Investigating HALocarbon impacts on the global Environment (InHALE)

Lead Research Organisation: University of Bristol
Department Name: Chemistry

Abstract

With the Kigali Amendment coming into force in 2019, the Montreal Protocol on Substances that Deplete the Ozone Layer has entered a major new phase in which the production and use of hydrofluorocarbons (HFCs) will be controlled in most major economies. This landmark achievement will enhance the Protocol's already-substantial benefits to climate, in addition to its success in protecting the ozone layer. However, recent scientific advances have shown that challenges lie ahead for the Montreal Protocol, due to the newly discovered production of ozone-depleting substances (ODS) thought to be phased-out, rapid growth of ozone-depleting compounds not controlled under the Protocol, and the potential for damaging impacts of halocarbon degradation products. This proposal tackles the most urgent scientific questions surrounding these challenges by combining state-of-the-art techniques in atmospheric measurements, laboratory experiments and advanced numerical modelling. We will: 1) significantly expand atmospheric measurement coverage to better understand the global distribution of halocarbon emissions and to identify previously unknown atmospheric trends, 2) combine industry models and atmospheric data to improve our understanding of the relationship between production (the quantity controlled under the Protocol), "banks" of halocarbons stored in buildings and products, and emissions to the atmosphere, 3) determine recent and likely future trends of unregulated, short-lived halocarbons, and implications for the timescale of recovery of the ozone layer, 4) explore the complex atmospheric chemistry of the newest generation of halocarbons and determine whether breakdown products have the potential to contribute to climate change or lead to unforeseen negative environmental consequences, 5) better quantify the influence of halocarbons on climate and refine the climate- and ozone-depletion-related metrics used to compare the effects of halocarbons in international agreements and in the design of possible mitigation strategies. This work will be carried out by a consortium of leaders in the field of halocarbon research, who have an extensive track record of contributing to Montreal Protocol bodies and the Intergovernmental Panel on Climate Change, ensuring lasting impact of the new developments that will be made.
 
Description Advanced Global Atmospheric Gases Experiment (AGAGE) 
Organisation Commonwealth Scientific and Industrial Research Organisation
Country Australia 
Sector Public 
PI Contribution International programme to measure and model atmospheric trace gases
Collaborator Contribution Data provision. Model development.
Impact Several publications (e.g. Rigby et al., 2013; 2014).
Start Year 2008
 
Description Advanced Global Atmospheric Gases Experiment (AGAGE) 
Organisation Empa - Swiss Federal Laboratories for Materials Science and Technology
Country Switzerland 
Sector Academic/University 
PI Contribution International programme to measure and model atmospheric trace gases
Collaborator Contribution Data provision. Model development.
Impact Several publications (e.g. Rigby et al., 2013; 2014).
Start Year 2008
 
Description Advanced Global Atmospheric Gases Experiment (AGAGE) 
Organisation Massachusetts Institute of Technology
Country United States 
Sector Academic/University 
PI Contribution International programme to measure and model atmospheric trace gases
Collaborator Contribution Data provision. Model development.
Impact Several publications (e.g. Rigby et al., 2013; 2014).
Start Year 2008
 
Description MET Office 
Organisation Meteorological Office UK
Country United Kingdom 
Sector Academic/University 
PI Contribution The MET Office are a subcontracted partner. Our contribution is financial but also data sharing.
Collaborator Contribution Initially the MET Office was conducting inversion modelling, however, their role now is primarily providing advice. The modelling is being done at the University of Bristol because the MET Office have enabled access to the NAME modelling via the JASMIN portal.
Impact None to date. The project is ongoing.
Start Year 2012
 
Description Massachusetts Institute of Technology 
Organisation Massachusetts Institute of Technology
Country United States 
Sector Academic/University 
PI Contribution I collaborate closely with Prof. Ron Prinn, who is PI of the AGAGE network, at MIT, Cambridge, MA, USA.
Collaborator Contribution Access to data, model development
Impact The collaboration has so far involved several joint publications (e.g. Rigby et al., 2013; 2014) and invited visits to MIT.
Start Year 2012
 
Description Met Office 
Organisation Meteorological Office UK
Country United Kingdom 
Sector Academic/University 
PI Contribution Expertise in inverse methods
Collaborator Contribution Exertise in atmospheric modelling
Impact Publications.
Start Year 2012
 
Description National Oceanic and Atmospheric Administration (NOAA) Earth System Research Laboratory (ESRL) 
Organisation National Oceanic And Atmospheric Administration
Department Earth System Research Laboratory (ESRL)
Country United States 
Sector Public 
PI Contribution Modelling of greenhouse gases.
Collaborator Contribution Provision of greenhouse gas data and expertise
Impact Several publications have resulted from this collaboration.
Start Year 2012
 
Description University of Wollongong 
Organisation University of Wollongong
Country Australia 
Sector Academic/University 
PI Contribution Model runs, data provision and processing, expertise in atmospheric modelling and statistics.
Collaborator Contribution Expertise in statistics
Impact Several publications, with further work in the pipeline.
Start Year 2013
 
Title OpenGHG 
Description A toolkit for greenhouse gas data analysis 
Type Of Technology Software 
Year Produced 2022 
Open Source License? Yes  
Impact Software is being used to evaluate the UK's greenhouse gas emissions 
 
Title mrghg/py12box: v0.2.2 
Description See documentation for 0.2.1. Updated packaging information 
Type Of Technology Software 
Year Produced 2022 
Open Source License? Yes  
Impact This software is used to calculate global emissions of ozone depleting substances and greenhouse gases for the WMO Scientific Assessment of Ozone Depletion. 
URL https://zenodo.org/record/6868589