Calixarenes: Metal-Organic Frameworks and Discrete Superstructures
Lead Research Organisation:
University of Edinburgh
Department Name: Sch of Chemistry
Abstract
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People |
ORCID iD |
| Euan Brechin (Principal Investigator) |
Publications
Coletta M
(2020)
Magneto-structural studies of an unusual [MnIIIMnIIGdIII(OR)4]4- partial cubane from 2,2'-bis-p-tBu-calix[4]arene.
in Dalton transactions (Cambridge, England : 2003)
Coletta M
(2016)
Investigations into cluster formation with alkyl-tethered bis-calix[4]arenes
in Supramolecular Chemistry
Coletta M
(2017)
A New Family of 3d-4f Bis-Calix[4]arene-Supported Clusters.
in Chemistry (Weinheim an der Bergstrasse, Germany)
Coletta M
(2017)
The remarkable influence of N,O-ligands in the assembly of a bis-calix[4]arene-supported [MnMnMn] cluster.
in Dalton transactions (Cambridge, England : 2003)
Coletta M
(2020)
A Brucite-Like Mixed-Valent Cluster Capped by [MnIIIp-tBu-calix[4]arene]- Moieties
in Chemistry
Coletta M
(2020)
With complements of the ligands: an unusual S-shaped [Mn7]2 assembly from tethered calixarenes.
in Dalton transactions (Cambridge, England : 2003)
Coletta M
(2016)
Bis-Calix[4]arenes: From Ligand Design to the Directed Assembly of a Metal-Organic Trigonal Antiprism.
in Chemistry (Weinheim an der Bergstrasse, Germany)
Fairbairn RE
(2012)
Calixarene-supported rare-earth clusters: heteroatom bridge influences cluster composition.
in Chemical communications (Cambridge, England)
Fairbairn RE
(2014)
Oxacalix[4]arene-supported di-, tetra- and undecanuclear copper(II) clusters.
in Dalton transactions (Cambridge, England : 2003)
MartÃnez-Lillo J
(2014)
A family of cationic oxime-based hexametallic manganese(III) single-molecule magnets.
in Dalton transactions (Cambridge, England : 2003)
McDonald C
(2015)
Molecular Pac-Man and Tacos: layered Cu(II) cages from ligands with high binding site concentrations.
in Dalton transactions (Cambridge, England : 2003)
McIntosh RD
(2011)
p-tert-Butylcalix[8]arene: a support for sodium and sodium-manganese clusters that exhibit interesting self-assembly properties.
in Dalton transactions (Cambridge, England : 2003)
McLellan R
(2015)
Linked supramolecular building blocks for enhanced cluster formation.
in Chemistry (Weinheim an der Bergstrasse, Germany)
McLellan R
(2013)
Complementary ligands direct the formation of a calix[8]arene-supported ferromagnetic Mn(IV)Mn(III) dimer.
in Dalton transactions (Cambridge, England : 2003)
McLellan R
(2014)
Discovering the pivotal role of carbonate in the formation of a bis-phenolate supported Co15 cluster.
in Chemical communications (Cambridge, England)
Palacios MA
(2015)
Facile interchange of 3d and 4f ions in single-molecule magnets: stepwise assembly of [Mn4 ], [Mn3Ln] and [Mn2Ln2 ] cages within calix[4]arene scaffolds.
in Chemistry (Weinheim an der Bergstrasse, Germany)
Sanz S
(2011)
Calix[4]arene-supported Fe(III)2Ln(III)2 clusters.
in Chemical communications (Cambridge, England)
Sanz S
(2012)
Calix[4]arene-supported rare earth octahedra.
in Chemical communications (Cambridge, England)
Taylor S
(2014)
Assembly of a calix[4]arene-supported Mn III Mn II cluster mediated by halogen interactions
in CrystEngComm
Taylor S
(2011)
Calix[4]arene supported clusters: a dimer of [Mn III Mn II ] dimers
in Chem. Commun.
Taylor SM
(2012)
Oxacalix[3]arene-supported supertetrahedron.
in Chemical communications (Cambridge, England)
Taylor SM
(2011)
A family of calix[4]arene-supported [Mn(III)2Mn(II)2] clusters.
in Chemistry (Weinheim an der Bergstrasse, Germany)
Taylor SM
(2012)
p-tert-Butylcalix[8]arene: an extremely versatile platform for cluster formation.
in Chemistry (Weinheim an der Bergstrasse, Germany)
| Description | Synthesised a range of covalent organic nanocapsules with appropriate functionality for the controlled combination with C[4]-supported polynuclear metal cluster motifs. Synthesised a range of multi-calixarene building blocks with appropriate functionality for the controlled combination with C[4]-supported polynuclear metal cluster motifs. Utilised nanometre scale building blocks to form novel families of polymeric metal-organic frameworks and discrete metal-organic superstructures. |
| Exploitation Route | Fundamental chemistry and physics with potential future application in materials. |
| Sectors | Chemicals |
| URL | http://www.chem.ed.ac.uk/staff/academic-staff/professor-euan-k-brechin |