Control of Electrons by Few-Cycle Intense Laser Pulses
Lead Research Organisation:
Imperial College London
Department Name: Physics
Abstract
Intense, phase-stabilised, femtosecond laser pulses comprising only a few optical cycles ( few-cycle pulses) offer a unique new tool for the manipulation of electrons in matter The strong oscillating electric field of the pulse moves valence electrons in quasi-classical trajectories, but the interaction on the sub optical-cycle timescale is too brief for nuclear motion to occur. Thus the motion of the electrons in small quantum systems (e.g. atoms, molecules, clusters, surfaces, nanosystems) can be controlled whilst the nuclei are fixed in position. This proposal outlines an in-depth programme of research in this rapidly emerging area.The breakthrough of intense carrier envelope phase-stabilised (CEP stabilised), few-cycle pulses provides precisely defined strong electric field optical waveforms. These fully controlled few-cycle pulses permit, for the first time, the control of strongly driven electron motion down to the quantum limit with sub-optical period (< 1 fs) temporal resolution and near atomic scale (~10^-10m) spatial resolution. It is now possible to implement a new type of coherent control of strong field electron processes that are inherently sensitive to the CEP. It is important to stress that it is the electric field waveform, rather than the pulse intensity envelope , that is harnessed to control the system. Control of electrons is provided by these fields at the natural spatial and temporal scales relevant to electronic states in matter (i.e. < 10^-10m and < 10^-15s) - this opens up exciting new possibilities in quantum control. The control we will exercise isolates electron motion from the ion (nuclear) motion, the latter being effectively frozen on the timescale of the pulse duration. Thus the control of quasi-classical electron states within otherwise unaltered material will be feasible.This proposal concerns the development of these new optical techniques and their application to the investigation and control of electron processes in matter. The timeliness of this proposal is underlined by the growing interest in this field internationally with major efforts starting up, for instance in Sweden (Lund), France (Saclay), USA (Boulder, Berkeley, Ohio) and most notably in Germany (MPG-MPQ, Garching). The motivation for all these projects is the prospect of achieving the highest degree of quantum control in matter that can lead to new breakthroughs in chemical, material and optical sciences. Our project objectives include demonstration of selective bond cleaving via controlled electron recollision, optimisation of brightness and minimisation of pulse duration in coherent XUV and incoherent hard X-ray light sources, creation of spin entangled electronic states via ionisation of two-electron systems and development of compact detectors for laser phase.
Organisations
Publications
Raz O
(2011)
Vectorial phase retrieval for linear characterization of attosecond pulses.
in Physical review letters
Petrovic VS
(2012)
Transient X-ray fragmentation: probing a prototypical photoinduced ring opening.
in Physical review letters
Brugnera L
(2011)
Trajectory selection in high harmonic generation by controlling the phase between orthogonal two-color fields.
in Physical review letters
Okell W
(2015)
Temporal broadening of attosecond photoelectron wavepackets from solid surfaces
in Optica
Witting T
(2012)
Sub-4-fs laser pulse characterization by spatially resolved spectral shearing interferometry and attosecond streaking
in Journal of Physics B: Atomic, Molecular and Optical Physics
Maimaris M
(2022)
Sub-10-fs observation of bound exciton formation in organic optoelectronic devices.
in Nature communications
Hutchison C
(2012)
Stable generation of high-order harmonics of femtosecond laser radiation from laser produced plasma plumes at 1 kHz pulse repetition rate.
in Optics letters
Ganeev R
(2014)
Spatial coherence measurements of non-resonant and resonant high harmonics generated in laser ablation plumes
in Applied Physics Letters
Torres R
(2010)
Revealing molecular structure and dynamics through high-order harmonic generation driven by mid-IR fields
in Physical Review A
Skopalová E
(2010)
Pulse-length dependence of the anisotropy of laser-driven cluster explosions: transition to the impulsive regime for pulses approaching the few-cycle limit.
in Physical review letters
Henkel J
(2013)
Prediction of attosecond light pulses in the VUV range in a high-order-harmonic-generation regime
in Physical Review A
Haessler S
(2014)
Optimization of Quantum Trajectories Driven by Strong-Field Waveforms
in Physical Review X
Haessler S
(2014)
Optimization of Quantum Trajectories Driven by Strong-Field Waveforms
Haessler S
(2014)
Optimization of Quantum Trajectories Driven by Strong-Field Waveforms
Haessler S
(2013)
Optimisation of Quantum Trajectories Driven by Strong-field Waveforms
Skopalová E
(2011)
Numerical simulation of attosecond nanoplasmonic streaking
in New Journal of Physics
Zaïr A
(2013)
Molecular internal dynamics studied by quantum path interferences in high order harmonic generation
in Chemical Physics
Austin DR
(2011)
Lateral shearing interferometry of high-harmonic wavefronts.
in Optics letters
Ganeev RA
(2012)
Isolated sub-fs XUV pulse generation in Mn plasma ablation.
in Optics express
Chipperfield LE
(2009)
Ideal waveform to generate the maximum possible electron recollision energy for any given oscillation period.
in Physical review letters
Ganeev R
(2012)
High-order harmonic generation in graphite plasma plumes using ultrashort laser pulses: a systematic analysis of harmonic radiation and plasma conditions
in Journal of Physics B: Atomic, Molecular and Optical Physics
Ganeev R
(2012)
High-order harmonic generation in fullerenes using few- and multi-cycle pulses of different wavelengths
in Journal of the Optical Society of America B
Ganeev R
(2011)
High-order harmonic generation from metal plasmas using 1 kHz laser pulses
in Journal of Modern Optics
Vozzi C
(2010)
High harmonic generation spectroscopy of hydrocarbons
in Applied Physics Letters
Description | New understanding of how multiple colour fields can be used to control strong laser fielod processes like HHG were obtained. In particular we demonstrated theoretically and experimentally the improvements to harmonic spectral range and efficiency of using a multi-colour field. Further we demonstrated how the quantum trajectory is controlled in a 2-colour field (omega/2omega). Other important outcomes were in generation of few cycle pulses and in HHG spectroscopy for making sub-cycle measurements of molecular cation dynamics. |
Exploitation Route | Potential that techniques may be used in bioimaging or in energy research. Publication via usual journals and presentation at conferences, but no immediate non-academic impacts were found. |
Sectors | Chemicals,Energy,Pharmaceuticals and Medical Biotechnology |
URL | http://www3.imperial.ac.uk/quantumopticslaserscience/research/laser_consortium |
Description | This research has led to widely cited results. |