Manufacturable nanoscale architectures for heterojunction solar cells
Lead Research Organisation:
University of Cambridge
Department Name: Physics
Abstract
This project will produce manufacturable nanoscale architectures for heterojunction solar cells. Though routed strongly within 'science', the objectives are to achieve engineering solutions to allow the breakthrough needed in this field (target efficiency 10%). Excitonic solar cells based on molecular semiconductors require the presence of a heterojunction between electron and hole-accepting semiconductors in order to separate charges from photogenerated excitons. Large heterojunction interfacial areas are required if all photogenerated excitons are to reach the heterojunction before decaying, and this requires a complex nanoscale architecture. Current methods to achieve this nanostructure and limited and solar cell performance of such devices has stalled. We propose therefore to develop generic routes to separate the control of the nanoscale morphology from the selection of the donor and acceptor semiconductors. This will represent a critical advance in allowing a stable process window, and should allow improved photovoltaic performance through better morphology control and the ability to use semiconductors better matched to the solar spectrum. These routes will be compatible with low temperature processing (this is critical for low-cost manufacturing). The general principle we will use is to separate the processes needed to form the desired nanoscale architecture from the subsequent formation of the active semiconductor-semiconductor heterojunctions at which charge separation is achieved.Central to our approach is the use of 'sacrificial' polymer structures that provide excellent control of nanoscale morphology, and their later replacement with active semiconductors. We will use the controlled nanoscale structures produced using di-block copolymers
Organisations
Publications
Plank NO
(2008)
A simple low temperature synthesis route for ZnO-MgO core-shell nanowires.
in Nanotechnology
Plank N
(2009)
Efficient ZnO Nanowire Solid-State Dye-Sensitized Solar Cells Using Organic Dyes and Core-shell Nanostructures
in The Journal of Physical Chemistry C
Li L
(2010)
Enhanced photocatalytic properties in well-ordered mesoporous WO3
in Chemical Communications
Guldin S
(2010)
Dye-sensitized solar cell based on a three-dimensional photonic crystal.
in Nano letters
Crossland E
(2010)
Systematic Control of Nucleation Density in Poly(3-Hexylthiophene) Thin Films
in Advanced Functional Materials
Docampo P
(2010)
Control of Solid-State Dye-Sensitized Solar Cell Performance by Block-Copolymer-Directed TiO 2 Synthesis
in Advanced Functional Materials
Nedelcu M
(2010)
Monolithic route to efficient dye-sensitized solar cells employing diblock copolymers for mesoporous TiO 2
in J. Mater. Chem.
Guldin S
(2011)
Improved conductivity in dye-sensitised solar cells through block-copolymer confined TiO 2 crystallisation
in Energy Environ. Sci.
Guldin S
(2011)
Tunable Mesoporous Bragg Reflectors Based on Block-Copolymer Self-Assembly
in Advanced Materials
Abrusci A
(2011)
Influence of Ion Induced Local Coulomb Field and Polarity on Charge Generation and Efficiency in Poly(3-Hexylthiophene)-Based Solid-State Dye-Sensitized Solar Cells
in Advanced Functional Materials
Abrusci A
(2011)
Facile infiltration of semiconducting polymer into mesoporous electrodes for hybrid solar cells
in Energy & Environmental Science
Fang J
(2011)
Conjugated zwitterionic polyelectrolyte as the charge injection layer for high-performance polymer light-emitting diodes.
in Journal of the American Chemical Society
Chen Z
(2011)
Enhanced charge transport by incorporating additional thiophene units in the poly(fluorene-thienyl-benzothiadiazole) polymer
in Organic Electronics
Docampo P
(2012)
Triblock-Terpolymer-Directed Self-Assembly of Mesoporous TiO 2 : High-Performance Photoanodes for Solid-State Dye-Sensitized Solar Cells
in Advanced Energy Materials
Guldin S
(2012)
Layer-by-layer formation of block-copolymer-derived TiO(2) for solid-state dye-sensitized solar cells.
in Small (Weinheim an der Bergstrasse, Germany)
Stefik M
(2012)
Networked and chiral nanocomposites from ABC triblock terpolymer coassembly with transition metal oxide nanoparticles
in J. Mater. Chem.
Guldin S
(2013)
Self-cleaning antireflective optical coatings.
in Nano letters
Description | This grant supported the study of new nanostructures for use principally in solar cells. The principal focus was on the construction of ordered metal oxide nanostructures which were then complemented with organic or organometallic light-absorbing dyes and semiconductors. The control of nanostructure has proved to be very effective for use in a wide range of solar cell structures. |
Exploitation Route | The work done during this contract has supported the long-term development of excitonic solar cells. |
Sectors | Education Electronics |
Description | New structures were developed to allow cascading of photo generated excitons (towards) and charges (away from) donor-acceptor heterojunctions. For example, a novel light-harvesting chromophore was incorporated within a solar cell comprising a titanium dioxide - dye - solid state hole transport material, enabling extended spectral response. Beneficiaries: academic and industrial communities Contribution Method: New fundamental understanding |
First Year Of Impact | 2010 |
Sector | Education,Electronics |
Impact Types | Cultural |