Investigating HALocarbon impacts on the global Environment (InHALE)
Lead Research Organisation:
University of Bristol
Department Name: Chemistry
Abstract
With the Kigali Amendment coming into force in 2019, the Montreal Protocol on Substances that Deplete the Ozone Layer has entered a major new phase in which the production and use of hydrofluorocarbons (HFCs) will be controlled in most major economies. This landmark achievement will enhance the Protocol's already-substantial benefits to climate, in addition to its success in protecting the ozone layer. However, recent scientific advances have shown that challenges lie ahead for the Montreal Protocol, due to the newly discovered production of ozone-depleting substances (ODS) thought to be phased-out, rapid growth of ozone-depleting compounds not controlled under the Protocol, and the potential for damaging impacts of halocarbon degradation products. This proposal tackles the most urgent scientific questions surrounding these challenges by combining state-of-the-art techniques in atmospheric measurements, laboratory experiments and advanced numerical modelling. We will: 1) significantly expand atmospheric measurement coverage to better understand the global distribution of halocarbon emissions and to identify previously unknown atmospheric trends, 2) combine industry models and atmospheric data to improve our understanding of the relationship between production (the quantity controlled under the Protocol), "banks" of halocarbons stored in buildings and products, and emissions to the atmosphere, 3) determine recent and likely future trends of unregulated, short-lived halocarbons, and implications for the timescale of recovery of the ozone layer, 4) explore the complex atmospheric chemistry of the newest generation of halocarbons and determine whether breakdown products have the potential to contribute to climate change or lead to unforeseen negative environmental consequences, 5) better quantify the influence of halocarbons on climate and refine the climate- and ozone-depletion-related metrics used to compare the effects of halocarbons in international agreements and in the design of possible mitigation strategies. This work will be carried out by a consortium of leaders in the field of halocarbon research, who have an extensive track record of contributing to Montreal Protocol bodies and the Intergovernmental Panel on Climate Change, ensuring lasting impact of the new developments that will be made.
Organisations
- University of Bristol (Lead Research Organisation)
- University of Wollongong (Collaboration)
- National Oceanic and Atmospheric Administration (Collaboration)
- Commonwealth Scientific and Industrial Research Organisation (Collaboration)
- Meteorological Office UK (Collaboration)
- Massachusetts Institute of Technology (Collaboration)
- Empa - Swiss Federal Laboratories for Materials Science and Technology (Collaboration)
- SPARC (Project Partner)
- GEOMAR Helmholtz Ctr for Ocean Research (Project Partner)
- Dept for Env Food & Rural Affairs DEFRA (Project Partner)
- Honeywell International Inc (Project Partner)
- Marine and Atmospheric Research (Project Partner)
- Spanish National Research Council (CSIC) (Project Partner)
- NCAR (Project Partner)
- Macalester College (Project Partner)
- National Institute for Env Studies NIES (Project Partner)
- Academia Sinica Taiwan (Project Partner)
- Karlsruhe Institute of Technology (KIT) (Project Partner)
- Vietnam National University Ho Chi Minh (Project Partner)
- CICERO Ctr fr Intnatnl Climate & Env Res (Project Partner)
- Empa (Swiss Fed Labs of Mat Sci Tech) (Project Partner)
- CNRS (Project Partner)
- University of Malaysia (Project Partner)
- Fudan University (Project Partner)
Publications
An M
(2023)
Anthropogenic Chloroform Emissions from China Drive Changes in Global Emissions.
in Environmental science & technology
An M
(2024)
Sustained growth of sulfur hexafluoride emissions in China inferred from atmospheric observations.
in Nature communications
An M
(2024)
Substantial increase in perfluorocarbons CF4 (PFC-14) and C2F6 (PFC-116) emissions in China.
in Proceedings of the National Academy of Sciences of the United States of America
Curchod BFE
(2024)
Perspective on Theoretical and Experimental Advances in Atmospheric Photochemistry.
in The journal of physical chemistry. A
Garavagno M
(2024)
Trifluoroacetic Acid: Toxicity, Sources, Sinks and Future Prospects
in Sustainability
Wang Y
(2024)
Rising Perfluorocyclobutane (PFC-318, c-C4F8) Emissions in China from 2011 to 2020 Inferred from Atmospheric Observations.
in Environmental science & technology
Weng W
(2024)
Nitrogen Trifluoride Emissions in China from 2017 to 2021 Derived from Atmospheric Observations
in Environmental Science & Technology Letters
Western L
(2024)
MALTA: A Zonally Averaged Global Atmospheric Transport Model for Long-Lived Trace Gases
in Journal of Advances in Modeling Earth Systems
| Description | Using atmospheric observations of ozone depleting substances from global networks, several key research outcomes have been achieved, including: the identification of persistent emissions of the potent greenhouse gas, HFC-23, despite the implementation of the Kigali Amendment to the Montreal Protocol (Adam et al., 2024), the finding that HCFC radiative forcing had likely peaked in 2021 (Western et al., 2023), and studies showing the role of emissions from China of chloroform and sulphur hexafluoride (An et al., 2023; 2024). |
| Exploitation Route | The measurements and code underpinning the outcomes of this award have been released into the public domain. Our outcomes will be summarised and shared with the public and parties to the Montreal Protocol through the upcoming WMO Scientific Assessment of Ozone Depletion. |
| Sectors | Environment |
| Description | Lead authorship of WMO Scientific Assessment of Ozone Depletion 2022 |
| Geographic Reach | Multiple continents/international |
| Policy Influence Type | Participation in a guidance/advisory committee |
| URL | https://csl.noaa.gov/assessments/ozone/2022/ |
| Description | Advanced Global Atmospheric Gases Experiment (AGAGE) |
| Organisation | Commonwealth Scientific and Industrial Research Organisation |
| Country | Australia |
| Sector | Public |
| PI Contribution | International programme to measure and model atmospheric trace gases |
| Collaborator Contribution | Data provision. Model development. |
| Impact | Several publications (e.g. Rigby et al., 2013; 2014). |
| Start Year | 2008 |
| Description | Advanced Global Atmospheric Gases Experiment (AGAGE) |
| Organisation | Empa - Swiss Federal Laboratories for Materials Science and Technology |
| Country | Switzerland |
| Sector | Academic/University |
| PI Contribution | International programme to measure and model atmospheric trace gases |
| Collaborator Contribution | Data provision. Model development. |
| Impact | Several publications (e.g. Rigby et al., 2013; 2014). |
| Start Year | 2008 |
| Description | Advanced Global Atmospheric Gases Experiment (AGAGE) |
| Organisation | Massachusetts Institute of Technology |
| Country | United States |
| Sector | Academic/University |
| PI Contribution | International programme to measure and model atmospheric trace gases |
| Collaborator Contribution | Data provision. Model development. |
| Impact | Several publications (e.g. Rigby et al., 2013; 2014). |
| Start Year | 2008 |
| Description | MET Office |
| Organisation | Meteorological Office UK |
| Country | United Kingdom |
| Sector | Academic/University |
| PI Contribution | The MET Office are a subcontracted partner. Our contribution is financial but also data sharing. |
| Collaborator Contribution | Initially the MET Office was conducting inversion modelling, however, their role now is primarily providing advice. The modelling is being done at the University of Bristol because the MET Office have enabled access to the NAME modelling via the JASMIN portal. |
| Impact | None to date. The project is ongoing. |
| Start Year | 2012 |
| Description | Massachusetts Institute of Technology |
| Organisation | Massachusetts Institute of Technology |
| Country | United States |
| Sector | Academic/University |
| PI Contribution | I collaborate closely with Prof. Ron Prinn, who is PI of the AGAGE network, at MIT, Cambridge, MA, USA. |
| Collaborator Contribution | Access to data, model development |
| Impact | The collaboration has so far involved several joint publications (e.g. Rigby et al., 2013; 2014) and invited visits to MIT. |
| Start Year | 2012 |
| Description | Met Office |
| Organisation | Meteorological Office UK |
| Country | United Kingdom |
| Sector | Academic/University |
| PI Contribution | Expertise in inverse methods |
| Collaborator Contribution | Exertise in atmospheric modelling |
| Impact | Publications. |
| Start Year | 2012 |
| Description | National Oceanic and Atmospheric Administration (NOAA) Earth System Research Laboratory (ESRL) |
| Organisation | National Oceanic And Atmospheric Administration |
| Department | Earth System Research Laboratory (ESRL) |
| Country | United States |
| Sector | Public |
| PI Contribution | Modelling of greenhouse gases. |
| Collaborator Contribution | Provision of greenhouse gas data and expertise |
| Impact | Several publications have resulted from this collaboration. |
| Start Year | 2012 |
| Description | University of Wollongong |
| Organisation | University of Wollongong |
| Country | Australia |
| Sector | Academic/University |
| PI Contribution | Model runs, data provision and processing, expertise in atmospheric modelling and statistics. |
| Collaborator Contribution | Expertise in statistics |
| Impact | Several publications, with further work in the pipeline. |
| Start Year | 2013 |
| Title | OpenGHG |
| Description | A toolkit for greenhouse gas data analysis |
| Type Of Technology | Software |
| Year Produced | 2022 |
| Open Source License? | Yes |
| Impact | Software is being used to evaluate the UK's greenhouse gas emissions |
| Title | mrghg/py12box: v0.2.2 |
| Description | See documentation for 0.2.1. Updated packaging information |
| Type Of Technology | Software |
| Year Produced | 2022 |
| Open Source License? | Yes |
| Impact | This software is used to calculate global emissions of ozone depleting substances and greenhouse gases for the WMO Scientific Assessment of Ozone Depletion. |
| URL | https://zenodo.org/record/6868589 |
