Impact | ~100 people attended a meeting around the above topic, where a talk was delivered by myself on molten-salt membranes. |
Year(s) Of Engagement Activity | 2022 |
Description | Science News article |
Form Of Engagement Activity | A press release, press conference or response to a media enquiry/interview |
Part Of Official Scheme? | No |
Geographic Reach | International |
Primary Audience | Public/other audiences |
Results and Impact | Media interview and article |
Year(s) Of Engagement Activity | 2023 |
URL | https://www.snexplores.org/article/offshore-wind-farms-clean-electricity-hydrogen-carbon-capture |
Description | UCL Hydrogen Innovation Network & Showcase |
Form Of Engagement Activity | Participation in an activity, workshop or similar |
Part Of Official Scheme? | No |
Geographic Reach | National |
Primary Audience | Professional Practitioners |
Results and Impact | Co-organised and participated in the UCL Hydrogen Innovation Network & Showcase, hosed by UCL's Hydrogen Innovation Network (Co-I), the showcase demonstrated UCL's capabilities as a leading hub for hydrogen activity and innovation in the UK and brought together some of the leading voices on hydrogen research within industry, academia and government. Keynote speech by minister for Energy Efficiency and Green Finance Lord Callanan Keynote speech by shadow Minister for Energy Security and Labour MP for Southampton Test, Dr Alan Whitehead |
Year(s) Of Engagement Activity | 2023 |
URL | https://www.ucl.ac.uk/electrochemical-innovation-lab/news/2023/nov/hydrogen-critical-achieving-net-z... |
Description | World Fuel Cell Conference 2023 |
Form Of Engagement Activity | A talk or presentation |
Part Of Official Scheme? | No |
Geographic Reach | International |
Primary Audience | Postgraduate students |
Results and Impact | Talk: Tuning the membrane electrode assembly for high-performance proton exchange membrane fuel cells Presented at the World Fuel Cell Conference 2023 (Imperial, London) - International audience |
Year(s) Of Engagement Activity | 2023 |
URL | https://www.iahe-fcd.org/wfcc2023 |