Holocene Land-Ocean-Atmosphere Interactions on the Eastern Seaboard of North America
Lead Research Organisation:
Swansea University
Department Name: School of the Environment and Society
Abstract
Past terrestrial responses to climate-ocean interactions in the North Atlantic region are a critical research priority because they show how changes in key aspects of climate that will be affected by future global warming, such as ice sheet volume & ocean circulation, may be translated into phenomena of socio-economic importance, including the atmospheric water balance & soil moisture availability. Although we are beginning to understand the nature & magnitude of changes in the circulation of the North Atlantic over the last 10,000 years, terrestrial responses to these events are still poorly understood in terms of timing, magnitude & spatial pattern. It is imperative to rectify this deficiency in order to generate & test hypotheses to explain the processes of change, to understand the strength of relationships between oceanic & terrestrial climate change, & to enable future soil conditions & water resources to be predicted using computer models. Plan of work This project will investigate four sites located on a transect along the eastern seaboard of North America, from northern Newfoundland to Maine. This region was highly sensitive to past changes in ice sheet mass balance & ocean circulation. The selected sites are all raised (rain-fed) peat bogs, which provide superb climate archives. Plant & animal (testate amoebae) fossils preserved in well-dated cores extracted from these bogs will be used to reconstruct past changes in Bog Surface Wetness (an index of surface water balance) over the last 8500 years, at a time resolution of 10-100 years. The same core samples will be analysed for stable isotopes of oxygen & hydrogen. The spatial & temporal distribution of the heavy isotopes of these elements in precipitation is related to air temperature, & hence to atmospheric circulation. The isotope signal captured in the cellulose fraction of Sphagnum moss closely tracks that of the precipitation used by the plant for cellulose synthesis. Hence, fossil Sphagnum from raised peat preserves a clear signal of past changes in climate & atmospheric circulation. Modern precipitation along the eastern seaboard of North America is derived mainly from the Atlantic Ocean. A strong temperature contrast exists between the Arctic waters of the Labrador Current, which flows southwards along this coast, & the warm waters of the Gulf Stream further offshore. Past isotopic ratios in precipitation falling over coastal areas will have been strongly influenced by changes in these ocean currents & in the heat transport by the Gulf Stream. By combining the oxygen & hydrogen isotope records, we will estimate the deuterium excess, an index of the conditions prevailing at the sea surface when evaporation occurred, including the extent of sea ice. The stable isotope data will be compared with isotope measurements on ice cores from Greenland & Canadian ice caps, and more cautiously, with estimated isotope values for surface seawater & lakes that have been derived from sediment analyses. Hence, analyses of fossils & stable isotopes from the same core levels will allow us to reconstruct the timing, magnitude & spatial pattern of the terrestrial response, as well as exploring the impact of different causal factors such as meltwater discharges, changes in atmospheric & ocean circulation & solar variability on the climate of the study area. In this way, insight will be gained into the mechanisms that have driven climate change over the last 8500 years. Hypotheses to be tested: 1) Between 8500 & 6800 years ago, the climate of the study area was strongly influenced by repeated discharges of glacial meltwater from the decaying North American Ice Sheet to the north, resulting in cooling & increased bog wetness. 2) After the disappearance of the ice sheet, 6800 years ago, the climate of the study area was indirectly influenced by cyclical variations in sea ice extent, ocean currents & deepwater formation north of Iceland.
Organisations
Publications

Daley T
(2011)
The 8200yr BP cold event in stable isotope records from the North Atlantic region
in Global and Planetary Change

Loader N
(2016)
Measurements of hydrogen, oxygen and carbon isotope variability in Sphagnum moss along a micro-topographical gradient in a southern Patagonian peatland
in Journal of Quaternary Science

Loader NJ
(2015)
Simultaneous determination of stable carbon, oxygen, and hydrogen isotopes in cellulose.
in Analytical chemistry

Mackay H
(2016)
A mid to late Holocene cryptotephra framework from eastern North America
in Quaternary Science Reviews


Pyne-O'Donnell S
(2012)
High-precision ultra-distal Holocene tephrochronology in North America
in Quaternary Science Reviews

Woodley EJ
(2012)
High-temperature pyrolysis/gas chromatography/isotope ratio mass spectrometry: simultaneous measurement of the stable isotopes of oxygen and carbon in cellulose.
in Rapid communications in mass spectrometry : RCM
Description | The aim of the Swansea component of the PRECIP project (lead institution: Southampton, NE/G019851/1) was to develop and implement the application of stable-isotope analyses (oxygen-18 and hydrogen-2) to cellulose extracted from Sphagnum moss, in order to reconstruct past changes in North Atlantic climate and hydrology from raised peat bogs situated on the Atlantic margin of Canada and the NE USA. Recent technological developments permitted us to install and develop an on-line equilibration system capable of measuring these two isotopes, plus carbon-13, on the same sample of peat cellulose. This is only the second system of its kind to be installed in the world and the first to be used to retrieve information on hydrogen, oxygen and carbon isotopes simultaneously. After a considerable effort to install, calibrate and verify the analytical results obtained from this system, many hundreds of moss samples have now been extracted and analysed from 7 well-dated peat cores. In order to understand the processes controlling the different isotope signals in peat, these three isotopes have also been measured on surface moss samples from an instrumented transect across a modern pool-tussock sequence. This has demonstrated that the carbon-isotope signal is highly correlated with water-table depth, hence providing an integrated record of past wet and dry periods, whereas the oxygen- and hydrogen-isotope signals are strongly influenced by diurnal and seasonal variations in hydrological processes such as evaporation. Current efforts are now focussed on the interpretation of the records obtained from the peat cores. |
Exploitation Route | The on-line equilibration system has been used in the following NERC-funded projects: NE/G019673/1 NE/I022809/1 NE/I022981/1 NE/I022833/1 NE/I023104/1 NE/J013595/1 |
Sectors | Environment |
Description | Data cited in IPCC AR5 |
Geographic Reach | Multiple continents/international |
Policy Influence Type | Citation in other policy documents |
Title | Simultaneous determination of COH stable isotopes in organic matter |
Description | A technological development is developed through which the stable carbon-, oxygen- and non-exchangeable hydrogen-isotopic ratios (d13C, d18O, d2H) are determined on a single carbohydrate (cellulose) sample with precision equivalent to conventional techniques. This triple-isotope approach offers significant new research opportunities, most notably in physiology and medicine, isotope biogeochemistry, forensic science and palaeoclimatology, when isotopic analysis of a common sample is desirable or when sample material is limited |
Type Of Material | Technology assay or reagent |
Year Produced | 2014 |
Provided To Others? | Yes |
Impact | The development of a triple-isotope method represents a significant improvement over existing methods. The system performs comparably with standard methods in terms of analytical precision and importantly, requires less than a third of the sample material needed for single determinations using standard techniques. Analysis time is comparable with that of a single isotope determination by continuous flow. As the samples do not require nitration prior to analysis, significant efficiencies arise in the development of multiple-isotope time series. A further benefit of running three isotopic measurements on a single common sample is the increased statistical confidence in the mean value resulting from replicate analyses in cases where sample material is limited. If the triple-isotope approach is routinely adopted, we anticipate that the added information provided by the hydrogen-isotope data from a-cellulose samples will greatly facilitate modelling of hydrogen-isotope fractionation in plants and lead to a more complete understanding of carbon-, oxygen- and hydrogen-isotopic variability in the Earth system |
Description | Poster on stable isotopes in peat |
Form Of Engagement Activity | Participation in an activity, workshop or similar |
Part Of Official Scheme? | No |
Geographic Reach | International |
Primary Audience | Professional Practitioners |
Results and Impact | Quaternary Research Association (QRA) Annual discussion meeting on "Drivers and Responders" in the study of climate forcing. Poster presented outlining peat research with stable isotopes. |
Year(s) Of Engagement Activity | 2016 |
Description | Simultaneous determination of COH isotopes in organic matter |
Form Of Engagement Activity | A talk or presentation |
Part Of Official Scheme? | No |
Geographic Reach | International |
Primary Audience | Other academic audiences (collaborators, peers etc.) |
Results and Impact | Talk led to questions and discussion. Submitted for publication. |
Year(s) Of Engagement Activity | 2014 |