MULTI-DIMENSIONAL NONLINEAR OPTICAL METALLOCHROMOPHORES
Lead Research Organisation:
University of Manchester
Department Name: Chemistry
Abstract
The inbuilt limitations of current semiconductor-based electronics in terms of speed, scale and mode of operation have inspired much research in the areas of molecular electronics and photonics. Within this broad scientific field, nonlinear optical (NLO) materials are especially interesting. NLO effects allow the manipulation of laser light beams and can therefore be used in electro-optical data processing, and also revolutionary all-optical technologies. We propose to use directed synthetic chemistry to prepare a range of new strongly coloured molecular salts designed to show very large NLO effects. The active molecules in these salts have 2D or 3D shapes and contain complexed metal ions such as iron or ruthenium which introduce extra potentially useful features. Adding or removing electrons (and/or protons in some cases) will allow us to reversibly control the optical properties of the dyes we prepare. The project will involve collaborative studies with a number of leading research groups in Europe, Australia and the USA, allowing us to both measure and understand by computer modelling the optical properties. Our work is driven primarily by scientific curiosity, but the long-term goal is to create new materials which may be useful in future optical data processing devices.Keywords describing areas of proposal: Synthetic Chemistry, Coordination Chemistry, Nonlinear Optics, Stark Spectroscopy
Organisations
People |
ORCID iD |
Benjamin Coe (Principal Investigator) |
Publications
Coe B
(2011)
Ferrocenyl Diquat Derivatives: Nonlinear Optical Activity, Multiple Redox States, and Unusual Reactivity
in Organometallics
Coe B
(2009)
The syntheses, structures and nonlinear optical and related properties of salts with julolidinyl electron donor groups
in Dyes and Pigments
Coe B
(2009)
Syntheses and Properties of Salts of Chromophores with Ferrocenyl Electron Donor Groups and Quaternary Nitrogen Acceptors
in Organometallics
Coe B
(2010)
Two-Dimensional, Pyrazine-Based Nonlinear Optical Chromophores with Ruthenium(II) Ammine Electron Donors
in Inorganic Chemistry
Coe B
(2010)
Quadratic and Cubic Nonlinear Optical Properties of Salts of Diquat-Based Chromophores with Diphenylamino Substituents
in The Journal of Physical Chemistry A
Coe B
(2010)
Diquat Derivatives: Highly Active, Two-Dimensional Nonlinear Optical Chromophores with Potential Redox Switchability
in Journal of the American Chemical Society
Coe BJ
(2010)
Combining very large quadratic and cubic nonlinear optical responses in extended, tris-chelate metallochromophores with six pi-conjugated pyridinium substituents.
in Journal of the American Chemical Society
Coe BJ
(2010)
Evolution of linear absorption and nonlinear optical properties in V-shaped ruthenium(II)-based chromophores.
in Journal of the American Chemical Society
Coe BJ
(2009)
Nonlinear optical and related properties of iron(II) pentacyanide complexes with quaternary nitrogen electron acceptor units.
in Inorganic chemistry
Coe BJ
(2010)
Syntheses and properties of two-dimensional, dicationic nonlinear optical chromophores based on pyrazinyl cores.
in The Journal of organic chemistry
Coe BJ
(2016)
Helquat Dyes: Helicene-like Push-Pull Systems with Large Second-Order Nonlinear Optical Responses.
in The Journal of organic chemistry
Coe BJ
(2013)
Heptametallic, octupolar nonlinear optical chromophores with six ferrocenyl substituents.
in Chemistry (Weinheim an der Bergstrasse, Germany)