SUPERGEN Excitonic Solar Cell Consortium - MAIN CORE
Lead Research Organisation:
University of Warwick
Department Name: Chemistry
Abstract
Excitonic Solar Cells (ESCs) are a class of non-conventional solar cells, based on organic and nanostructured materials, in which the charge carriers are generated and simultaneously separated across a heterointerface. They include dye-sensitized nanocrystalline cells, organic cells and hybrid organic-inorganic cells, and in all cases cell fabrication can be achieved using low cost, large area deposition methods on both rigid and flexible substrates. Consequently, ESCs offer genuine medium to long term prospects for reducing the cost of PV below the commercially important threshold of $1 per watt peak. To date work on all types of ESC has been largely restricted to basic studies in academic and national research laboratories, with particular emphasis on improving device understanding and cell efficiency, which are 11% for state of the art dye cells, and much lower for the less well developed organic (4-5%) and hybrid cells (2-3%). However, progress in all types of ESC has undoubtedly been impressive in recent years, with research activity growing rapidly throughout the world. Major improvements in performance have been demonstrated in all cell types with the SUPERGEN Consortium at the forefront of much of this progress. There have also been initial steps to commercialise some ESCs, with the first manufacturing plant to produce dye sensitised cells opening in the UK in 2007. However, much fundamental research still needs to be carried out, in particular on the less well developed organic and hybrid cells, but also on the more mature dye cells where many important challenges must be addressed to enable future successful commercialisation. The UK is in an excellent position to lead this activity in an emerging area of PV technology and renewed SUPERGEN funding will enable the Consortium to remain at the forefront of innovative research, while exploiting its strong connections to a number of relevant commercial organisations.Our proposed Main Core programme builds on the successes of our first SUPERGEN project which benefited strongly from the integration of expertise and knowledge in the two main areas of excitonic solar cells, namely dye sensitised cells and organic cells. We will continue to promote cross-fertilisation of ideas for optimising existing cell types and for innovating new types of cells, with the overall aim of improving the performance of different types of ESC. Training will remain a key priority for the Consortium and the exchange of PDRAs and PhD students between the partner universities will ensure the highest quality multi-disciplinary research environment. The UK has a very strong international position in research into ESCs and the renewal of the SUPERGEN programme will help ensure it remains both competitive and innovative in future years.
Organisations
Publications
Urbina A
(2013)
Work function engineering of ZnO electrodes by using p-type and n-type doped carbon nanotubes.
in Nanotechnology
Brenner T
(2012)
White-light bias external quantum efficiency measurements of standard and inverted P3HT : PCBM photovoltaic cells
in Journal of Physics D: Applied Physics
Li Z
(2013)
Voltage-dependent photocurrent transients of PTB7:PC70BM solar cells: Experiment and numerical simulation
in Journal of Applied Physics
Hancox I
(2011)
Utilizing n-type vanadium oxide films as hole-extracting layers for small molecule organic photovoltaics
in Applied Physics Letters
Bailey J
(2014)
Understanding the role of ultra-thin polymeric interlayers in improving efficiency of polymer light emitting diodes
in Journal of Applied Physics
Wood S
(2013)
Understanding the relationship between molecular order and charge transport properties in conjugated polymer based organic blend photovoltaic devices.
in The Journal of chemical physics
Risbridger T
(2012)
Two-Dimensional Photocurrent and Transmission Mapping of Aqueous Dye-Sensitized Solar Cells
in The Journal of Physical Chemistry C
Li Z
(2011)
Transient photocurrent measurements of PCDTBT:PC70BM and PCPDTBT:PC70BM Solar Cells: Evidence for charge trapping in efficient polymer/fullerene blends
in Journal of Applied Physics
Dimitrov S
(2014)
Towards optimisation of photocurrent from fullerene excitons in organic solar cells
in Energy & Environmental Science
Guijarro N
(2012)
Toward Antimony Selenide Sensitized Solar Cells: Efficient Charge Photogeneration at spiro-OMeTAD/Sb2Se3/Metal Oxide Heterojunctions.
in The journal of physical chemistry letters
Lutz T
(2012)
Thermal decomposition of solution processable metal xanthates on mesoporous titanium dioxide films: a new route to quantum-dot sensitised heterojunctions.
in Physical chemistry chemical physics : PCCP
Agostinelli T
(2011)
The role of alkane dithiols in controlling polymer crystallization in small band gap polymer:Fullerene solar cells
in Journal of Polymer Science Part B: Polymer Physics
Tsoi W
(2011)
The Nature of In-Plane Skeleton Raman Modes of P3HT and Their Correlation to the Degree of Molecular Order in P3HT:PCBM Blend Thin Films
in Journal of the American Chemical Society
Zhang W
(2009)
Systematic improvement in charge carrier mobility of air stable triarylamine copolymers.
in Journal of the American Chemical Society
Hou B
(2021)
Synthetic Mechanism Studies of Iron Selenides: An Emerging Class of Materials for Electrocatalysis
in Catalysts
Tsoi W
(2011)
Surface and subsurface morphology of operating nanowire:fullerene solar cells revealed by photoconductive-AFM
in Energy & Environmental Science
Hou B
(2013)
Structure and Band Edge Energy of Highly Luminescent CdSe 1- x Te x Alloyed Quantum Dots
in The Journal of Physical Chemistry C
Bansal N
(2013)
Solution Processed Polymer-Inorganic Semiconductor Solar Cells Employing Sb 2 S 3 as a Light Harvesting and Electron Transporting Material
in Advanced Energy Materials
Cho S
(2010)
Soft X-ray Spectroscopy of C 60 /Copper Phthalocyanine/MoO 3 Interfaces: Role of Reduced MoO 3 on Energetic Band Alignment and Improved Performance
in The Journal of Physical Chemistry C
New E
(2013)
Small molecule tandem organic photovoltaic cells incorporating an a-NPD optical spacer layer
in Organic Electronics
Ehrler B
(2012)
Singlet exciton fission-sensitized infrared quantum dot solar cells.
in Nano letters
Etherington M
(2014)
Recombination pathways in polymer:fullerene photovoltaics observed through spin polarization measurements
in Applied Physics Letters
Kirchartz T
(2016)
Reciprocity between Charge Injection and Extraction and Its Influence on the Interpretation of Electroluminescence Spectra in Organic Solar Cells
in Physical Review Applied
Hou B
(2014)
Rapid phosphine-free synthesis of CdSe quantum dots: promoting the generation of Se precursors using a radical initiator
in J. Mater. Chem. A
Gao F
(2012)
Quantifying Loss Mechanisms in Polymer:Fullerene Photovoltaic Devices
in Advanced Energy Materials
Cho S
(2012)
Probing the effect of relative molecular orientation on the photovoltaic device performance of an organic bilayer heterojunction using soft x-ray spectroscopies
in Applied Physics Letters
Ravirajan P
(2012)
Post-Processing Treatments in Hybrid Polymer/Titanium Dioxide Multilayer Solar Cells
in Journal of Nanoelectronics and Optoelectronics
Beatrup D
(2014)
Polaron stability in semiconducting polymer neat films.
in Chemical communications (Cambridge, England)
Brenner T
(2011)
Phase-Dependent Photocurrent Generation in Polymer/Fullerene Bulk Heterojunction Solar Cells
in The Journal of Physical Chemistry C
Hancox I
(2012)
Optimization of a High Work Function Solution Processed Vanadium Oxide Hole-Extracting Layer for Small Molecule and Polymer Organic Photovoltaic Cells
in The Journal of Physical Chemistry C
Wade J
(2015)
Operational electrochemical stability of thiophene-thiazole copolymers probed by resonant Raman spectroscopy.
in The Journal of chemical physics
Kirchartz T
(2013)
On the Differences between Dark and Light Ideality Factor in Polymer:Fullerene Solar Cells
in The Journal of Physical Chemistry Letters
Hewat TE
(2014)
Neutral copper(I) dipyrrin complexes and their use as sensitizers in dye-sensitized solar cells.
in Dalton transactions (Cambridge, England : 2003)
Kim J
(2015)
Morphology-performance relationships in polymer/fullerene blends probed by complementary characterisation techniques - effects of nanowire formation and subsequent thermal annealing
in Journal of Materials Chemistry C
Kirchartz T
(2012)
Meaning of reaction orders in polymer:fullerene solar cells
in Physical Review B
Nightingale A
(2013)
Large-scale synthesis of nanocrystals in a multichannel droplet reactor
in Journal of Materials Chemistry A
Hou B
(2013)
Initial stages in the formation of Cu2ZnSn(S,Se)4 nanoparticles.
in Chemistry (Weinheim an der Bergstrasse, Germany)
Wheeler S
(2015)
Influence of Surface Recombination on Charge-Carrier Kinetics in Organic Bulk Heterojunction Solar Cells with Nickel Oxide Interlayers
in Physical Review Applied
Vaissier V
(2015)
Influence of Intermolecular Interactions on the Reorganization Energy of Charge Transfer between Surface-Attached Dye Molecules
in The Journal of Physical Chemistry C
Bansal N
(2013)
Influence of crystallinity and energetics on charge separation in polymer-inorganic nanocomposite films for solar cells.
in Scientific reports
Manke F
(2015)
Influence of a nearby substrate on the reorganization energy of hole exchange between dye molecules.
in Physical chemistry chemical physics : PCCP
Dalgleish S
(2011)
Indole-substituted nickel dithiolene complexes in electronic and optoelectronic devices
in Journal of Materials Chemistry
Hancox I
(2010)
Increased efficiency of small molecule photovoltaic cells by insertion of a MoO 3 hole-extracting layer
in Energy Environ. Sci.
Beaumont N
(2011)
Increased efficiency in small molecule organic photovoltaic cells through electrode modification with self-assembled monolayers
in Energy & Environmental Science
Ehrler B
(2012)
In situ measurement of exciton energy in hybrid singlet-fission solar cells.
in Nature communications
Wood S
(2014)
In situ formation of organic-inorganic hybrid nanostructures for photovoltaic applications
in Faraday Discuss.
Ehrler B
(2012)
Hybrid pentacene/a-silicon solar cells utilizing multiple carrier generation via singlet exciton fission
in Applied Physics Letters
Mawyin J
(2011)
Hybrid Heterojunction Nanorods for Nanoscale Controlled Morphology in Bulk Heterojunction Solar Cells
in The Journal of Physical Chemistry C
Grew B
(2014)
High Mobility Titanium-doped Indium Oxide for Use in Tandem Solar Cells Deposited via Pulsed DC Magnetron Sputtering
in Energy Procedia
Sullivan P
(2011)
Halogenated Boron Subphthalocyanines as Light Harvesting Electron Acceptors in Organic Photovoltaics
in Advanced Energy Materials