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UK director of the Felix partnership

Lead Research Organisation: University of Surrey
Department Name: ATI Physics

Abstract

Accelerators are often used to smash particles together or irradiate targets, and sometimes the purpose of this irradiation is to generate other kinds of radiation such as electromagnetic radiation. The other very important reason to use an accelerator is that any charge radiates when subject to acceleration, such as the centripetal acceleration when it is forced to perform a circular path in what is called a synchrotron, and if the speed of the particle is close to the speed of light the radiation is dominantly in the forwards direction. Particle beams can produce very bright and well collimated "laser-like" synchrotron light beams, and in some ways these beams can be much more attractive than regular lasers. For example, the intensity can be extremely high, since the beam of particles can't be damaged or burnt in the way that lasers made from glasses or crystals can. The light pulse duration is related to the particle beam pulse, and this can be very short. Finally, the wavelength of the light is determined by the particle beam energy and the strength of the acceleration, and since these parameters are widely tunable, so is the colour of the light. There are a dozen or so large accelerator based photon sources in Europe that sceintists can visit for experiment, including the UK synchrotron, the Diamond Light Source at Harwell. Many of these sources use the standard circular ring and the synchrotron light is generated by the centripetal force, but some are linear or have straight sections with what is called a line of magnets that cause the electrons to wiggle or undulate on their way through, and these can greatly enhance the light output. One such facility is the FELIX laboratory at the Radboud University, Nijmegen, the Netherlands, which is dedicated to providing intense, tunable and short pulsed infrared light.

The vision of this project is to provide free and easy access for any UK scientist to the FELIX Laboratory. FELIX is a suite of three Free Electron Lasers; unique, flexible, ultrafast light source for mid-infrared and THz spectroscopy. Mid-IR/THz light is important because the photon energy corresponds to many useful phenomena such as the "fingerprint" vibrations that allow identification of molecules, or some spin-flip or magnetic transitions important for memory devices, to name a few. FELIX's set of light characteristics are impossible to obtain simultaneously using standard UK University lab scale equipment, and a large-scale infrastructure, here a free-electron laser (FEL), is crucial for ground-breaking research at the extremes of what is achievable with modern day technology. FELIX provides a powerful means for investigating and manipulating matter in territory that is otherwise impossible to chart, driving it to otherwise unobtainable excited states with unprecedented temporal precision, revealing new functionalities. It is continuously tuneable in a region of the electromagnetic spectrum uniquely suited for driving specific excitations of not only molecules, clusters and collective modes of biologically important proteins, but also electrons in metals and semiconductors. The equipment sharing and user facility access model maximises the size of the UK community, and the provision of a variety of excellent beamlines maximises its diversity.

In this project we aim to understand better the needs of the UK research community, and help them to gain access to this world-leading facility. At the same time we aim to drive developments at FELIX that will meet the UK Community needs of the future.

Publications

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Douglas-Walker TE (2025) Vibrational and Electronic Spectroscopy of 2-Cyanoindene Cations. in ACS earth & space chemistry

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Hansen K (2025) Roadmap on carbon molecular nanostructures in space in The European Physical Journal D

 
Description The facility supports a wide variety of high-quality scientific endeavours for the UK and others. In the reporting period a very exciting new discovery was made that mechanical rotation in the form of chiral phonons induced by FELIX could be used to induce magnetization. A local group have shown that chiral excitations can be produced by infrared pulses and used them to switch the magnetization direction of a coupled magnetic film, controlled by the handed-ness of the phonons [Nature 628, 540 (2024)]. Till now, there has been no FELIX user community from the UK with ex-pertise in magnetism, but the new techniques are expected to generate new interest. UK groups at institutions like the York, Glasgow, and Durham have strong research programs in spintronics and ultrafast magnetization dynamics. The discovery at FELIX about using chiral phonons to control magnetization could be highly relevant for these efforts, providing an alternative non-optical control mechanism. The UK Centre for Doctoral Training in Spintronics (led by Glasgow, York, and Sheffield) could also have researchers interested in applying FELIX's techniques in next-generation spintronic devices. Very recently, Dr Rostislav Mikhaylovskiy joined Lancaster univer-sity and brings not only excellence in ultrafast magnetism [Nature 630, 335 (2024)] but has also begun to make FELIX applications.
In a similar vein, the FELIX group showed that a special optical trick can be used to per-manently flip the internal electric order of a ferroelectric material using only infrared light [M. Kwaaitaal, et al Nature Photonics 18, 569 (2024)]. Normally, flipping this electric order (which is like a tiny built-in electric memory inside the material) requires applying an external voltage (just as flipping the magnetization mentioned above normally requires a magnetic field). Here it was found that -when the material is in a special state called epsilon-near-zero (ENZ)- this flipping effect can be achieved using only ultrafast laser pulses. This could lead to fast, energy-efficient optical memory. Several UK groups, St Andrews, Queens Belfast and Warwick, have each been exploring optical properties of ENZ materials and potential applications.
The main new driver of the developing UK chemistry user community at FELIX is in la-boratory astrophysics. Three key themes are emerging: (1) Ice and Ice Surface Chemistry - Study-ing the dynamics and spectroscopy of astrophysical ices at the UK's LISA beamline; (2) Infrared Action Spectroscopy of Complex Organic Molecules - Conducted at: (a) the IRIS Infrared Spec-troscopy beamline (focused on molecular structure determination at room temperature); and (b) FELion Cryogenic Ion Trap beamline (high-resolution spectroscopy of cold molecular ions). Infra-red action spectroscopy is essential for detecting very small molecular quantities and weak absorp-tion features, requiring the high-intensity of FELIX. The technique is crucial for interpreting IR spectra from JWST, where astronomical gas clouds produce strong absorption, even for weak transitions, making replication in standard laboratory conditions extremely challenging. This growing UK community aims to understand how polycyclic aromatic hydrocarbons (PAHs), their de-rivatives, and fullerene-based species behave in space. These studies are key for identifying molec-ular species, refining astronomical spectra analysis, and revealing fundamental interstellar process-es such as ionization, protonation, and hydrogenation in the interstellar medium. Recent milestones in this expanding UK-FELIX collaboration include first-time publications from new user groups at the University of Edinburgh and UEA. The study of astrochemical ices at LISA is also thriving, with a new generation of ECRs at Queen Mary University of London (QMUL) now active.
Exploitation Route These impacts are mainly academic, and mainly centre on our understanding of chemistry of molecules in space. Potential economic impacts include new kinds of magnetic memory storage.
Sectors Education

 
Description Researchers at HFML-FELIX and Syngenta (Jealott's Hill International Research Centre, UK) have used FELIX to demonstrate the differentiation of hydroxylated derivatives of two plant protection compounds (azoxystrobin and benzovindiflupyr) contained at low levels in relevant plant matrices. This work has now been published in the journal Environmental Science & Technology. Agrochemicals frequently undergo various chemical and metabolic transformation reactions in the environment that often result in a wide range of derivates that must be comprehensively characterized to understand their toxicity profiles and their persistence and outcome in the environment. The development of plant protection compounds involves the characterization of potential environmental transformation products (and other possible related compounds) in order to understand the toxicity and persistence. However, correctly identifying isomer(s) remains a challenge using currently applied analytical methodologies. In this study, we demonstrated the application of infrared ion spectroscopy as an orthogonal tandem mass spectrometry technique that combines the sensitivity and selectivity of Liquid Chromotography-Mass-Spectroscopy (LC-MS) analysis with molecular structure identification using infrared spectroscopy. We have shown that this approach has the potential to significantly improve the current analytical workflow and could lead to improved agrochemical byproduct identification. Furthermore, IR spectra can be computationally predicted for candidate molecular structures, enabling the tentative identification of agrochemical derivatives and other unknowns in the environment without using physical reference standards. All the samples were synthesized at Syngenta, UK. The beam-time for this work was paid for by Syngenta at commercial rates. The company is keen to develop a more long term programme of such work and has fully sponsored a 4-year PhD studentship. FELIX and Syngenta are partners on a new EU-FET-Open project led by Warwick (also with Bristol and others). Reference Structural Elucidation of Agrochemicals and Related Derivatives Using Infrared Ion Spectroscopy. Matthias J.A. Vink, F.A.M.G. Geenen, G. Berden, Timothy J.C. O' Riordan, Peter Howe, W.A., J. Oomens, Simon J. Perry and J. Martens: (2022) Environ. Sci. Technol., 56, 15563-15572.
First Year Of Impact 2022
Sector Agriculture, Food and Drink,Chemicals
Impact Types Economic

 
Description UK FELIX Partnership 
Organisation Radboud University Nijmegen
Department FELIX Laboratory
Country Netherlands 
Sector Academic/University 
PI Contribution I helped set up this collaboration in 1993, and it has been active ever since. I have provided support for new UK users of FELIX, monitoring and reporting. I supported running of a FELIX user workshop in 2023.
Collaborator Contribution FELIX provides beam time to UK Users and academic/scientific and technical support for the experiments at the beam line. It provides infrastructure for a variety of experiments of interest to UK users.
Impact All of the outputs from FELIX users in the UK have benefitted from this collaboration.