Microwave-Induced Nanoscale Convection, Polarisation, and Thermal Effects Leading to Innovative Analytical Technology
Lead Research Organisation:
University of Bath
Department Name: Chemistry
Abstract
Our project hypothesis is that extremely energetic microwave-driven convection and heating are possible for both inlaid-disk nanoelectrodes and nanoparticles immersed in solution and that massive improvements in electroanalytical processes can be achieved with these microwave effects. These phenomena (temperature, mass transport) can be directly measured and quantified in electrochemical experiments employing nanoelectrodes. At very small electrodes turbulence can be suppressed and unusually fast convective flow can be achieved (driven by microwave induced thermal gradients) giving high currents and beneficial effects e.g. kinetic resolution in analytical applications (sulphide, thiol, arsenite, oxygen, carbon dioxide, etc.). More importantly, the adsorption of microwaves into the double layer of interfaces with sufficiently fast RC time constant (e.g. at nanoelectrodes) has never been reported and may again lead to novel chemical phenomena (e.g. for processes involving H2, CO2, or CO adsorbates on Pt, Pd, or Au). These kinds of processes (which occur only at nanoelectrodes or nanoparticles) could be important for sensor and fuel cell processes.
Organisations
People |
ORCID iD |
Frank Marken (Principal Investigator) |
Publications
Cabello G
(2016)
In situ microwave-enhanced electrochemical reactions at stainless steel: Nano-iron for aqueous pollutant degradation
in Electrochemistry Communications
Dale S
(2012)
Microwave Activation of Electrochemical Processes in Ionic Liquid Impregnated Ionomer Spheres
in Electroanalysis
Halls J
(2012)
Nano-TiO2-flavin adenine dinucleotide film redox processes in contact to humidified gas | salt electrolyte
in Bioelectrochemistry
Dale S
(2011)
Salt matrix voltammetry: Microphase redox processes at ammonium chloride | gold | gas triple phase boundaries
in Electrochemistry Communications
Rassaei L
(2010)
Microwave-electrochemical formation of colloidal zinc oxide at fluorine doped tin oxide electrodes
in Electrochimica Acta
Ferancová A
(2010)
dsDNA modified carbon nanofiber-solidified paste electrodes: probing Ni(II)-dsDNA interactions
in Microchimica Acta
Cheng N
(2010)
One-step growth of 3-5nm diameter palladium electrocatalyst in a carbon nanoparticle-chitosan host and characterization for formic acid oxidation
in Electrochimica Acta
Rassaei L
(2010)
Discharge cavitation during microwave electrochemistry at micrometre-sized electrodes.
in Chemical communications (Cambridge, England)
Rassaei L
(2009)
Focusing microwaves at electrodes A review: localised microwave effects at electrochemical sensors
in Chimica Oggi-Chemistry Today
Rassaei L
(2009)
Effects of microwave radiation on electrodeposition processes at tin-doped indium oxide (ITO) electrodes
in Electrochimica Acta
Rassaei L
(2009)
Microwave-enhanced electroanalytical processes: generator-collector voltammetry at paired gold electrode junctions.
in The Analyst
Cutress I
(2009)
Microwave-Assisted Electroanalysis: A Review
in Electroanalysis
Rassaei L
(2009)
Microwave-Enhanced Electrochemistry in Locally Superheated Aqueous-Glycerol Electrolyte Media
in The Journal of Physical Chemistry C
Marken F
(2008)
Chemical and electro-chemical applications of in situ microwave heating
in Annual Reports Section "C" (Physical Chemistry)
Description | We were able to focus microwave energy into a very small spot adjacent to the electrode into the solution phase. This provides a completely new mechanism of microwave enhancement where extreme conditions are generated not at the electrode surface, but just a small distance away in the solution. We discovered that for very small "nano-electodes" the extreme conditions reached levels that plasma, arching, and discharge occurred, which ultimately damaged the sensor electrodes. For micro-electrodes the extreme conditions created super-heating and extreme mass transport. These are unusual conditions and we still explore potential applications, for example in "flash-synthesis" of metal nanoparticles at micro-steel electrodes. |
Exploitation Route | Creating extreme conditions in a small volume does not directly link to traditional microwave technology fields, but in analysis and in micro-fluidics, this should trigger new technologies (e.g. in fast digestion or heat shock conversion). The type of measurements we started during this project are now performed also by researchers in China and further developments may be possible. |
Sectors | Environment,Healthcare |
Description | Researchers in China have continued using our methodology. Collaborators in Brazil have recently started exploring microwave activation in corrosion and other electrochemical processes. Discussion with industry has so far not developed into follow-up non-academic developments. |
First Year Of Impact | 2010 |
Sector | Environment,Healthcare |
Impact Types | Societal |