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From arc magmas to ores (FAMOS): A mineral systems approach

Lead Research Organisation: The Open University
Department Name: Faculty of Sci, Tech, Eng & Maths (STEM)

Abstract

Society is dependent on a reliable supply of metals and minerals for economic growth, improved standards of living, and development of infrastructure. Population growth means that even with increased recycling and resource efficiency, new mineral deposits still need to be discovered. The efficient exploration for, and discovery of, new resources requires new concepts and new tools.
The Mineral Systems approach to exploration considers ore deposits on a lithospheric scale, in terms of the "ingredients", processes and environments that favour their formation. This approach amounts to a "source-pathway-trap" model, with an increased emphasis on predictive capacity, rather than just feature recognition. Historically, much research has focused on the trap, and characterisation of the ore deposits themselves; here we aim to focus deeper in the system by integrating ore deposit formation with concepts of magmatism that arise from igneous petrology and volcanology. Therein lies a challenge because extant models for porphyry systems are increasingly at odds with magmatic models for crustal construction and arc volcanism. Rather than seeing magmatic systems in terms of large, liquid-rich magma chambers, emerging petrological models for crustal magmatism are turning instead to crystal-dominated, volatile-bearing "mushy" systems that traverse most or all of the crust. The dynamics of such systems have important consequences not just for arc magmatism, but also for the chemistry of the volatiles that are exsolved. These same volatiles fuel mineralisation and this is the synergy that we aim to exploit by assembling a multidisciplinary team of researchers from economic geology, igneous and metamorphic petrology, volcanology, geochemistry, numerical modelling and fluid dynamics. Our team embraces almost everyone currently engaged in porphyry mineralisation research in the UK and capitalises on strong existing links between UK ROs and the mining industry, many of who are Project Partners.
The research will involve analysis of minerals from a wide variety of mineralised and barren settings using a wealth of modern analytical tools that enable determination of an extensive suite of trace elements and isotope tracers. As each trace element responds to magmatic processes in subtly different ways due to the affinity of different elements for different phases (minerals, melts and fluids), so the multi-element approach affords many advantages over conventional proxies in which the full potential of the Periodic Table is not exploited. The analysis of natural systems will be underpinned by high pressure and temperature experiments to establish the phase relationships of ascending arc magmas and the partition coefficients that capture the affinities of elements for certain phases. As fluid accumulation and migration is an essential, but poorly understood, final step in ore deposit formation, we will develop, in tandem with the geochemistry, numerical models for fluid-bearing mushy systems. Finally, consideration will be given to critical metals that are passengers through the main ore-forming processes, but constitute important, often under-explored, by-products of porphyry mineralisation.
The research proposed has a strong element of blue skies investigation, but a particular focus on outcomes that will benefit industry through improved exploration tools. Thus the project bridges the divide between academic and applied research in a way that is not normally possible through industry-funded projects. This bridging activity lies at the heart of the Highlight Topic call, specifically through the integration of new advances in the study of mineral systems, igneous petrology and geochemistry, with a view to identifying conditions that can act as pathfinders for new targets. A key outcome will be a range of trace element proxies that will enable the mining industry to establish the potential fertility of a magmatic arc on local to regional scales.

Planned Impact

We have taken an "embedded impact" approach with FAMOS. Stakeholders and beneficiaries have been involved with the development of the project from its initiation (including the initial Highlight Topic suggestion). The scientific content of the proposal was developed in discussion with representatives from industry, and the final consortium has assembled an Advisory Board that includes industry representatives so as to maintain two-way knowledge exchange and ensure development of impact. We have also engaged an international set of project partners (PP) who will extend the reach of our impact (see letters of support). The embedded impact will be delivered through various activities to support outreach, engagement and dissemination.

The key impact goal for FAMOS is to improve discovery rates of porphyry deposits by aiding exploration under cover, influencing decision making in the exploration process, reducing exploration risk and reducing the environmental impacts of drilling and associated disruptive fieldwork through more efficient prospectivity assessment.

There are four impact objectives within FAMOS:

1) A revised Mineral Systems model of porphyry deposit formation. This will lead to improved targeting at regional and igneous complex scales and better inputs to national strategies on mineral resources. Beneficiaries include PRIVATE SECTOR COMPANIES involved in mining, exploration and consultancy (e.g. PPs Anglo American, Rio Tinto, BHPBilliton, Freeport McMoRan), and NATIONAL AGENCIES charged with encouraging exploration and developing strategic resources (e.g. BGS and PP USGS).

2) New proxies for porphyry fertility. This will provide low-cost tools and approaches that will support improved decision-making during exploration. By using multiple proxies within a single sample, more data-rich exploration is possible, and in turn less sampling is required and less environmental impact is caused. Beneficiaries will include PRIVATE SECTOR COMPANIES involved in exploration, consultancy, and the provision of data and analytical equipment to industry (i.e. service companies, e.g. see PPs Olympus, Zeiss and SRK ES letters of support).

3) E-tech elements in porphyries. We will generate vital data for better global and national e-tech resource estimation. This facilitates improved targeting for specific e-techs during exploration, and improved metallurgical characterisation of them. Beneficiaries will be GOVERNMENT AGENCIES who advise on resource strategy (e.g. BGS, PP USGS), and POLICY MAKERS IN GOVERNMENT planning future clean energy strategies. PRIVATE SECTOR COMPANIES exploring for resources (see PP Anglo American letter of support) and end-users of e-techs will benefit through improved strategic knowledge of future supplies and the WIDER PUBLIC will gain through support of sustainable environmental technologies for a low-carbon society.

4) Outreach, education and training. We have planned activities to increase public understanding of resource issues (discovery, depletion, environmental and social impacts, the 'e-tech' concept), particularly through NHM outreach, and activities to encourage the uptake of the new model and proxies with professional geoscientists through training workshops, short courses and engagement at high profile conferences. Beneficiaries include the WIDER PUBLIC, PRIVATE SECTOR COMPANIES as publicly traded bodies and employers of skilled professionals and PROFESSIONAL BODIES such as the IOM3 and Mineral Deposits Studies Group (see letter of support) who support training and professional development for their members.

Publications

10 25 50
 
Description The results of the FAMOS grant have been used to place new constraints on the processes that contribute to the evolution of economically important ore deposits. This includes during similar processes, such as the partitioning of elements into fluids and gases that are released by during volcanic eruptions.
Exploitation Route Understanding the triggers for the enrichment of economically important concentrations of metals in the crust can be used to help predict which region of crust should be mined in the future.
Sectors Education

Energy

Environment

Manufacturing

including Industrial Biotechology

Culture

Heritage

Museums and Collections

Other

 
Description The findings of this research have helped to refine models that are used to explain the formation of the Earth's magmatic copper deposits.
First Year Of Impact 2000
Sector Energy,Manufacturing, including Industrial Biotechology
Impact Types Societal

Economic

 
Title Laser ablation ICP-MS of silver and selenium in melt inclusions 
Description We developed the new capability to analyse selenium and silver in melt inclusions that are 50 microns in size (and larger) using laser ablation ICP-MS. 
Type Of Material Improvements to research infrastructure 
Year Produced 2020 
Provided To Others? Yes  
Impact This new capability allowed us to demonstrate that selenium partitions into fluids during shallow crustal processes and during subaerial eruptions. This finding will aid in the understanding of the toxic hazards associated with volcanic eruptions and the evolution of ore deposits in the crust. 
URL https://www.sciencedirect.com/user/identity/landing?code=t7Lu0ftPHAXFtJ4aPx5x3P92LyL6INfa2iB8NnFU&st...
 
Title Research Data supporting "Chalcophile element processing at an active continental arc volcano" 
Description Two excel spreadsheets containing compositional data for silicate melts and volcanic gases and aerosols collected from Villarrica Volcano, Chile. Data were collected as part of Emily Mason's EPSRC studentship. The first excel spreadsheet, Mason Data 1, contains volcanic gas and aerosol composition and associated metadata for Villarrica Volcano, Chile, global compilations of emanation coefficients and emission rates. Tab 1 contains a detailed description of the datasets. Samples were collected using filter packs and cascade impactors from the crater rim. Filters were analysed at the University of Cambridge using ICP-MS. The second excel spreadsheet, Mason Data 2, contains melt inclusion major, volatile and trace element data for erupted products of Villarrica Volcano, Chile. Tab 1 gives a full description of the datasets. Major elements and sulfur, chlorine concentrations were measured by electron microprobe at the University of Cambridge. Trace elements were measured at the Open University using Laser Ablation ICP-MS. 
Type Of Material Database/Collection of data 
Year Produced 2023 
Provided To Others? Yes  
URL https://www.repository.cam.ac.uk/handle/1810/361418
 
Description BHP 
Organisation BHP Billiton
Country Australia 
Sector Private 
PI Contribution Presented initial project results to representatives from BHP in May and November 2018, highlighting industry-relevant aspects.
Collaborator Contribution BHP agreed to open up project results from two PhD projects they are supporting and provide access to samples from several of their operations.
Impact None
Start Year 2018
 
Description Barbara Kunz spoke about the FAMOS project at Soapbox Science 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach Regional
Primary Audience Public/other audiences
Results and Impact Dr Barbara Kunz, research project officer working in the geochemistry lab of the School of Environment, Earth and Ecosystem Sciences at the Open University (OU) spoke about the FAMOS project at Soapbox Science, Milton Keynes in June 2019. Soapbox Science is a novel public outreach platform for promoting women scientists and the science they do.
Year(s) Of Engagement Activity 2019
URL http://soapboxscience.org
 
Description Science-a-thon 
Form Of Engagement Activity Engagement focused website, blog or social media channel
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Public/other audiences
Results and Impact A series of images & short caption on Twitter about about Barbara Kunz's day of science, to show what day to day science looks likes.
Year(s) Of Engagement Activity 2019