Nanotribology: measurement and modelling across the rubbing interface
Lead Research Organisation:
Imperial College London
Department Name: Mechanical Engineering
Abstract
The term nanotribology was first coined by IBM in the early 1990s to refer to the study of tribology research and processes (such as friction and wear) at the nanoscale, i.e. at the scale of tens to thousands of atoms and molecules. Initially the main focus of nanotribology research was to understand and improve the lubrication of tiny devices such as hard discs and micromachines. More recently, nanotribology has become very important in the study of sliding biological systems such as human joints and stem cell development (it has been found that the development of stem cells into various types of specialist cells is partly-controlled by their mechanical environment).However in addition to these explicitly nanoscale systems, we now realise that many aspects of macroscale sliding contacts, such as dry friction, friction modifier additive reactions and wear are actually determined by nanoscale processes and can be best understood by applying the tools and insights that have been developed over the last fifteen years for nanotribology research. Unfortunately tribology researchers in the UK have, by and large, not kept pace with the international development of nanotribology and there is no group in the UK that has the ability to participate and compete on the world-stage in the field in more than one or two narrow areas. The problem is that world-leading nanotribology research requires the coupling of several different, advanced experimental and numerical techniques (nanoprobes, focussed ion beam milling, spectroscopy, molecular dynamics simulation etc.) and UK tribology groups have tended not to have the resources and background to be able to establish such a broad activity.The intention of this Grant application is to enable us to establish such a platform of capability for research in nanotribology. The Grant will part-fund specialists in the various key experimental and numerical skill areas required to conduct research in nanotribology, thus ensuring that we can build and maintain the broad technique base needed. These specialists, as well as providing support to research projects that need to make use of the techniques concerned, will also carry out feasibility studies aimed primarily at developing new tools for nanotribology research. The future goal will be to link nanotribology with conventional continuum tribology so as to enable modelling and prediction of the behaviour of systems where both scales are crucial, for example in the mixed lubrication of machine components, in wear and in lubrication of micro-scale biological systems.
Publications
Heyes DM
(2018)
Incremental viscosity by non-equilibrium molecular dynamics and the Eyring model.
in The Journal of chemical physics
Spikes H
(2018)
Stress-augmented thermal activation: Tribology feels the force
in Friction
Profito F
(2017)
Experimental Validation of a Mixed-Lubrication Regime Model for Textured Piston-Ring-Liner Contacts
in Materials Performance and Characterization
Bodnarchuk MS
(2017)
Molecular Dynamics Studies of Overbased Detergents on a Water Surface.
in Langmuir : the ACS journal of surfaces and colloids
Ma S
(2017)
Nanohydrogel Brushes for Switchable Underwater Adhesion
in The Journal of Physical Chemistry C
Ewen J
(2017)
Nonequilibrium molecular dynamics simulations of stearic acid adsorbed on iron surfaces with nanoscale roughness
in Tribology International
Putignano C
(2016)
Theory of reciprocating contact for viscoelastic solids.
in Physical review. E
Mackowiak S
(2016)
Non-equilibrium phase behavior and friction of confined molecular films under shear: A non-equilibrium molecular dynamics study.
in The Journal of chemical physics
Ewen JP
(2016)
Nonequilibrium Molecular Dynamics Simulations of Organic Friction Modifiers Adsorbed on Iron Oxide Surfaces.
in Langmuir : the ACS journal of surfaces and colloids
Wang P
(2016)
Development of hydrodynamic micro-bearings
in Journal of Physics: Conference Series
Heyes D
(2016)
Equilibrium fluctuations of liquid state static properties in a subvolume by molecular dynamics
in The Journal of Chemical Physics
Zhang J
(2016)
On the Mechanism of ZDDP Antiwear Film Formation
in Tribology Letters
Ewen J
(2016)
Nonequilibrium Molecular Dynamics Investigation of the Reduction in Friction and Wear by Carbon Nanoparticles Between Iron Surfaces
in Tribology Letters
Ewen JP
(2016)
A Comparison of Classical Force-Fields for Molecular Dynamics Simulations of Lubricants.
in Materials (Basel, Switzerland)
Zhang J
(2016)
Effect of Base Oil Structure on Elastohydrodynamic Friction
in Tribology Letters
Ma S
(2015)
Nanoporous Substrate-Infiltrated Hydrogels: a Bioinspired Regenerable Surface for High Load Bearing and Tunable Friction
in Advanced Functional Materials
Bodnarchuk M
(2015)
Response of Calcium Carbonate Nanoparticles in Hydrophobic Solvent to Pressure, Temperature, and Water
in The Journal of Physical Chemistry C
Smith ER
(2015)
A localized momentum constraint for non-equilibrium molecular dynamics simulations.
in The Journal of chemical physics
Heyes D
(2015)
Scaling of Lennard-Jones liquid elastic moduli, viscoelasticity and other properties along fluid-solid coexistence
in physica status solidi (b)
Medina S
(2015)
Transient effects in lubricated textured bearings
in Proceedings of the Institution of Mechanical Engineers, Part J: Journal of Engineering Tribology
Spikes H
(2015)
On the Commonality Between Theoretical Models for Fluid and Solid Friction, Wear and Tribochemistry
in Tribology Letters
Leong J
(2015)
Confining Liquids on Silicon Surfaces to Lubricate MEMS
in Tribology Letters
Parkes M
(2015)
Synovial Fluid Lubrication: The Effect of Protein Interactions on Adsorbed and Lubricating Films
in Biotribology
Spikes H
(2015)
Friction Modifier Additives
in Tribology Letters
Description | (i) Demonstration of viability of lubricating MEMS using low viscosity liquids (ii) Novel method of lubricating MEMS combined with low viscosity liquids combined with boundary lubricating additives (iii) Novel method of studying flow profiles in high pressure lubricated contacts using fluorescence recovery (iv) Demonstration of highly non-Couette flow in EHD contacts sliding at high contact pressures using both experiments and molecular dynamics simulations (v) Control of EHD friction using surface treatments (vi) Novel method for studying organic friction modifiers on surfaces using fluorescence (vii) Novel approach to reducing TiO2 in commercially pure titanium and titanium alloys (viii) Development of mass-conserving algorithms to study cavitation in textured surfaces (ix) Development of phase maps for fluids in confinement using molecular dynamics simulations (x) Novel methods to determine stresses at the nanoscale in atomistic and molecular simulations, leading to new coupling strategies (xi) Novel strategy to perform molecular-to-continuum coupling simulations (xii) Develpment of software to perform multi-physics simulations involving fluid/solid interactions and multiple scales. |
Exploitation Route | To develop microelectromechanical systems (MEMS) which can operate reliably with hiogh sliding parts. This is currently not possible. To reduce friction in high pressure rolling-sliding lubricated contacts by surface treatment and surface design To explore the experimental and modelling tools developed by the group to develop new environmentally friendly lubricants and improve components reliability To prove a means of routing production of inexpensive Ti alloys with good wear resistance To provide tools for virtual design by integrating tribological models at different scales. Company support for follow on R&D: Boeing Shell SKF BP Element Six National Rail Bosch Afton Chemicals Exxon Mobil Rolls-Royce Johnson Matthey Oleon Croda AftonChemical |
Sectors | Aerospace Defence and Marine Chemicals Energy Environment Healthcare Manufacturing including Industrial Biotechology Transport |
Description | They have been used by numerous companies to improve their lubricant and component life models and to develop improved lubricants able to deliver low friction and thus save energy; e.g. BP, Shell, SKF, Ford, Bosch, Rolls Royce, Afton Chemical, Hyundai, Croda, Oleon |
First Year Of Impact | 2010 |
Sector | Aerospace, Defence and Marine,Chemicals,Energy,Manufacturing, including Industrial Biotechology,Transport |
Impact Types | Societal Economic |
Description | EPSRC Established Career Fellowship - EP/N025954/1 - A MULTIDISCIPLINARY PLATFORM FOR FUTURE TRIBOLOGICAL MODELLING |
Amount | £1,205,326 (GBP) |
Funding ID | EP/N025954/1 |
Organisation | Engineering and Physical Sciences Research Council (EPSRC) |
Sector | Public |
Country | United Kingdom |
Start | 05/2016 |
End | 05/2021 |
Description | Diffusion in Solutes in Polymeric Systems |
Organisation | City University of Hong Kong |
Country | Hong Kong |
Sector | Academic/University |
PI Contribution | Using Fluorescence Imaging, the diffusion of small molecules across polymeric nanocomposite membranes were investigated |
Start Year | 2011 |
Description | Joint Workshop and memorandum of understanding with State Key Tribology Laboratory (SKTL) Tsinghua, Beijing |
Organisation | Tsinghua University China |
Country | China |
Sector | Academic/University |
PI Contribution | Agreement with SKTL to hold regular workshops, student exchanges etc. Two workshops held to date (2011&2012) and two student exchanges (2012), two joint papers as outcomes |
Start Year | 2011 |
Description | SKF ENGINEERING & RESEARCH SERVICES B.V. |
Organisation | SKF |
Department | S.K.F. Engineering & Research Services B.V |
Country | Netherlands |
Sector | Private |
PI Contribution | Establishment of SKF University Technology Centre for Tribology at Imperial College |
Collaborator Contribution | Funding for stablishment of SKF University Technology Centre for Tribology at Imperial College |
Impact | More than 10 PhD projects and eight PDRA projects to investigate transmission tribology |
Start Year | 2009 |
Description | Shell Global Solutions UK Renewal |
Organisation | Shell Global Solutions International BV |
Department | Shell Global Solutions UK |
Country | Netherlands |
Sector | Private |
PI Contribution | Renewal of Shell GS UTC in Fuels and Lubricants at Imperial College 2013 |
Collaborator Contribution | Renewal of Shell GS UTC in Fuels and Lubricants at Imperial College 2018 |
Impact | Establishment of Shell GS UTC in Fuels and Lubricants at Imperial College 2013, seven PhD projects and five PDRA projects Renewal in 2108 for a further four years - four PhD students and one PDRA project to date |
Start Year | 2017 |
Description | The Tribology of PAEK |
Organisation | Texas A&M University |
Country | United States |
Sector | Academic/University |
PI Contribution | The friction, wear and contact temperature of a PAEK contact under various loads and speeds were examined |
Start Year | 2012 |
Description | BP Pangbourne UK Presentation |
Form Of Engagement Activity | A talk or presentation |
Part Of Official Scheme? | No |
Primary Audience | |
Results and Impact | Description fo research findings. |
Year(s) Of Engagement Activity | 2012 |
Description | Presentation to Shell Houston USA |
Form Of Engagement Activity | A talk or presentation |
Part Of Official Scheme? | No |
Geographic Reach | International |
Primary Audience | |
Results and Impact | Presentation of research findings to Shell Houston USA. |
Year(s) Of Engagement Activity | 2014 |
Description | Presentation to Shell Thornton |
Form Of Engagement Activity | A talk or presentation |
Part Of Official Scheme? | No |
Geographic Reach | International |
Primary Audience | Professional Practitioners |
Results and Impact | Presentation of reaserch findings to Shell Global Solutions Thornton. |
Year(s) Of Engagement Activity | 2013 |