Observation and control of ultrafast surface photochemistry
Lead Research Organisation:
University College London
Department Name: Chemistry
Abstract
The ultimate goal of any branch of Chemistry, including surface Chemistry, is to understand reactions at a fundamental level. In order to achieve this, it is necessary to both observe the reaction on an atomic length scale, and also to monitor the reaction on the same time scale as bond breaking and making - the femtosecond timescale (1 fs = 10-15 s). With the advent of scanning probe microscopy, the observation of surface reactions at the atomic length scale has become almost routine. However, observing the dynamics of surface reactions with femtosecond accuracy still remains a considerable challenge. This proposal will address this issue. It aims to establish the foundations for understanding the detailed dynamics of surface processes, by using state-of-the-art femtosecond pump-probe techniques to monitor reactions in real time. It will also investigate the possibility, long discussed theoretically but not yet achieved experimentally, of using shaped femtosecond laser pulses to control surface photochemistry. If this control technique is successful it will have a huge impact and will contribute greatly to our understanding of surface reaction processes. The programme of research will be made possible by bringing together two independent well-established research groups within the UCL Chemistry department to form a unique team with the necessary experimental expertise in both surface science and ultrafast laser technology.
Organisations
Publications
Wilson E
(2010)
Low Pressure RAIRS Studies of Model Catalytic Systems
in The Journal of Physical Chemistry C
Payne D
(2016)
Coverage-dependent two-photon photoexcitation at the H2O/TiO2 interface
in Surface Science
Butorac J
(2016)
A RAIRS, TPD and femtosecond laser-induced desorption study of CO, NO and coadsorbed CO + NO on Pd(111)
in RSC Advances
Payne DT
(2017)
Creating Excess Electrons at the Anatase TiO2(101) Surface.
in Topics in catalysis
Zhang Y
(2019)
State-Selective Dynamics of TiO2 Charge-Carrier Trapping and Recombination.
in The journal of physical chemistry letters
Hussain H
(2019)
Water-Induced Reversal of the TiO2(011)-(2 × 1) Surface Reconstruction: Observed with in Situ Surface X-ray Diffraction.
in The journal of physical chemistry. C, Nanomaterials and interfaces
Tanner AJ
(2021)
Chemical Modification of Polaronic States in Anatase TiO2(101).
in The journal of physical chemistry. C, Nanomaterials and interfaces
Description | We have used ultra-fast spectroscopy to investigate catalytic reactions of relevance to the car exhaust catalyst |
Exploitation Route | Further experiments can be undertaken. The findings shed light on CO/NO catalytic processes |
Sectors | Chemicals,Education,Energy |