Nanoengineered Materials for Clean Catalytic Technologies
Lead Research Organisation:
CARDIFF UNIVERSITY
Department Name: Chemistry
Abstract
Catalysis lies at the heart of life on earth, powers our homes and puts food on our tables. However to a large degree our ability to transform individual atoms and molecules into new pharmaceutical medicines, fuels, and fertilisers has depended upon an equal combination of brilliant science and serendipitous discoveries. This reflects the complex interactions between reacting molecules and products, their surrounding environment, and of course the catalyst itself, which ideally remains unchanged over thousands of reaction cycles. Recent advances in chemical synthesis and analysis now offer an unprecedented opportunity to sculpt the atomic structure of solid catalysts and to peer inside their microscopic workings.Over the next five years, I propose to integrate these new experimental and theoretical breakthroughs with my own expertise in catalyst design and testing, to develop a new generation of nanoengineered materials for the clean production of valuable chemical feedstocks and sustainable biofuels. New collaborations, forged with world leaders in the areas of inorganic solid-state chemistry, nanoscale imaging and computer modelling, will help me to develop the multidisciplinary skillsets needed to achieve my vision of solid catalysts, tailored 'on demand', for efficient clean technologies that will benefit society over the coming decade.
People |
ORCID iD |
Adam Lee (Principal Investigator) |
Publications
Bonne M
(2011)
A general route to synthesize supported isolated oxide and mixed-oxide nanoclusters at sizes below 5 nm.
in Chemical communications (Cambridge, England)
Rabee A
(2017)
Acidity-Reactivity Relationships in Catalytic Esterification over Ammonium Sulfate-Derived Sulfated Zirconia
in Catalysts
Lee A
(2012)
Active Site Elucidation in Heterogeneous Catalysis via In Situ X-Ray Spectroscopies
in Australian Journal of Chemistry
Parlett C
(2014)
Alumina-grafted SBA-15 as a high performance support for Pd-catalysed cinnamyl alcohol selective oxidation
in Catalysis Today
Dacquin JP
(2009)
An efficient route to highly organized, tunable macroporous-mesoporous alumina.
in Journal of the American Chemical Society
Pirez C
(2014)
An energy-efficient route to the rapid synthesis of organically-modified SBA-15 via ultrasonic template removal
in Green Chem.
Woodford J
(2012)
Better by design: nanoengineered macroporous hydrotalcites for enhanced catalytic biodiesel production
in Energy & Environmental Science
Dingwall L
(2012)
Bifunctional Organorhodium Solid Acid Catalysts for Methanol Carbonylation
in ACS Catalysis
Osatiashtiani A
(2014)
Bifunctional SO 4 /ZrO 2 catalysts for 5-hydroxymethylfufural (5-HMF) production from glucose
in Catal. Sci. Technol.
Fairlamb I
(2013)
C-H and C-X Bond Functionalization - Transition Metal Mediation
Wilson K
(2012)
Catalysis for Alternative Energy Generation
Zeinalipour-Yazdi C
(2016)
CO adsorption over Pd nanoparticles: A general framework for IR simulations on nanoparticles
in Surface Science
Erden S
(2010)
Continuous Atmospheric Plasma Oxidation of Carbon Fibres: Influence on the Fibre Surface and Bulk Properties and Adhesion to Polyamide 12
in Plasma Chemistry and Plasma Processing
Montero J
(2010)
Cs Promoted Triglyceride Transesterification Over MgO Nanocatalysts
in Topics in Catalysis
Lee, A.F.
(2010)
Evidence for the surface catalysed Suzuki-Miyaura reaction over Pd nanocatalysts: An operando XAS study
in ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY
Eze V
(2013)
Heterogeneous catalysis in an oscillatory baffled flow reactor
in Catalysis Science & Technology
Woodford J.
(2010)
Hierarchical nanoporous solid base catalysts for biofuels
in ACS National Meeting Book of Abstracts
Woodford J.
(2010)
Hierarchical nanoporous solid base catalysts for biofuels
in ACS National Meeting Book of Abstracts
Dacquin J.-P.
(2010)
Hierarchical porous catalysts tailored for biodiesel production
in ACS National Meeting Book of Abstracts
Dacquin J.-P.
(2010)
Hierarchical porous catalysts tailored for biodiesel production
in ACS National Meeting Book of Abstracts
Parlett CM
(2013)
Hierarchical porous materials: catalytic applications.
in Chemical Society reviews
Parlett C
(2013)
Hierarchically Ordered Nanoporous Pd/SBA-15 Catalyst for the Aerobic Selective Oxidation of Sterically Challenging Allylic Alcohols
in ACS Catalysis
Lee A
(2012)
High-Pressure XPS of Crotyl Alcohol Selective Oxidation over Metallic and Oxidized Pd(111)
in ACS Catalysis
Buckley J
(2010)
Hydroxyapatite supported antibacterial Ag3PO4 nanoparticles
in Journal of Materials Chemistry
Woodford J
(2013)
Identifying the active phase in Cs-promoted MgO nanocatalysts for triglyceride transesterification
in Journal of Chemical Technology & Biotechnology
Shamsuddin S
(2010)
Impact of in-line atmospheric plasma fluorination of carbon fibers on the performance of unidirectional, carbon fiber-reinforced polyvinylidene fluoride
in Advances in Polymer Technology
Montero J
(2010)
In situ studies of structure-reactivity relations in biodiesel synthesis over nanocrystalline MgO
in Chemical Engineering Journal
Lee A
(2010)
In situ studies of titania-supported Au shell-Pd core nanoparticles for the selective aerobic oxidation of crotyl alcohol
in Catalysis Today
Lee A
(2011)
In-situ X-ray Studies of Clean Catalytic Technologies
in MRS Proceedings
Menzel R
(2009)
Inverse gas chromatography of as-received and modified carbon nanotubes.
in Langmuir : the ACS journal of surfaces and colloids
Kapil A
(2011)
Kinetic Modeling Studies of Heterogeneously Catalyzed Biodiesel Synthesis Reactions
in Industrial & Engineering Chemistry Research
Parlett C
(2012)
Mesoporous Silicas as Versatile Supports to Tune the Palladium-Catalyzed Selective Aerobic Oxidation of Allylic Alcohols
in ChemCatChem
Naughton J
(2011)
Metastable De-excitation Spectroscopy and Density Functional Theory Study of the Selective Oxidation of Crotyl Alcohol over Pd(111)
in The Journal of Physical Chemistry C
Davison T
(2013)
Multiscale modelling of heterogeneously catalysed transesterification reaction process: an overview
in RSC Advances
Lee A.F.
(2011)
Nanoengineering the active site in heterogeneous catalysis
in ACS National Meeting Book of Abstracts
Lee A.F.
(2011)
Nanoengineering the active site in heterogeneous catalysis
in ACS National Meeting Book of Abstracts
Montero J.M.
(2010)
New solid base catalysts for biodiesel synthesis
in ACS National Meeting Book of Abstracts
Montero J.M.
(2010)
New solid base catalysts for biodiesel synthesis
in ACS National Meeting Book of Abstracts
Liu D
(2012)
On the impact of Cu dispersion on CO2 photoreduction over Cu/TiO2
in Catalysis Communications
Parlett C
(2013)
Operando synchronous DRIFTS/MS/XAS as a powerful tool for guiding the design of Pd catalysts for the selective oxidation of alcohols
in Catalysis Today
Dacquin JP
(2012)
Pore-expanded SBA-15 sulfonic acid silicas for biodiesel synthesis.
in Chemical communications (Cambridge, England)
Lee A
(2010)
Preface
in Topics in Catalysis
Walker RA
(2012)
Preservation of York Minster historic limestone by hydrophobic surface coatings.
in Scientific reports
Wilson K
(2012)
Rational design of heterogeneous catalysts for biodiesel synthesis
in Catalysis Science & Technology
Lee AF
(2011)
Reaction-driven surface restructuring and selectivity control in allylic alcohol catalytic aerobic oxidation over Pd.
in Journal of the American Chemical Society
Naughton J
(2010)
Reactivity of crotonaldehyde and propene over Au/Pd(111) surfaces.
in Physical chemistry chemical physics : PCCP
Vinod C
(2011)
Recent advances in the heterogeneously catalysed aerobic selective oxidation of alcohols
in Journal of Chemical Technology & Biotechnology
Lee A
(2015)
Recent developments in heterogeneous catalysis for the sustainable production of biodiesel
in Catalysis Today
Description | See EP/G007594/4 |
Exploitation Route | Yes |
Sectors | Agriculture, Food and Drink,Chemicals,Energy,Environment,Pharmaceuticals and Medical Biotechnology |
Description | Selective catalytic transformations for agrochemicals |
Organisation | Syngenta International AG |
Country | Switzerland |
Sector | Private |
PI Contribution | Two part-sponsored PhD studentships have undertake fundamental research into the mechanism of palladium catalysed transformations and identified key factors controlling the catalytic performance and stability of nanoparticles. |
Collaborator Contribution | Access to laboratories, intellectual guidance, provision of catalysts |
Impact | One PhD graduated to date, and 2 peer-reviewed publications. |
Start Year | 2009 |
Description | Synchtrotron studies of nanostructured materials |
Organisation | Elettra Sincrotrone Trieste |
Country | Italy |
Sector | Academic/University |
PI Contribution | New research areas in catalysis and materials science developed resulting in numerous jointly authored publications over 17 years. |
Collaborator Contribution | Access to synchtrotron facilities and training of 8 PhD students and PDRAs |
Impact | Joint publications, contributions to annual highlights, invited seminar and Fonda-Fasella 2004 award |