High Temperature Superconductors for Fusion Technologies
Lead Research Organisation:
UNIVERSITY OF OXFORD
Department Name: Materials
Abstract
Nuclear fusion - the joining together of atomic nuclei of light elements such as hydrogen to form larger nuclei - is the process by which vast amounts of energy is produced in stars like our sun. If it can be harnessed on Earth it has the potential deliver a nearly unlimited and safe source of energy which does not produce the environmentally damaging CO2 emissions that are released by burning traditional fossil fuels. However, for nuclear fusion to occur, extremely high temperatures and pressures are required because positively charged atomic nuclei within a plasma have to collide with each other with sufficient energy to overcome the immensely strong electrostatic repulsion forces. To achieve nuclear fusion in a machine on Earth, extraordinarily high temperatures of around 150 million degrees Celsius are needed, about 10 times higher than the temperature of the sun's core. This precludes the use of traditional materials to confine the plasma, and in the most common type of fusion reactor called a tokamak, strong magnetic fields are used instead. Since the power density of a particular geometry of tokamak scales with the strength of the magnetic field to the power of four, there is a huge benefit to using higher field magnets for plasma confinement.
High temperature superconductors - materials that can conduct electricity without any resistance - are an enabling technology for a new generation of compact nuclear fusion reactors that are widely believed will open the door to commercialisation of fusion for energy generation. This is because state-of-the-art high temperature superconducting tapes can carry extremely high electrical currents, even when subjected to enormous magnetic fields that completely destroy superconductivity in the best low temperature superconductors. However, although high temperature superconducting materials with fantastic properties are now available in lengths up to about 1 km in the form of flexible tapes known as coated conductors, the materials are incredibly complex and sensitive to damage, making their practical deployment in magnets for fusion devices a major challenge.
This programme of research involves using a unique combination of advanced materials characterisation and modelling techniques to determine how high temperature superconductors will degrade in the harsh environment of a fusion reactor where they will be continually bombarded by high energy neutrons. The focus will be on understanding the underlying damage and recovery mechanisms in these complex functional ceramics under the most realistic conditions possible. Since in operation the superconductors will be irradiated by neutrons whilst in their superconducting state at cryogenic temperatures, innovative in situ experiments will be performed to understand the differences between room temperature and low temperature radiation damage. The experimental programme will be supported by first principles modelling of pristine and defect structures in the superconducting compounds, and the outcomes will be used to validate larger scale simulations of radiation damage as well as providing key data on degradation to feed into materials selection and magnet design decisions for the next generation of fusion magnets. The advanced characterisation methodologies developed in this fellowship will also be applied to understanding radiation damage in a wider range of fusion relevant materials.
High temperature superconductors - materials that can conduct electricity without any resistance - are an enabling technology for a new generation of compact nuclear fusion reactors that are widely believed will open the door to commercialisation of fusion for energy generation. This is because state-of-the-art high temperature superconducting tapes can carry extremely high electrical currents, even when subjected to enormous magnetic fields that completely destroy superconductivity in the best low temperature superconductors. However, although high temperature superconducting materials with fantastic properties are now available in lengths up to about 1 km in the form of flexible tapes known as coated conductors, the materials are incredibly complex and sensitive to damage, making their practical deployment in magnets for fusion devices a major challenge.
This programme of research involves using a unique combination of advanced materials characterisation and modelling techniques to determine how high temperature superconductors will degrade in the harsh environment of a fusion reactor where they will be continually bombarded by high energy neutrons. The focus will be on understanding the underlying damage and recovery mechanisms in these complex functional ceramics under the most realistic conditions possible. Since in operation the superconductors will be irradiated by neutrons whilst in their superconducting state at cryogenic temperatures, innovative in situ experiments will be performed to understand the differences between room temperature and low temperature radiation damage. The experimental programme will be supported by first principles modelling of pristine and defect structures in the superconducting compounds, and the outcomes will be used to validate larger scale simulations of radiation damage as well as providing key data on degradation to feed into materials selection and magnet design decisions for the next generation of fusion magnets. The advanced characterisation methodologies developed in this fellowship will also be applied to understanding radiation damage in a wider range of fusion relevant materials.
Publications

Adams K
(2023)
Comparing neutron and helium ion irradiation damage of REBa 2 Cu 3 O 7-d coated conductor using x-ray absorption spectroscopy
in Superconductor Science and Technology

Iliffe W
(2023)
The effect of in situ irradiation on the superconducting performance of REBa2Cu3O7-d-coated conductors
in MRS Bulletin

Iliffe W
(2024)
STEP's Plan for Understanding REBCO Coated Conductors in the Fusion Environment
in IEEE Transactions on Plasma Science

Iliffe W
(2023)
The effect of in situ irradiation on the superconducting performance of REBa2Cu3O7-d-coated conductors
in MRS Bulletin

Nicholls R
(2022)
Understanding irradiation damage in high-temperature superconductors for fusion reactors using high resolution X-ray absorption spectroscopy
in Communications Materials
Description | Hi-scale training school (Turkey) |
Geographic Reach | Europe |
Policy Influence Type | Influenced training of practitioners or researchers |
Impact | Unskilled graduate students in the field of superconductivity about materials. |
Description | Short course |
Geographic Reach | Multiple continents/international |
Policy Influence Type | Influenced training of practitioners or researchers |
Impact | Upskilled researchers on superconductivity in materials science of superconductors. |
Description | Superconductivity Summer School |
Geographic Reach | Multiple continents/international |
Policy Influence Type | Influenced training of practitioners or researchers |
Impact | This summer school trains new researchers in the field of applied superconductivity, mainly those carrying out higher degrees but also some individuals from an industry R&D setting. It usually runs every 2 years, and I have been involved since 2017. It attracts delegates from Europe and North America as well as the UK. In addition to introducing the fundamentals of this multidisciplinary field, the summer school focuses on applications of superconductors, from large scale magnets to thin film quantum devices. It is lectured by experts in the field and the feedback from delegates is always positive. |
Description | Superconductivity Summer School (Oxford) |
Geographic Reach | Multiple continents/international |
Policy Influence Type | Influenced training of practitioners or researchers |
Impact | Around 50 attendees from around the world, most of whom are graduate students working in the superconductivity field. |
Title | Comparing neutron and helium ion irradiation damage of REBa2Cu3O7-d coated conductor using X-ray absorption spectroscopy |
Description | Dataset accompanying publication entitled "Comparing neutron and helium ion irradiation damage of REBa2Cu3O7-d coated conductor using X-ray absorption spectroscopy" by Adams et al, Superconductor Science and Technology, accepted 06/08/23 |
Type Of Material | Database/Collection of data |
Year Produced | 2023 |
Provided To Others? | Yes |
URL | https://ora.ox.ac.uk/objects/uuid:ec050bc9-bc89-4d5f-bf20-2481d28f823a |
Title | Understanding irradiation damage in high-temperature superconductors for fusion reactors using high resolution X-ray absorption spectroscopy |
Description | XANES data was collected on the I20 beam line at Diamond Light Source. It has been normalised using the Athena software. STEM analysis was performed using the Atomap software followed by home-written python code. DFT calculations were performed with CASTEP and the spectra were calculated using OPTADOS. |
Type Of Material | Database/Collection of data |
Year Produced | 2022 |
Provided To Others? | Yes |
Impact | Publication Understanding irradiation damage in high-temperature superconductors for fusion reactors using high resolution X-ray absorption spectroscopy Nicholls, Rebecca J. ; Diaz-Moreno, Sofia ; Iliffe, William ; Linden, Yatir ; Mousavi, Tayebeh ; Aramini, Matteo ; Danaie, Mohsen ; Grovenor, Chris R. M. ; Speller, Susannah C. London: Nature Publishing Group Communications materials, 2022, Vol.3 (1), p.1-14 |
URL | https://deposit.ora.ox.ac.uk/concern/datasets/uuid_17527813-ab8d-4794-b54f-1a6d95bac08c?locale=en |
Description | Careers fair |
Form Of Engagement Activity | Participation in an activity, workshop or similar |
Part Of Official Scheme? | No |
Geographic Reach | Local |
Primary Audience | Schools |
Results and Impact | Stall at a school careers fair in Cambridge promoting Materials Science and science subjects at the University of Oxford. Increased awareness of Materials Science as a subject to study at University. |
Year(s) Of Engagement Activity | 2023 |
Description | Fusion Industry School |
Form Of Engagement Activity | Participation in an activity, workshop or similar |
Part Of Official Scheme? | No |
Geographic Reach | International |
Primary Audience | Industry/Business |
Results and Impact | The Fusion Industry School was initiated as an annual event in 2022. It runs over 2 weeks: one week in York and the second week in Oxford. I contributed a 90 minute lecture on "Magnets and Magnet Technologies". The delegates were mainly individuals in the fusion industry, and the lectures were intended to educate this diverse audience on the main challenges and science behind fusion technologies. The feedback from the first cohort was excellent (for the entire event, and the magnets lecture), with 100% of delegates saying they would recommend to colleagues, and the event will run again in 2023. |
Year(s) Of Engagement Activity | 2022,2023 |
Description | Invited talk at COGX festival (O2 arena London) |
Form Of Engagement Activity | A talk or presentation |
Part Of Official Scheme? | No |
Geographic Reach | National |
Primary Audience | Industry/Business |
Results and Impact | Invited talk on how superconductors can contribute towards net zero goals at the COGX deep tech festival. Available online (https://www.youtube.com/watch?v=MY2o7EEkxG4). |
Year(s) Of Engagement Activity | 2023 |
Description | Live radio interviews on LK99 |
Form Of Engagement Activity | A broadcast e.g. TV/radio/film/podcast (other than news/press) |
Part Of Official Scheme? | No |
Geographic Reach | International |
Primary Audience | Public/other audiences |
Results and Impact | Interviewed live on radio as an expert commenting on the LK99 story: Tom Swarbrick show, LBC, 27th July, 2023; The Agenda, Dubai Eye, 8th August, 2023 |
Year(s) Of Engagement Activity | 2023 |
Description | Media interviews on LK99 superconductor |
Form Of Engagement Activity | A press release, press conference or response to a media enquiry/interview |
Part Of Official Scheme? | No |
Geographic Reach | International |
Primary Audience | Public/other audiences |
Results and Impact | Interviewed by the following news outlets as an expert in superconducting materials when the LK99 room temperature superconductor claim was announced: New Scientist, The Times, Independent, inews, Scientific American, Phys.org, IFL science, The Straits Times |
Year(s) Of Engagement Activity | 2023 |
Description | Podcast on superconductors |
Form Of Engagement Activity | A broadcast e.g. TV/radio/film/podcast (other than news/press) |
Part Of Official Scheme? | No |
Geographic Reach | International |
Primary Audience | Public/other audiences |
Results and Impact | Podcast interview to raise awareness of the potential of superconducting materials towards net zero goals. It is available online (https://globalventuring.com/university/beyond-the-breakthrough-superconductors-net-zero/). |
Year(s) Of Engagement Activity | 2023 |
Description | Press release - opening of Active Materials Laboratory, DLS |
Form Of Engagement Activity | A press release, press conference or response to a media enquiry/interview |
Part Of Official Scheme? | No |
Geographic Reach | National |
Primary Audience | Public/other audiences |
Results and Impact | I was interviewed as the first user of the Active Materials Laboratory at Diamond Light Source. The opening was reported on local radio (Jack FM), was reported in the local press and was featured in Feb 23 issue of "Materials World" (https://www.iom3.org/resource/activating-research.html). This highlighted my recent research on radiation damage of superconductors. |
Year(s) Of Engagement Activity | 2023 |
Description | Public Lecture |
Form Of Engagement Activity | A talk or presentation |
Part Of Official Scheme? | No |
Geographic Reach | International |
Primary Audience | Public/other audiences |
Results and Impact | Public lecture entitled "Can superconductors help to save the planet" and book launch. This was a public facing event associated with the IOP/Oxford Instruments Superconductivity Summer School 2022, Wolfson College, Oxford. The event was both in-person, live-streamed and recorded (https://www.youtube.com/watch?v=BkFWic9gv8w) and attracted delegates from the international summer school, representatives from the superconductivity industry, school students and the general public. The event was followed by the launch of my new book for a general audience "A Materials Science Guide to Superconductors: and how to make them super", at which 30-40 books were sold. Refreshments were served during the book launch and there was a lot of discussion between the summer school delegates and members of the public. |
Year(s) Of Engagement Activity | 2022 |
Description | STEM learning advisory board |
Form Of Engagement Activity | A formal working group, expert panel or dialogue |
Part Of Official Scheme? | No |
Geographic Reach | National |
Primary Audience | Policymakers/politicians |
Results and Impact | Science Advisory Board Member for STEM learning, an organisation that provides CPD training for schools in STEM subjects. The advisory board oversees the activities of STEM learning, providing steer for future engagements/CPD offerings, and evaluating their work. This work provides a channel for influencing and engaging with school-level science curriculum and delivery, which is crucial for widening participation in STEM at higher level. |
Year(s) Of Engagement Activity | 2022,2023 |
Description | School Chemistry teachers "Solutions in Situ" event - CPD for teachers |
Form Of Engagement Activity | A talk or presentation |
Part Of Official Scheme? | No |
Geographic Reach | Local |
Primary Audience | Schools |
Results and Impact | Gave a talk at the inaugural "Solutions in Situ" event hosted by Wychwood School. This is an initiative for local school chemistry teachers to come together and discuss best practice and hear about new research (CPD). It has led to several school visits to my department, plus me visiting schools to talk to students. |
Year(s) Of Engagement Activity | 2023 |
Description | School visit (Cambridge) |
Form Of Engagement Activity | A talk or presentation |
Part Of Official Scheme? | No |
Geographic Reach | National |
Primary Audience | Schools |
Results and Impact | I ran a lunchtime session with superconductivity demos for KS3 students and an after school session with sixth form science students |
Year(s) Of Engagement Activity | 2023 |
Description | School visits |
Form Of Engagement Activity | Participation in an open day or visit at my research institution |
Part Of Official Scheme? | No |
Geographic Reach | National |
Primary Audience | Schools |
Results and Impact | Taster lectures, demos, lab tours in the Department of Materials and at St Catherine's college for a range of events including: university open days, Headstart/UNIQ courses, Women in Science days, other school visits. Main impact is to enthuse school students in science and inspire them to consider STEM careers, particularly those from under-represented groups. |
Year(s) Of Engagement Activity | 2020,2021,2022,2023 |
Description | Schools talk (Oxford) |
Form Of Engagement Activity | A talk or presentation |
Part Of Official Scheme? | No |
Geographic Reach | Local |
Primary Audience | Schools |
Results and Impact | Schools talk for the Quantum Society at Stowe School, with attendance from local partnership schools. Included in depth discussion with students interested in applying to study Materials Science. |
Year(s) Of Engagement Activity | 2024 |
Description | Schools talks (Oxfordshire) |
Form Of Engagement Activity | A talk or presentation |
Part Of Official Scheme? | No |
Geographic Reach | Regional |
Primary Audience | Schools |
Results and Impact | Talk on "Can superconductors help us save the planet" at Radley College with attendance of >100 including from local state partnership schools and local independent Girls' school. Lively discussion after the event and interest in attending Materials Science University open days. |
Year(s) Of Engagement Activity | 2023 |