Calixarenes: Metal-Organic Frameworks and Discrete Superstructures

Lead Research Organisation: University of Edinburgh
Department Name: Sch of Chemistry

Abstract

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Publications

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Sanz S (2011) Calix[4]arene-supported Fe(III)2Ln(III)2 clusters. in Chemical communications (Cambridge, England)

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Taylor SM (2011) A family of calix[4]arene-supported [Mn(III)2Mn(II)2] clusters. in Chemistry (Weinheim an der Bergstrasse, Germany)

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Fairbairn RE (2012) Calixarene-supported rare-earth clusters: heteroatom bridge influences cluster composition. in Chemical communications (Cambridge, England)

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Sanz S (2012) Calix[4]arene-supported rare earth octahedra. in Chemical communications (Cambridge, England)

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Taylor SM (2012) Oxacalix[3]arene-supported supertetrahedron. in Chemical communications (Cambridge, England)

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Taylor SM (2012) p-tert-Butylcalix[8]arene: an extremely versatile platform for cluster formation. in Chemistry (Weinheim an der Bergstrasse, Germany)

 
Description Synthesised a range of covalent organic nanocapsules with appropriate functionality for the controlled combination with C[4]-supported polynuclear metal cluster motifs. Synthesised a range of multi-calixarene building blocks with appropriate functionality for the controlled combination with C[4]-supported polynuclear metal cluster motifs. Utilised nanometre scale building blocks to form novel families of polymeric metal-organic frameworks and discrete metal-organic superstructures.
Exploitation Route Fundamental chemistry and physics with potential future application in materials.
Sectors Chemicals

URL http://www.chem.ed.ac.uk/staff/academic-staff/professor-euan-k-brechin