DIAMOND: Decommissioning, Immobilisation And Management Of Nuclear wastes for Disposal
Lead Research Organisation:
University of Leeds
Department Name: Inst of Particle Science & Engineering
Abstract
Legacy waste treatment and disposal, as well as decommissioning and site remediation, from the last 60 years of the UK's civil nuclear program are conservatively estimated at a cost of 70B for the UK taxpayer. The diversity of issues that must be addressed in tackling this problem is immense and requires a wide range of innovative solutions drawn from an equally wide range of technology discipline areas. The proposed research program is divided into three work packages (WPs): (1) Environment, Migration and Risk; (2) Decommissioning, the Historic Legacy and Site Termination; and (3) Materials - Design, Development and Performance.WP 1: Environment, Migration and RiskCleaning up contaminated land is a substantial component of nuclear site restoration. The range of radioactive contaminants present, and the potential for mixed contamination, represents a major challenge. In particular, the potential for migration of soluble and colloidal species in the subsurface is a key uncertainty in defining site end points. Currently, most cleanup is expected to be through invasive technologies; hence, we will explore more cost-effective in situ technologies such as barrier treatment systems. Many of the uncertainties and technical challenges associated with geological disposal of immobilised radioactive wastes are critically dependent on the rate of release from the engineered facility, and on the subsequent behaviour of the radionuclides in the disturbed zone and the far field. Work Package 2: Decommissioning, the Historic Legacy and Site TerminationHeterogeneous wastes present in fuel storage and handling facilities are a key target of the consortium. These wastes comprise irradiated fuel, contaminated materials and corrosion products. Total volumes and compositions (both chemical and radioactive) are poorly known, although there are believed to be several hundred m3 in each of the main storage ponds. Improved and accurate characterisation is therefore a priority, and novel technologies for retrieval and treatment are proposed here. In addition, historical activities have created small volumes of orphan wastes for which no clear management route exists; their diversity requires new and versatile treatment methods which will be developed in this programme. We also focus on the quantification of radionuclide inventories, contaminant transport through engineered pathways and waste retrieval as areas where we can make a further contribution.Work Package 3: Materials- Design, Development and PerformanceGeological disposal has been accepted by Government as the best available approach for the long term management of UK radioactive wastes, supported by a robust programme of interim storage . The focus of research in this WP is therefore to address key knowledge gaps in the conditioning, storage and disposal of wastes in order to underpin future decision making in waste management. Research is based on three key themes, aimed at: 1) understanding the effects of radiation and radiolysis on the stability of nuclear ceramics during interim storage; 2) understanding the corrosion mechanisms of spent nuclear fuels, steel packaging and HLW glasses under conditions of storage and disposal; 3) development of new materials and processing routes with the flexibility to immobilise a spectrum of wastes, including fuel debris and graphite, in a form suitable for storage and disposal. A further aspect of this WP will be development of new synthetic routes to advanced inert matrix fuels.
Organisations
Publications
Davoisne C
(2010)
Advances in Materials Science for Environmental and Nuclear Technology
Giovanni B
(2011)
Trends in Colloid and Interface Science XXIV
May CC
(2012)
The effect of EDTA on the groundwater transport of thorium through sand.
in Water research
Rice HP
(2014)
Measuring particle concentration in multiphase pipe flow using acoustic backscatter: generalization of the dual-frequency inversion method.
in The Journal of the Acoustical Society of America
Conroy DJ
(2010)
Biosensing for the environment and defence: aqueous uranyl detection using bacterial surface layer proteins.
in Sensors (Basel, Switzerland)
Mulroue J
(2011)
An ab initio study of the effect of charge localization on oxygen defect formation and migration energies in magnesium oxide
in Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences
Mulroue J
(2011)
Ab initio study of intrinsic defects in zirconolite
in Physical Review B
Duffy D
(2012)
Modelling the effects of electronic excitations in ionic-covalent materials
in Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms
Hyatt N
(2011)
Diamond: A New Research Programme to Support UK Decommissioning, Immobilisation and Management of Nuclear Wastes for Disposal
in MRS Proceedings
Stennett M
(2012)
Rapid microwave synthesis of Pb 5 (VO 4 ) 3 X (X = F, Cl, Br and I) vanadinite apatites for the immobilisation of halide radioisotopes.
in MRS Proceedings
Gilbert M
(2011)
Krypton and Helium Irradiation Damage in Yttria-stabilised Zirconia
in MRS Proceedings
Hunter T
(2011)
Ultrasonic velocimetry for the in situ characterisation of particulate settling and sedimentation
in Minerals Engineering
Hunter T
(2012)
An acoustic backscatter system for in situ concentration profiling of settling flocculated dispersions
in Minerals Engineering
Ohe T
(2018)
Adsorption and diffusion of strontium in simulated rock fractures quantified via ion beam analysis
in Mineralogical Magazine
Hallam R
(2018)
Sorption of Tc(IV) to some geological materials with reference to radioactive waste disposal
in Mineralogical Magazine
Van Veelen A
(2018)
Uranium uptake onto Magnox sludge minerals studied using EXAFS
in Mineralogical Magazine
Stockdale A
(2018)
Uranyl binding to humic acid under conditions relevant to cementitious geological disposal of radioactive wastes
in Mineralogical Magazine
Ojovan M
(2010)
Glassy Wasteforms for Nuclear Waste Immobilization
in Metallurgical and Materials Transactions A
Dragosavac MM
(2012)
Production of porous silica microparticles by membrane emulsification.
in Langmuir : the ACS journal of surfaces and colloids
Schmidt R
(2012)
Effects of sintering temperature on the internal barrier layer capacitor (IBLC) structure in CaCu3Ti4O12 (CCTO) ceramics
in Journal of the European Ceramic Society
Kuenzel C
(2013)
Production of nepheline/quartz ceramics from geopolymer mortars
in Journal of the European Ceramic Society
Hill GL
(2011)
High-pressure and -temperature ion exchange of aluminosilicate and gallosilicate natrolite.
in Journal of the American Chemical Society
Protchenko AV
(2012)
A stable two-coordinate acyclic silylene.
in Journal of the American Chemical Society
Saleh L
(2011)
Group 3 and Lanthanide Boryl Compounds: Syntheses, Structures, and Bonding Analyses of Sc-B, Y-B, and Lu-B s-Coordinated NHC Analogues
in Journal of the American Chemical Society
Kuenzel C
(2012)
Ambient Temperature Drying Shrinkage and Cracking in Metakaolin-Based Geopolymers
in Journal of the American Ceramic Society
Zhang T
(2012)
Magnesium-silicate-hydrate cements for encapsulating problematic aluminium containing wastes
in Journal of Sustainable Cement-Based Materials
Reid D
(2012)
The fluorite related modulated structures of the Gd2(Zr2-xCex)O7 solid solution: An analogue for Pu disposition
in Journal of Solid State Chemistry
Giddings A
(2011)
Synthesis, structure and characterisation of the n=4 Aurivillius phase Bi5Ti3CrO15
in Journal of Solid State Chemistry
Mulroue J
(2013)
Charge localization on the hexa-interstitial cluster in MgO.
in Journal of physics. Condensed matter : an Institute of Physics journal
Davoisne C
(2011)
Krypton irradiation damage in Nd-doped zirconolite and perovskite
in Journal of Nuclear Materials
Heath P
(2013)
Encapsulation of TRISO particle fuel in durable soda-lime-silicate glasses
in Journal of Nuclear Materials
Kuenzel C
(2015)
Encapsulation of Cs/Sr contaminated clinoptilolite in geopolymers produced from metakaolin
in Journal of Nuclear Materials
Mulroue J
(2013)
Trapping of He in intrinsic defects in zirconolite
in Journal of Nuclear Materials
Stennett M
(2011)
Rapid synthesis of Pb5(VO4)3I, for the immobilisation of iodine radioisotopes, by microwave dielectric heating
in Journal of Nuclear Materials
Gilbert M
(2011)
Krypton and helium irradiation damage in neodymium-zirconolite
in Journal of Nuclear Materials
Phillips J
(2011)
Anion capture with calcium, aluminium and iron containing layered double hydroxides
in Journal of Nuclear Materials
Godinho J
(2011)
Sintering of CaF2 pellets as nuclear fuel analog for surface stability experiments
in Journal of Nuclear Materials
Rose P
(2011)
Crystallisation of a simulated borosilicate high-level waste glass produced on a full-scale vitrification line
in Journal of Non-Crystalline Solids
Bingham P
(2011)
Oxidation state and local environment of selenium in alkali borosilicate glasses for radioactive waste immobilisation
in Journal of Non-Crystalline Solids
Ivanov P
(2012)
The effect of humic acid on uranyl sorption onto bentonite at trace uranium levels.
in Journal of environmental monitoring : JEM
Stockdale A
(2011)
Estimation of Model VII humic binding constants for Pd2+, Sn2+, U4+, NpO2(2+), Pu4+ and PuO2(2+).
in Journal of environmental monitoring : JEM
Douglas D
(2011)
Laser Ablation of a Sample In Liquid-LASIL
in Journal of Analytical Atomic Spectrometry
Cassingham N
(2011)
The Structural Role of Zn in Nuclear Waste Glasses
in International Journal of Applied Glass Science
Holdich R
(2010)
Membrane Emulsification with Oscillating and Stationary Membranes
in Industrial & Engineering Chemistry Research
Holdich R
(2013)
Continuous Membrane Emulsification with Pulsed (Oscillatory) Flow
in Industrial & Engineering Chemistry Research
Dragosavac M
(2011)
Continuous Flow Stirred Cell Microfiltration of Ion Exchange Media to Determine Mass Transfer Kinetics and Equilibrium Data
in Industrial & Engineering Chemistry Research
Thorpe CL
(2012)
Alkaline Fe(III) reduction by a novel alkali-tolerant Serratia sp. isolated from surface sediments close to Sellafield nuclear facility, UK.
in FEMS microbiology letters
Cook A
(2012)
Calibration of the scanning Kelvin probe force microscope under controlled environmental conditions
in Electrochimica Acta
Cole I
(2011)
Multiscale modelling of the corrosion of metals under atmospheric corrosion
in Electrochimica Acta