Solid-state NMR Research Service for UK Universities
Lead Research Organisation:
Durham University
Department Name: Chemistry
Abstract
Solid-state NMR is an important technique for characterising and studying solid materials whether they are homogeneous or heterogeneous, crystalline or amorphous. It can be applied across a wide-range of chemistry including novel organic, inorganic, organometallic and hybrid compounds, polymers (both natural and synthetic), fuels, pharmaceutical and excipients, composites, ceramics, catalysts, liquid crystals and biologically-based systems. This proposal is for a solid-state nuclear magnetic resonance (NMR) research service. The service will be available to members of the UK academic community and will based around a new state-of-the-art 400 MHz spectrometer. It will build upon the well-established and highly-experienced service currently running at Durham. The service will offer experiment planning and interpretation, in addition to providing high-quality spectra. It will promote the application of solid-state NMR to chemical problems and will act as a centre for practical training in solid-state NMR methodology. The EPSRC service will run in parallel to a commercial service supporting the research and development needs of industry. The case for support describes how the service will be structured, how it will operate and how much instrument time will be available to its users. It is proposed that the Service will operate for a period of five years to permit a major equipment upgrade to be carried out and its impact evaluated.
Organisations
Publications
Baraka A
(2007)
Preparation and characterization of melamine-formaldehyde-DTPA chelating resin and its use as an adsorbent for heavy metals removal from wastewater
in Reactive and Functional Polymers
Al-Yasari A
(2009)
Preparation of high-oxygen-content apatite silicates through Ti-doping: effect of Ti-doping on the oxide ion conductivity
in Journal of Materials Chemistry
Castro M
(2009)
Silicoaluminophosphate Molecular Sieves STA-7 and STA-14 and Their Structure-Dependent Catalytic Performance in the Conversion of Methanol to Olefins
in The Journal of Physical Chemistry C
Senthilkumar S
(2007)
Size-selective voltammetry: modification of the interface between two immiscible electrolyte solutions by zeolite Y.
in Langmuir : the ACS journal of surfaces and colloids
Apperley DC
(2010)
Speciation of chloroindate(III) ionic liquids.
in Dalton transactions (Cambridge, England : 2003)
Kleeberg C
(2012)
Spectroscopic and structural characterization of the CyNHC adduct of B2pin2 in solution and in the solid state.
in The Journal of organic chemistry
Zencirci N
(2009)
Structural Features, Phase Relationships and Transformation Behavior of the Polymorphs I-VI of Phenobarbital
in Crystal Growth & Design
Attfield M
(2010)
Structural Variety within Gallium Diphosphonates Affected by the Organic Linker Length
in Inorganic Chemistry
Coles MP
(2009)
Superbasicity of a bis-guanidino compound with a flexible linker: a theoretical and experimental study.
in Journal of the American Chemical Society
Robinson M
(2009)
Synthesis and catalytic activity of nanoporous aluminosilicate materials
in Journal of Molecular Catalysis A: Chemical
Haque S
(2007)
Synthesis and Characterization of Grafted Nanohydroxyapatites Using Functionalized Surface Agents
in Langmuir
Shin JF
(2012)
Synthesis and characterization of proton conducting oxyanion doped Ba2Sc2O5.
in Dalton transactions (Cambridge, England : 2003)
Sandoval M
(2009)
Synthesis and characterization of zeotype ANA framework by hydrothermal reaction of natural clinker
in Fuel
Percival J
(2008)
Synthesis and structural characterisation of the Li ion conducting garnet-related systems, Li6ALa2Nb2O12 (A=Ca, Sr)
in Solid State Ionics
Robinson M
(2010)
Synthesis of nanoporous aluminosilicate materials and their application as highly selective heterogeneous catalysts for the synthesis of ß-amino alcohols
in Journal of Molecular Catalysis A: Chemical
Copping R
(2008)
Tetravalent metal complexation by Keggin and lacunary phosphomolybdate anions.
in Inorganic chemistry
Craythorne SJ
(2009)
The co-entrapment of a homogeneous catalyst and an ionic liquid by a sol-gel method: recyclable ionogel hydrogenation catalysts.
in Chemistry (Weinheim an der Bergstrasse, Germany)
Brigden C
(2007)
The synthesis and characterization of Al-Beta and all-silica Beta formed in fluoride and caustic media
in Microporous and Mesoporous Materials
Vile J
(2011)
Tribenzotriquinacene-based polymers of intrinsic microporosity
in Polymer Chemistry
White RJ
(2009)
Tuneable porous carbonaceous materials from renewable resources.
in Chemical Society reviews
Jones M
(2009)
Zinc(II) Homogeneous and Heterogeneous Species and Their Application for the Ring-Opening Polymerisation of rac -Lactide
in European Journal of Inorganic Chemistry
Di Iulio C
(2010)
Zinc(II) silsesquioxane complexes and their application for the ring-opening polymerization of rac-lactide.
in Inorganic chemistry
Description | The Solid-State NMR service provided NMR spectra and interpretation services for users without ready access to this important, but relatively expensive, analytical technique for analysing solid materials. This work fed into a large number of papers (74 listed here) over the period. Aided by the baseline EPSRC funding, the Service ran a busy commercial operation over the funding period, supplying services to 10-15 companies per year in, for example, the petrochemical, pharmaceutical, agrichemical, polymer and defence industries. |
Exploitation Route | This is best addressed by individual users of the Service. We have indicated below the areas in which the Service had a significant impact. |
Sectors | Agriculture Food and Drink Chemicals Healthcare Manufacturing including Industrial Biotechology Pharmaceuticals and Medical Biotechnology |
Description | EPSRC |
Amount | £668,649 (GBP) |
Funding ID | Contract 01SSN01112011 |
Organisation | Engineering and Physical Sciences Research Council (EPSRC) |
Sector | Public |
Country | United Kingdom |
Start | 11/2011 |
End | 10/2016 |