Synthesis of a uranium(VI)-carbene: reductive formation of uranyl(V)-methanides, oxidative preparation of a [R2C-U-O]2+ analogue of the [O-U-O]2+ uranyl ion (R = Ph2PNSiMe3), and comparison of the nature of U(IV)-C, U(V)-C, and U(VI)-C double bonds. (2012)


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PubMed Identifier: 22621395

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Type: Journal Article/Review

Volume: 134

Parent Publication: Journal of the American Chemical Society

Issue: 24

ISSN: 0002-7863