Domain boundary in multi-FERROIC materials
Lead Research Organisation:
University of Cambridge
Department Name: Earth Sciences
Abstract
The propagation of magnetic domain walls in a nanowire is already used as a memory device today: each time a domain wall passes a pick-up coil, a signal is emitted and encoded. The same technology does not apparently work in ferroelectric or ferroelastic domain walls because the movement of the wall is much less smooth: it can 'jerk' and emit spontaneously acoustic or electric signals. These signals are unwanted and lead to 'noise' in any device application. This limitation is not a physical necessity, though. Smooth movements are seen in ferroelastic SrTiO3 while most porous materials are almost totally 'jerky' and form avalanches of domain walls which can not be controlled in any device application.
The first aim of the proposal is to investigate the crossover between noisy and silent wall propagation.
Ferroelastic and ferroelectric domain walls (they are often both) have another fantastic property: they can be changed easily by doping, they can be bent, and they can form complex domain patterns which contain much more information than can be encoded in single magnetic domain walls. Examples are superconducting domain walls in WO3, highly conducting and photovoltaic walls in BiFeO3 and polar walls in CaTiO3. All these materials are well known and can be deposited routinely as thin films on appropriate substrates. What is missing is the knowledge of the mechanism by which such walls change their local structure and how this effect changes their mobilities. Walls are very thin (1-10nm) and it is therefore extremely difficult and costly to investigate their structural properties by experimental means. We have done some of the most advanced experimental work in this field but now it has become timely to advance our research theoretically by computer simulation of the relevant domain patterns. The appropriate theory is based on complex Landau-Ginzburg theory with interacting order parameters, the computer simulation of the domain patterns is based on mechanical, non-local models of interacting local state parameters with a large number of interacting 'atoms'. Here a minimum of 1 million particles are required to see boundary effects, propagating kink excitations and mutual jamming of domain walls. We will extend this size to >10 million particles.
Our second aim is hence to derive realistic thermodynamic potentials for interacting domain walls and simulate the pattern formation on a large enough scale to be realistic for possible device applications.
The first aim of the proposal is to investigate the crossover between noisy and silent wall propagation.
Ferroelastic and ferroelectric domain walls (they are often both) have another fantastic property: they can be changed easily by doping, they can be bent, and they can form complex domain patterns which contain much more information than can be encoded in single magnetic domain walls. Examples are superconducting domain walls in WO3, highly conducting and photovoltaic walls in BiFeO3 and polar walls in CaTiO3. All these materials are well known and can be deposited routinely as thin films on appropriate substrates. What is missing is the knowledge of the mechanism by which such walls change their local structure and how this effect changes their mobilities. Walls are very thin (1-10nm) and it is therefore extremely difficult and costly to investigate their structural properties by experimental means. We have done some of the most advanced experimental work in this field but now it has become timely to advance our research theoretically by computer simulation of the relevant domain patterns. The appropriate theory is based on complex Landau-Ginzburg theory with interacting order parameters, the computer simulation of the domain patterns is based on mechanical, non-local models of interacting local state parameters with a large number of interacting 'atoms'. Here a minimum of 1 million particles are required to see boundary effects, propagating kink excitations and mutual jamming of domain walls. We will extend this size to >10 million particles.
Our second aim is hence to derive realistic thermodynamic potentials for interacting domain walls and simulate the pattern formation on a large enough scale to be realistic for possible device applications.
Planned Impact
Besides the academic impact (already described) we expect significant industrial impact. Our main partners for the industrial applications of the results in the UK are Dr. Neil Mathur (Materials Sciences) and Prof. Jim Scott FRS (Physics) who have excellent track records for the transfer of academic research into industry. Prof. Marty Gregg at Queens University in Belfast works on ferroelectric devices and has visited our group on a regular base. His work will lead to better applications of memory devices.
The PI has three contact points for potential applications abroad:
1. the company Samco in Kyoto has repeatedly supported the PI with substantial financial investments. The have also helped to support part of the salary of Prof. Scott FRS in my group. This company produces thin film deposition facilities. Their main interest is the production of novel device materials with interfacial properties which are confined enough to be useful for large scale applications. The most promising development here is the array of parallel twin walls for potential photovoltaic applications and similar devices for ferroelectric switching. Our model simulations will help to find optimal solutions for the pattern formation (parallel walls, jamming of crossing walls and the pinning by surfaces).
2. The second company interested in the project is expected to be Samsung where one of our former students (Kim DJ) holds the post of manager of their development laboratory. Again, if the project is successful further collaborations with Samsung are expected to develop. Technical managers of Samsung visit the UK rather often so a special trip to Korea can be avoided. The magnetic racetrack technology is currently further improved at SKKU in Seoul, Korea and additional cooperation with the Korean group may be desirable. A decision will be taken after the second year of the project.
3. A most promising development in photovoltaics is initiated by the US-DoE in Washington DC. The program director is a long-standing collaborator of the PI (R.Ramesh). He will hold this position for another year with responsibilities for small scale energy generation. The concrete work will develop on applications in photovoltaics with Prof. Jan Seidel in Sydney. The PI has published one of the key papers in this field with Jan and a visit to or from Sydney is budgeted in this proposal.
Once we can increase the efficiency of the photovoltaic response to >15% we will be able to negotiate joint work with BP which has already signaled support in principle for the development of alternative energy generation. Previously, I was supported by BP for some of my research and have attracted funding for fluid mechanics applications to the Department of Earth Sciences in Cambridge. Industrial applications overseas are more straightforward because they are based directly on domain boundary technologies rather than power applications.
While these collaborations are based on the personal knowledge of industrial partners, we will certainly endeavor to interact with Science Park companies which are operating outside pharma industry. The EPSRC funded KTA in Cambridge is specialized to engineering-based services which can include domain boundary engineering and some materials sciences. We will make use of the local RSD division working on KTAs. In order to attract UK industry we will organize KTA research conferences related to the materials aspects and the fundamental physics of functional, mobile twin boundaries.
The PI has three contact points for potential applications abroad:
1. the company Samco in Kyoto has repeatedly supported the PI with substantial financial investments. The have also helped to support part of the salary of Prof. Scott FRS in my group. This company produces thin film deposition facilities. Their main interest is the production of novel device materials with interfacial properties which are confined enough to be useful for large scale applications. The most promising development here is the array of parallel twin walls for potential photovoltaic applications and similar devices for ferroelectric switching. Our model simulations will help to find optimal solutions for the pattern formation (parallel walls, jamming of crossing walls and the pinning by surfaces).
2. The second company interested in the project is expected to be Samsung where one of our former students (Kim DJ) holds the post of manager of their development laboratory. Again, if the project is successful further collaborations with Samsung are expected to develop. Technical managers of Samsung visit the UK rather often so a special trip to Korea can be avoided. The magnetic racetrack technology is currently further improved at SKKU in Seoul, Korea and additional cooperation with the Korean group may be desirable. A decision will be taken after the second year of the project.
3. A most promising development in photovoltaics is initiated by the US-DoE in Washington DC. The program director is a long-standing collaborator of the PI (R.Ramesh). He will hold this position for another year with responsibilities for small scale energy generation. The concrete work will develop on applications in photovoltaics with Prof. Jan Seidel in Sydney. The PI has published one of the key papers in this field with Jan and a visit to or from Sydney is budgeted in this proposal.
Once we can increase the efficiency of the photovoltaic response to >15% we will be able to negotiate joint work with BP which has already signaled support in principle for the development of alternative energy generation. Previously, I was supported by BP for some of my research and have attracted funding for fluid mechanics applications to the Department of Earth Sciences in Cambridge. Industrial applications overseas are more straightforward because they are based directly on domain boundary technologies rather than power applications.
While these collaborations are based on the personal knowledge of industrial partners, we will certainly endeavor to interact with Science Park companies which are operating outside pharma industry. The EPSRC funded KTA in Cambridge is specialized to engineering-based services which can include domain boundary engineering and some materials sciences. We will make use of the local RSD division working on KTAs. In order to attract UK industry we will organize KTA research conferences related to the materials aspects and the fundamental physics of functional, mobile twin boundaries.
People |
ORCID iD |
Ekhard Salje (Principal Investigator) |
Publications
Aktas O
(2013)
Ferroelectric precursor behavior in PbSc 0.5 Ta 0.5 O 3 detected by field-induced resonant piezoelectric spectroscopy
in Physical Review B
Aktas O
(2014)
Polar correlations and defect-induced ferroelectricity in cryogenic KTaO 3
in Physical Review B
Aktas O
(2013)
Polar precursor ordering in BaTiO3 detected by resonant piezoelectric spectroscopy
in Applied Physics Letters
Aktas O
(2013)
Resonant ultrasonic spectroscopy and resonant piezoelectric spectroscopy in ferroelastic lead phosphate, Pb3(PO4)2.
in Journal of physics. Condensed matter : an Institute of Physics journal
Aktas O
(2015)
Elastic softening of leucite and the lack of polar domain boundaries
in American Mineralogist
Aufort J
(2015)
Effect of pores and grain size on the elastic and piezoelectric properties of quartz-based materials
in American Mineralogist
Barrett N
(2018)
Evidence for a surface anomaly during the cubic-tetragonal phase transition in BaTiO3(001)
in Applied Physics Letters
Baró J
(2016)
Avalanche criticality during compression of porcine cortical bone of different ages.
in Physical review. E
Baró J
(2016)
Fracking and labquakes
in Philosophical Magazine
Baró J
(2014)
Avalanche correlations in the martensitic transition of a Cu-Zn-Al shape memory alloy: analysis of acoustic emission and calorimetry.
in Journal of physics. Condensed matter : an Institute of Physics journal
Beirau T
(2018)
Radiation-damage-induced transitions in zircon: Percolation theory applied to hardness and elastic moduli as a function of density
in Applied Physics Letters
Beirau T
(2018)
Locally preserved a ? ß phase transition in natural radiation-damaged titanite (CaTiSiO5): evidence from laser-induced photoluminescence and dielectric measurements.
in Journal of physics. Condensed matter : an Institute of Physics journal
Ding X
(2017)
Statistics of twinning in strained ferroelastics.
in Journal of physics. Condensed matter : an Institute of Physics journal
Ding X
(2015)
Heat transport by phonons and the generation of heat by fast phonon processes in ferroelastic materials
in AIP Advances
Dul'kin E
(2014)
Ferroelectric precursor behavior of highly cation-ordered PbSc0.5Ta0.5O3 detected by acoustic emission: Tweed and polar nanoregions
in Applied Physics Letters
Fang Y
(2015)
Fe-vacancy ordering in superconducting K 1- x Fe 2- y Se 2 : first-principles calculations and Monte Carlo simulations
in Superconductor Science and Technology
Gao L
(2016)
Metastable phase transformation and hcp- ? transformation pathways in Ti and Zr under high hydrostatic pressures
in Applied Physics Letters
Gonnissen J
(2016)
Direct Observation of Ferroelectric Domain Walls in LiNbO 3 : Wall-Meanders, Kinks, and Local Electric Charges
in Advanced Functional Materials
He X
(2016)
Parabolic temporal profiles of non-spanning avalanches and their importance for ferroic switching
in Applied Physics Letters
Jiang X
(2017)
Predicting mining collapse: Superjerks and the appearance of record-breaking events in coal as collapse precursors.
in Physical review. E
Jiang X
(2016)
Collapsing minerals: Crackling noise of sandstone and coal, and the predictability of mining accidents
in American Mineralogist
Kustov S
(2017)
Twinning in Ni-Fe-Ga-Co shape memory alloy: Temperature scaling beyond the Seeger model
in Scripta Materialia
Kustov S
(2017)
Re-entrant spin glass transitions: new insights from acoustic absorption by domain walls.
in Scientific reports
Lashley JC
(2014)
Thermal avalanches near a Mott transition.
in Journal of physics. Condensed matter : an Institute of Physics journal
Li S
(2016)
Ferroelastic shear bands in Pb3(PO4)2
in Applied Physics Letters
Li S
(2014)
Strain-controlled thermal conductivity in ferroic twinned films.
in Scientific reports
Li S
(2017)
Large recovery of six-fold twinned nanowires of a-Fe
in Acta Materialia
Liu L
(2016)
Breakdown of Shape Memory Effect in Bent Cu-Al-Ni Nanopillars: When Twin Boundaries Become Stacking Faults.
in Nano letters
Lu G
(2021)
Tip-induced flexoelectricity, polar vortices, and magnetic moments in ferroelastic materials
in Journal of Applied Physics
Nataf G
(2014)
Avalanches in compressed porous Si O 2 -based materials
in Physical Review E
Nataf G
(2014)
Predicting failure: acoustic emission of berlinite under compression
in Journal of Physics: Condensed Matter
Nataf G
(2020)
Domain-wall engineering and topological defects in ferroelectric and ferroelastic materials
in Nature Reviews Physics
Nataf GF
(2016)
Influence of defects and domain walls on dielectric and mechanical resonances in LiNbO3.
in Journal of physics. Condensed matter : an Institute of Physics journal
Pan Y
(2019)
Rotatable precipitates change the scale-free to scale dependent statistics in compressed Ti nano-pillars.
in Scientific reports
Puchberger S
(2017)
The noise of many needles: Jerky domain wall propagation in PbZrO3 and LaAlO3
in APL Materials
Pöttker H
(2014)
Twin boundary profiles with linear-quadratic coupling between order parameters.
in Journal of physics. Condensed matter : an Institute of Physics journal
Pöttker H
(2016)
Flexoelectricity, incommensurate phases and the Lifshitz point.
in Journal of physics. Condensed matter : an Institute of Physics journal
Salje E
(2013)
Mechanical spectroscopy in twinned minerals: Simulation of resonance patterns at high frequencies
in American Mineralogist
Salje E
(2018)
Intermittent flow under constant forcing: Acoustic emission from creep avalanches
in Applied Physics Letters
Salje E
(2015)
Acoustic emission during the ferroelectric transition Pm3¯m to P4mm in BaTiO3 and the ferroelastic transition R3¯m-C2/c in Pb3(PO4)2
in Applied Physics Letters
Salje E
(2016)
Ferroelastic Domain Boundary-Based Multiferroicity
Salje E
(2015)
Tweed, twins, and holes
in American Mineralogist
Salje E
(2019)
Ferroelectric switching and scale invariant avalanches in BaTi O 3
in Physical Review Materials
Description | novel approach to memeory elements in industry. Large international framework collaboration as consequence of my work. We have identified routs to extend the frequency range of memory devices to higher frequency. Furthermore, we have shown that scale invariance my apply in the GHz regime which limits certain technologies to the mid GHz scale while other can extend to higher frequencies. This is important for 5G and higher technologies. In addition, we discovered a useful response pattern for collapsing mechanical structures via their emission of acoustic noise. This is useful for the preventing of mining accidents and other sudden collapse scenarios. In each case the emission of acoustic signals (via rather simple microphones developed for the testing of nuclear power stations - commercially available) is analysed in an easy protocol and the amplitude, emission sequence and repetition times are measured. The analysis then shows precursors for collapse events. |
Exploitation Route | starting an new research institute in China. This institute acquired a new building and additional funding of 1.5 million USD. We employed 5 new PhD students and PRAs. New work on security issues in coal mines. The institute has been built. We have tested some equipment in Chinese coal mines with very good success. The nano-technology side of memory devices has been further developed and discussed with US groups in similar fields. Several European grants have been started (Groningen, Paris, Bielefeld) with partial reference to our results. |
Sectors | Digital/Communication/Information Technologies (including Software) Electronics Energy Manufacturing including Industrial Biotechology |
URL | https://www.esc.cam.ac.uk/directory/ekhard-salje |
Description | Prof Scott sadly died and no further collaboration with Samsun is panned. On the other hand, our collaboration with China (Xi'an with Prof Ding) has very much expanded. My former students are now professors there. New metals and new ways to test these metals have been developed. The new buildings in China are very successful with several new collaborators there. We have also extended the program to Prof Kustov (Spain) who is the world expert in acoustic measurements of domain boundary movements. The Chinese have developed some good applications (including ultralight bicycles) which is done exclusively in China. This project is now very large and includes several laboratories. I am not planning any further grant applications in this field from RCUK. We have filed one patent ( 201410320627.5). Industry (Schlumberger) has cooperated in part of the grant. This work has terminated since no fracking activities are expected in the UK. Several larger projects have emerged from the grant such as at the ETH Zurich (by transfer of a PDRA) and in China (from 6 visitors). Further work with laboratories in Luxembourg and France are ongoing but need no support from RCUK. |
First Year Of Impact | 2012 |
Sector | Aerospace, Defence and Marine,Digital/Communication/Information Technologies (including Software),Education,Energy,Manufacturing, including Industrial Biotechology |
Impact Types | Societal Economic |
Description | Fellowship |
Amount | £217,000 (GBP) |
Organisation | The Leverhulme Trust |
Sector | Charity/Non Profit |
Country | United Kingdom |
Start | 08/2016 |
End | 08/2018 |
Description | Resonant Ultrasonic Measurements |
Organisation | University of Cambridge |
Department | Magdalene College |
Country | United Kingdom |
Sector | Academic/University |
PI Contribution | none |
Collaborator Contribution | accommodation for visitors working with me |
Impact | support for chinese and other visitors, extremely important for my collaborations. |
Start Year | 2014 |
Description | ferroelastic nano-structures |
Organisation | Xi'an Jiaotong University |
Country | China |
Sector | Academic/University |
PI Contribution | setting up a new simulation laboratory in China |
Collaborator Contribution | providing the computer facilities, man power and space in Xi'an |
Impact | output just starting. Will be in form of scientific publications. |
Start Year | 2015 |
Description | nanostructures in alloys |
Organisation | University of the Balearic Islands |
Department | Physics |
Country | Spain |
Sector | Academic/University |
PI Contribution | Sergey Kustov University of the Balearic Islands/ Spain |
Collaborator Contribution | Measurements of friction under high amplitude. Measurements of phase diagrams. |
Impact | 4 publications published or submitted |
Start Year | 2017 |
Title | Device and method for measuring yield behavior of thin film material |
Description | The invention discloses a device and a method for measuring the yield behavior of a thin film material and belongs to the technical field of material science. The device comprises a lower substrate and a to-be-tested thin film deposited on the upper surface of the lower substrate, wherein a piezoelectric sensor is arranged at one side of the to-be-tested thin film and is composed of a piezoelectric sensing material layer deposited on one side wall of the to-be-tested thin film and platinum electrode layers deposited on both the upper and lower surfaces of the piezoelectric sensing material layer; the length of the lower substrate is greater than that of the to-be-tested thin film. The device is simple and compact in structure and convenient to use; according to the method, original signals can be collected directly and the use of waveguide is avoided, and thus the subsequent analysis is facilitated and the testing technique is simple and feasible. |
IP Reference | CN104181231 |
Protection | Patent granted |
Year Protection Granted | 2014 |
Licensed | No |
Impact | We are starting to talk with industry for possible applciations. |