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Origin and processing of water in the early Solar System

Lead Research Organisation: University of Manchester
Department Name: Earth Atmospheric and Env Sciences

Abstract

Liquid water allowed life to develop on the Earth. Yet we are still pondering on fundamental questions such as where does Solar System water come from, and when was it delivered to rocky planets in the inner Solar System? These fascinating issues motivate my interdisciplinary research across Planetary and Earth Sciences. Finding answers on the Earth may prove difficult because our planet's surface has been continuously eroded and recycled since its formation. However, asteroids whizzing around the Solar System, and to which we have access through meteorites found here on the Earth, have preserved vital records of the planet-forming epoch. Through this STFC Ernest Rutherford Fellowship I aim to characterise the water inventory in these planetary building blocks, in order to constrain the origin(s) of water in the Solar System. Eventually, a better understanding of the origin of water in our own Solar System will help interpretation of the recent discoveries of water-bearing planetesimals in extrasolar systems.

The formation of our Solar System started some 4.57 billion years ago from the collapse of a dense molecular cloud. From there it took several steps to form rocky planets in the inner Solar System: condensation of dust, agglomeration of cm-sized grains, accretion of 10-100 km-sized planetary embryos, heating and melting of some of these objects, and eventually further collisions leading to the formation of larger planets. The asteroid belt present today between the orbits of Mars and Jupiter contains leftovers of these planetary embryos that never made it to the final planet stage. This asteroid belt is the source of most meteorites found on the Earth. Studying these samples provides us with access to some of the processes that took place during the birth of our Solar System.

Different types of meteorites formed at different distances from the Sun, and at slightly different times after the Sun's formation. Some accreted directly from the disc of materials orbiting the young Sun (the chondrite group), and others formed through melting of larger bodies (the achondrite group). Previous studies on water in the early Solar System have focused on the carbonaceous chondrite meteorite group, which contains an abundance of carbon and water. However, the characteristics of water in older groups of meteorites (ordinary chondrites and early-formed achondrites) are poorly understood since very few studies have ever focused on these samples before. Is their water inventory consistent with that of the carbonaceous chondrite groups? How does it compare with comets? Were there previously unrecognised unknown water reservoirs that existed in the early Solar System? Does the isotopic signature of water vary with formation distance from the Sun? I will establish a comprehensive inventory of water in unexplored types of objects formed within 5 million years of the Solar System's formation, and integrate these new data into models of evolution of the early Solar System.

My study will provide new constraints on the origin of water in planetary building blocks and its processing during their evolution that eventually led to the formation of rocky planets. This space-related topic is timely as there are several upcoming international space missions that will visit primitive asteroids and collect materials to return to the Earth. I will leverage the excitement and the public interest for space exploration as a fantastic opportunity for engaging people towards Science. To this end I will participate in the numerous outreach activities attended by the Isotope group at the University of Manchester, and communicate my discoveries through its popular 'Earth and Solar System' blog.

Publications

10 25 50
 
Description Made some important discoveries on the water hydrogen isotope signature in the least metamorphosed ordinary chondrites. We now believe the very high D/H ratio host to be amorphous silicates inherited from the protosolar molecular cloud rather than water ice. This has key implications for dynamical models of the early Solar System that we are still working on.
Exploitation Route As mentioned above, a better understanding of the different H-bearing components and their isotopic signatures is key for early Solar System dynamical modelling. Others can use our published results.
Sectors Other

 
Description Member of the ESA PROSPECT Science Team
Geographic Reach Europe 
Policy Influence Type Membership of a guideline committee
 
Description Member of the European Space Agency "Geologic Mission" Topical Team
Geographic Reach Europe 
Policy Influence Type Membership of a guideline committee
 
Description Member of the STFC Solar System Advisory Panel (SSAP)
Geographic Reach National 
Policy Influence Type Participation in a guidance/advisory committee
 
Description Member of the UK Space Agency Space Exploration Advisory Committee
Geographic Reach Europe 
Policy Influence Type Participation in a guidance/advisory committee
 
Description Science team member for the NASA DIMPLE experiment
Geographic Reach North America 
Policy Influence Type Participation in a guidance/advisory committee
 
Description Deciphering the impact record at different times and different scales on the Moon
Amount £597,585 (GBP)
Funding ID ST/Y002318/1 
Organisation Science and Technologies Facilities Council (STFC) 
Sector Public
Country United Kingdom
Start 09/2024 
End 09/2027
 
Description PPAN/EI Capital Call 2018
Amount £235,559 (GBP)
Funding ID ST/S002170/1 
Organisation Science and Technologies Facilities Council (STFC) 
Sector Public
Country United Kingdom
Start 09/2018 
End 03/2019
 
Description Planetary Science at The University of Manchester
Amount £2,079,553 (GBP)
Funding ID ST/V000675/1 
Organisation Science and Technologies Facilities Council (STFC) 
Sector Public
Country United Kingdom
Start 03/2021 
End 03/2025
 
Description gyt
Amount £70,072 (GBP)
Funding ID ST/Y006011/1 
Organisation UK Space Agency 
Sector Public
Country United Kingdom
Start 01/2024 
End 12/2028
 
Title Apatite U-Pb dating in Brachina meteorite 
Description Raw LA-ICP-MS apatite U-Pb data for meteorite Brachina. This folder contains: - a .csv file with raw ICP-MS data - an .xml file with ICP-MS metadata - a LaserLog.csv with laser log file - a .lase file with laser metadata 
Type Of Material Database/Collection of data 
Year Produced 2023 
Provided To Others? Yes  
URL https://figshare.manchester.ac.uk/articles/dataset/Apatite_U-Pb_dating_in_Brachina_meteorite/2356613...
 
Title Bulk mineralogy, water abundance, and hydrogen isotope composition of unequilibrated ordinary chondrites Supplementary Data 
Description Supplementary data to the paper: 'Bulk mineralogy, water abundance, and hydrogen isotope composition of unequilibrated ordinary chondrites' (https://doi.org/10.1111/maps.14041). Included in this folder is:Raw_IRMS_data.xlsx - Data file containing the raw isotope ratio mass spectrometry (IRMS) data, including standards.RAW_XRD_data.xlsx - Data file containing the raw X-ray diffraction spectral data.IRMS_refdata (.ods and .xlsx) - Data file containing the IRMS data, alongside reference data and calculations of matrix H2O contents.Plots - Folder containing (where available) interactive plots 
Type Of Material Database/Collection of data 
Year Produced 2024 
Provided To Others? Yes  
URL https://figshare.manchester.ac.uk/articles/dataset/Bulk_mineralogy_water_abundance_and_hydrogen_isot...
 
Title Bulk mineralogy, water abundance, and hydrogen isotope composition of unequilibrated ordinary chondrites Supplementary Data 
Description Supplementary data to the paper: 'Bulk mineralogy, water abundance, and hydrogen isotope composition of unequilibrated ordinary chondrites' (https://doi.org/10.1111/maps.14041). Included in this folder is:Raw_IRMS_data.xlsx - Data file containing the raw isotope ratio mass spectrometry (IRMS) data, including standards.RAW_XRD_data.xlsx - Data file containing the raw X-ray diffraction spectral data.IRMS_refdata (.ods and .xlsx) - Data file containing the IRMS data, alongside reference data and calculations of matrix H2O contents.Plots - Folder containing (where available) interactive plots 
Type Of Material Database/Collection of data 
Year Produced 2024 
Provided To Others? Yes  
URL https://figshare.manchester.ac.uk/articles/dataset/Bulk_mineralogy_water_abundance_and_hydrogen_isot...
 
Title Carbonaceous chondrite organics triple oxygen isotope composition 
Description Raw oxygen isotope data obtained by secondary ion mass spectrometry (both CAMECA IMS 1270/80 and NanoSIMS 50L ion probes) on organics from CI and CM chondrites. 
Type Of Material Database/Collection of data 
Year Produced 2018 
Provided To Others? Yes  
Impact Related paper published in Proceedings of the National Academy of Sciences USA 
URL https://data.mendeley.com/datasets/hwwsdz8997/1
 
Title Carbonate U-Pb dating - martian meteorite ALH 84001 
Description Raw LA-ICP-MS carbonate U-Pb data for martian meteorite ALH 84001. This folder contains: - a .csv file with raw ICP-MS data - an .xml file with ICP-MS metadata - a LaserLog.csv with laser log file - a .lase file with laser metadata 
Type Of Material Database/Collection of data 
Year Produced 2023 
Provided To Others? Yes  
URL https://figshare.manchester.ac.uk/articles/dataset/Carbonate_U-Pb_dating_-_martian_meteorite_ALH_840...
 
Title Carbonate U-Pb dating - martian meteorite ALH 84001 
Description Raw LA-ICP-MS carbonate U-Pb data for martian meteorite ALH 84001. This folder contains: - a .csv file with raw ICP-MS data - an .xml file with ICP-MS metadata - a LaserLog.csv with laser log file - a .lase file with laser metadata 
Type Of Material Database/Collection of data 
Year Produced 2023 
Provided To Others? Yes  
URL https://figshare.manchester.ac.uk/articles/dataset/Carbonate_U-Pb_dating_-_martian_meteorite_ALH_840...
 
Title Data for: The isotopic composition of volatiles in the unique Bench Crater carbonaceous chondrite impactor found in the Apollo 12 regolith 
Description Data tables 1 and 2 to accompany Joy et al. Bench Crater manuscript. 
Type Of Material Database/Collection of data 
Year Produced 2021 
Provided To Others? Yes  
URL https://data.mendeley.com/datasets/5pjvm3g5tm/1
 
Title Data for: The isotopic composition of volatiles in the unique Bench Crater carbonaceous chondrite impactor found in the Apollo 12 regolith 
Description Data tables 1 and 2 to accompany Joy et al. Bench Crater manuscript. 
Type Of Material Database/Collection of data 
Year Produced 2021 
Provided To Others? Yes  
URL https://data.mendeley.com/datasets/5pjvm3g5tm
 
Title Data for: The isotopic composition of volatiles in the unique Bench Crater carbonaceous chondrite impactor found in the Apollo 12 regolith 
Description Table 1. Light isotope (H, C and N) compositions determined for fragments of the Bench Crater and Murchison meteorites in this study and related literature measurements. Table 2. Oxygen isotope results in phases within Bench Crater meteorite. 
Type Of Material Database/Collection of data 
Year Produced 2021 
Provided To Others? Yes  
URL https://data.mendeley.com/datasets/bft98fbnkr/1
 
Title Data for: The isotopic composition of volatiles in the unique Bench Crater carbonaceous chondrite impactor found in the Apollo 12 regolith 
Description Table 1. Light isotope (H, C and N) compositions determined for fragments of the Bench Crater and Murchison meteorites in this study and related literature measurements. Table 2. Oxygen isotope results in phases within Bench Crater meteorite. 
Type Of Material Database/Collection of data 
Year Produced 2021 
Provided To Others? Yes  
URL https://data.mendeley.com/datasets/mgtbvzf3nz
 
Title Data for: The isotopic composition of volatiles in the unique Bench Crater carbonaceous chondrite impactor found in the Apollo 12 regolith 
Description Table 1. Light isotope (H, C and N) compositions determined for fragments of the Bench Crater and Murchison meteorites in this study and related literature measurements. Table 2. Oxygen isotope results in phases within Bench Crater meteorite. 
Type Of Material Database/Collection of data 
Year Produced 2021 
Provided To Others? Yes  
URL https://data.mendeley.com/datasets/mgtbvzf3nz/1
 
Title Data for: The isotopic composition of volatiles in the unique Bench Crater carbonaceous chondrite impactor found in the Apollo 12 regolith 
Description Table 1. Light isotope (H, C and N) compositions determined for fragments of the Bench Crater and Murchison meteorites in this study and related literature measurements. Table 2. Oxygen isotope results in phases within Bench Crater meteorite. 
Type Of Material Database/Collection of data 
Year Produced 2021 
Provided To Others? Yes  
URL https://data.mendeley.com/datasets/bft98fbnkr
 
Title Electronic Supplementary Materials - Data Tables from Timing of geological events in the lunar highlands recorded in shocked zircon-bearing clasts from Apollo 16 
Description Apollo 16 soil-like regolith breccia 65745,7 contains two zircon-bearing clasts. One of these clasts is a thermally annealed silica-rich rock, which mineralogically has affinities with the High Alkali Suite (Clast 1), and yields zircon dates ranging from 4.08 to 3.38 Ga. The other clast is a KREEP-rich impact melt breccia (Clast 2) and yields zircon dates ranging from 3.97 to 3.91 Ga. The crystalline cores of both grains, which yield dates of ca 3.9 Ga, have undergone shock pressure modification at less than 20 GPa. We interpret that the U-Pb chronometer in these zircon grains has been partially reset by the Imbrium basin-forming event when the clasts were incorporated into the Cayley Plains ejecta blanket deposit. The zircon grains in Clast 1 have been partially decomposed, resulting in a breakdown polymineralic texture, with elevated U, Pb and Th abundances compared with those in the crystalline zircon. These decomposed areas exhibit younger dates around 3.4 Ga, suggesting a secondary high-pressure, high-temperature event, probably caused by an impact in the local Apollo 16 highlands area. 
Type Of Material Database/Collection of data 
Year Produced 2020 
Provided To Others? Yes  
URL https://rs.figshare.com/articles/Electronic_Supplementary_Materials_-_Data_Tables_from_Timing_of_geo...
 
Title Electronic Supplementary Materials - Data Tables from Timing of geological events in the lunar highlands recorded in shocked zircon-bearing clasts from Apollo 16 
Description Apollo 16 soil-like regolith breccia 65745,7 contains two zircon-bearing clasts. One of these clasts is a thermally annealed silica-rich rock, which mineralogically has affinities with the High Alkali Suite (Clast 1), and yields zircon dates ranging from 4.08 to 3.38 Ga. The other clast is a KREEP-rich impact melt breccia (Clast 2) and yields zircon dates ranging from 3.97 to 3.91 Ga. The crystalline cores of both grains, which yield dates of ca 3.9 Ga, have undergone shock pressure modification at less than 20 GPa. We interpret that the U-Pb chronometer in these zircon grains has been partially reset by the Imbrium basin-forming event when the clasts were incorporated into the Cayley Plains ejecta blanket deposit. The zircon grains in Clast 1 have been partially decomposed, resulting in a breakdown polymineralic texture, with elevated U, Pb and Th abundances compared with those in the crystalline zircon. These decomposed areas exhibit younger dates around 3.4 Ga, suggesting a secondary high-pressure, high-temperature event, probably caused by an impact in the local Apollo 16 highlands area. 
Type Of Material Database/Collection of data 
Year Produced 2020 
Provided To Others? Yes  
URL https://rs.figshare.com/articles/Electronic_Supplementary_Materials_-_Data_Tables_from_Timing_of_geo...
 
Title H and Cl isotope raw data on GRA 06128 meteorite 
Description Raw H and Cl isotope data obtained on meteorite GRA 06128 
Type Of Material Database/Collection of data 
Year Produced 2019 
Provided To Others? Yes  
Impact Raw data accompanying paper published in Geochimica et Cosmochimica Acta 
URL https://data.mendeley.com/datasets/zt8hfv3vfr/1
 
Title Zircon and monazite U-Pb dating - Ries impact crater 
Description Raw LA-ICP-MS zircon and monazite data for samples from basement rocks of the Ries crater. The analytical method used, instrument set up, and data processing workflow are described in the published paper "U-Pb dating of zircon and monazite from the uplifted Variscan crystalline basement of the Ries impact crater" (doi: 10.1111/maps.13798). For each studied sample, this folder contains:- a .csv file with raw ICP-MS data- an .xml file with ICP-MS metadata- a LaserLog.csv with laser log file- a .lase file with laser metadata 
Type Of Material Database/Collection of data 
Year Produced 2022 
Provided To Others? Yes  
URL https://figshare.manchester.ac.uk/articles/dataset/Zircon_and_monazite_U-Pb_dating_-_Ries_impact_cra...
 
Title Zircon and monazite U-Pb dating - Ries impact crater 
Description Raw LA-ICP-MS zircon and monazite data for samples from basement rocks of the Ries crater. The analytical method used, instrument set up, and data processing workflow are described in the published paper "U-Pb dating of zircon and monazite from the uplifted Variscan crystalline basement of the Ries impact crater" (doi: 10.1111/maps.13798).For each studied sample, this folder contains:- a .csv file with raw ICP-MS data- an .xml file with ICP-MS metadata- a LaserLog.csv with laser log file- a .lase file with laser metadata 
Type Of Material Database/Collection of data 
Year Produced 2022 
Provided To Others? Yes  
Impact Research paper published (https://doi.org/10.1111/maps.13798). 
URL https://figshare.manchester.ac.uk/articles/dataset/Zircon_and_monazite_U-Pb_dating_-_Ries_impact_cra...
 
Description NASA ANGSA 
Organisation University of New Mexico
Country United States 
Sector Academic/University 
PI Contribution Collaborating of geochemical analysis of newly opened Apollo lunar samples.
Collaborator Contribution Leading campaign of new analyses on newly opened Apollo lunar samples.
Impact Abstract submitted and work presented by Sam Bell at the 2022 Lunar and Planetary Science Conference.
Start Year 2019
 
Description New Views of the Moon II 
Organisation University of Manchester
Country United Kingdom 
Sector Academic/University 
PI Contribution Co-authorship of two chapters for the New Views of the Moon II book initiative - published 2023.
Collaborator Contribution Collaborators on two chapters for the New Views of the Moon II book initiative - published 2023.
Impact Two chapters for the New Views of the Moon II book initiative - published 2023: 1) Lunar indigenous water - lead author F.M. McCubbin (NASA JSC, USA) 2) Lunar resources - lead author I. Crawford (Birkbeck, University of London)
Start Year 2018
 
Description Bluedot festival 
Form Of Engagement Activity Participation in an activity, workshop or similar
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Public/other audiences
Results and Impact Participated in public engagement event with the Earth and Solar System outreach group at Bluedot Festival that takes place in July at the Jodrell Bank Observatory in Chesire. Over the weekend we interact with more than 1500 members of the public, discussing planetary science research we undertake in Manchester.
Year(s) Of Engagement Activity 2017,2018
 
Description Royal Society Summer Science Exhibition 2019 
Form Of Engagement Activity Participation in an activity, workshop or similar
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Public/other audiences
Results and Impact Participated in the 'Living on the Moon' exhibit at the Royal Society Summer Science Exhibition 2019, which was an interactive experience illustrating progress in lunar science over the last 50 years since the Apollo 11 Moon landings. During this week-long event, we estimate that we have interacted with at least 6,000 people (based on stickers distributed) out of 12,000 visitors. Overall, 69.4% of the surveyed visitors either said that they Strongly Agreed or Agreed that they learnt something new about the Apollo missions and 88.7% Strongly Agreed or Agreed that they have a better understanding of how we may explore the Moon in the future. All but one of the surveyed visitors (98.4%) stated that they Strongly Agreed or Agreed that it is important that money is invested into scientific research. Of the surveyed visitors, 83.9% either Strongly Agreed or Agreed that it is important that the UK is at the forefront of lunar exploration and research, with only 14.5% being neutral to this statement and 90.3% either Strongly Agreed or Agreed that the Living on the Moon exhibit inspired them to find out more about lunar exploration and research, with just 9.7% being neutral and 1.6% disagreeing.
Year(s) Of Engagement Activity 2019
URL http://livingonthemoon.info/
 
Description Science @ Central event at Central Library Manchester 
Form Of Engagement Activity Participation in an activity, workshop or similar
Part Of Official Scheme? No
Geographic Reach Local
Primary Audience Public/other audiences
Results and Impact Participated in public engagement event with the Earth and Solar System outreach group at the Central Library in Manchester. Probably interacted with around a hundred members of the public, discussing planetary science research we undertake in Manchester.
Year(s) Of Engagement Activity 2017