Augmenting Oxford's Centre for Advanced Electron Spin Resonance with a Bruker Elexsys E580 X/Q-band pulsed ESR spectrometer
Lead Research Organisation:
University of Oxford
Department Name: Oxford Physics
Abstract
The Centre for Advanced Electron Spin Resonance (CAESR) is a collaboration of researchers from the Oxford University Departments of Physics, Chemistry, Materials, Biochemistry, and Pathology. It was founded in 2006 with substantial support from EPSRC and the University to provide modern equipment and an academic focus for Oxford's multi-disciplinary research in electron spin resonance (ESR).
CAESR has been spectacularly successful. It has nucleated a world-leading community of ESR spectroscopists in Oxford, and its stakeholders now extend well beyond the original group of co-applicants. It has established a national and international reputation as a centre of excellence in ESR. CAESR's scientific productivity and the research projects that it supports are now significantly constrained by two limitations of the existing equipment: (i) the availability of only two frequencies, 9.5 GHz (X-band) and 95 GHz (W-band); and (ii) a severe shortage of experimental capacity at the "work-horse" X-band frequency.
We propose to reinforce CAESR's facilities with a Bruker Elexsys E580 X/Q-band pulsed electron spin resonance spectrometer. It will augment CAESR's facilities with a third frequency (Q-band, 35 GHz), and it will offer the experimental capacity needed by CAESR's growing community of participants. This instrument will significantly enhance CAESR's existing research projects and enable an exciting portfolio of new activities, covering a wide range of EPSRC priority areas and addressing each of EPSRC's Physics and Chemistry Grand Challenges. It will allow CAESR to apply ESR in innovative ways to new scientific problems and to lead methodological developments in ESR.
The instrument has two features that will make it unique in the UK: high-power at Q-band, offering the shortest, highest-bandwidth pulses available; and an arbitrary waveform generator, allowing the direct synthesis of complex pulses for the first time in a turn-key ESR system. For 20% of the time, the instrument will be accessible to the wider UK ESR community through collaboration with the CAESR community, and via a contract with the EPSRC National EPR Facility based in Manchester. Young scientists from the Integrated Magnetic Resonance Centre for Doctoral Training (based in Warwick) will have the opportunity to explore the cutting-edge experimental capabilities offered by the arbitrary waveform generator and high-power amplifier incorporated in the new instrument, during annual training sessions at CAESR.
The instrument's manufacturer, Bruker, seeks to strengthen links with CAESR by offering salary support for the Technical Manager. Through this interaction Bruker will receive first-hand feedback on instrument limitations, possible upgrades and new technical and methodological developments, and CAESR will receive preferential technical assistance in operating the instrumentation beyond its normal use-cases.
CAESR has been spectacularly successful. It has nucleated a world-leading community of ESR spectroscopists in Oxford, and its stakeholders now extend well beyond the original group of co-applicants. It has established a national and international reputation as a centre of excellence in ESR. CAESR's scientific productivity and the research projects that it supports are now significantly constrained by two limitations of the existing equipment: (i) the availability of only two frequencies, 9.5 GHz (X-band) and 95 GHz (W-band); and (ii) a severe shortage of experimental capacity at the "work-horse" X-band frequency.
We propose to reinforce CAESR's facilities with a Bruker Elexsys E580 X/Q-band pulsed electron spin resonance spectrometer. It will augment CAESR's facilities with a third frequency (Q-band, 35 GHz), and it will offer the experimental capacity needed by CAESR's growing community of participants. This instrument will significantly enhance CAESR's existing research projects and enable an exciting portfolio of new activities, covering a wide range of EPSRC priority areas and addressing each of EPSRC's Physics and Chemistry Grand Challenges. It will allow CAESR to apply ESR in innovative ways to new scientific problems and to lead methodological developments in ESR.
The instrument has two features that will make it unique in the UK: high-power at Q-band, offering the shortest, highest-bandwidth pulses available; and an arbitrary waveform generator, allowing the direct synthesis of complex pulses for the first time in a turn-key ESR system. For 20% of the time, the instrument will be accessible to the wider UK ESR community through collaboration with the CAESR community, and via a contract with the EPSRC National EPR Facility based in Manchester. Young scientists from the Integrated Magnetic Resonance Centre for Doctoral Training (based in Warwick) will have the opportunity to explore the cutting-edge experimental capabilities offered by the arbitrary waveform generator and high-power amplifier incorporated in the new instrument, during annual training sessions at CAESR.
The instrument's manufacturer, Bruker, seeks to strengthen links with CAESR by offering salary support for the Technical Manager. Through this interaction Bruker will receive first-hand feedback on instrument limitations, possible upgrades and new technical and methodological developments, and CAESR will receive preferential technical assistance in operating the instrumentation beyond its normal use-cases.
Planned Impact
The primary impact of this proposal is to advance scientific knowledge by equipping researchers with an exquisitely sensitive tool for understanding molecular structure and dynamics in unprecedented detail. The new pulsed X/Q-band spectrometer will impact significantly on the science output of its users in the following ways:
(i) The introduction of an extra intermediate frequency to CAESR's toolkit will allow previously impossible multifrequency studies, facilitating a much wider range of time scales and magnetic interactions to be interrogated.
(ii) Both the number of projects supported by CAESR and the quality of data obtained increase as the new instrument both doubles the number of available spectrometer hours and reduces data acquisition times.
(iii) The increased sensitivity of the spectrometer will hugely impact researchers whose samples were previously too dilute to study at CAESR (e.g., samples that cannot be synthesized in sufficient concentrations or proteins that precipitate at high concentrations).
(iv) The arbitrary waveform generator (AWG) allows much improved control over electron spin manipulation and is therefore of particular interest to CAESR's large community of users developing quantum information processing algorithms.
Either through our contract with the EPSRC National EPR Facility in Manchester, or through collaboration with CAESR members, all UK scientists with an interest in studying paramagnetic systems will benefit from the advantages of the high-power at Q-band and the AWG (both unique in the UK). Thus the facility will support the upwards trajectory of ESR science in the UK in terms of: methodological development (e.g., HiPER, CAESR); theory (e.g., Southampton, CAESR); and ESR-led applications (e.g., Cardiff, Dundee, Edinburgh, Manchester, UCL, UEA, York, Warwick, HiPER and CAESR). The acquisition of the new spectrometer will thereby promote further CAESR's and the UK's scientific impact (both through publications and conferences), expanding the international visibility of UK analytical science in general and the research areas of CAESR's stakeholders in particular.
Our wide portfolio of research interests will have potential long-term impacts in areas as diverse as (i) the design of antibiotic and anti-cancer drugs, (ii) government policy on extremely low frequency magnetic fields, (iii) an understanding of basic bacterial cell biology relevant to pathogenesis, leading to design of therapeutic pathways, (iv) the understanding of how to harvest solar energy efficiently in arrays of dye molecules, leading to efficient photovoltaic cells, (v) the understanding of charge delocalisation in molecular wires, leading to new magneto-optical materials, (vi) the development of a new generation of MRI probes capable of generating contrast through binding to receptors, (viii) the design of future renewable energy technologies and (viii) the construction of the scientific underpinnings of the emerging quantum technologies industry.
Our track record proves our commitment to and ability at training highly skilled researchers. Our programme will expand to include an annual training day for the Integrated Magnetic Resonance Centre for Doctoral Training, providing young scientists with hands-on experience of UK-unique instrumentation and advertising the spectrometer's capabilities to students from a wide variety of research groups.
Through our close relationship with Bruker, we will ensure that our methodological developments will have immediate impact on the R&D sector of the spectrometer's manufacturer. With ESR becoming ever more important in the study of proteins and their complexes, our many commercial partners and sponsors will not only benefit from our ESR-driven progress through collaborative projects but they will also be encouraged to apply the techniques with other project partners or indeed within their own R&D departments.
(i) The introduction of an extra intermediate frequency to CAESR's toolkit will allow previously impossible multifrequency studies, facilitating a much wider range of time scales and magnetic interactions to be interrogated.
(ii) Both the number of projects supported by CAESR and the quality of data obtained increase as the new instrument both doubles the number of available spectrometer hours and reduces data acquisition times.
(iii) The increased sensitivity of the spectrometer will hugely impact researchers whose samples were previously too dilute to study at CAESR (e.g., samples that cannot be synthesized in sufficient concentrations or proteins that precipitate at high concentrations).
(iv) The arbitrary waveform generator (AWG) allows much improved control over electron spin manipulation and is therefore of particular interest to CAESR's large community of users developing quantum information processing algorithms.
Either through our contract with the EPSRC National EPR Facility in Manchester, or through collaboration with CAESR members, all UK scientists with an interest in studying paramagnetic systems will benefit from the advantages of the high-power at Q-band and the AWG (both unique in the UK). Thus the facility will support the upwards trajectory of ESR science in the UK in terms of: methodological development (e.g., HiPER, CAESR); theory (e.g., Southampton, CAESR); and ESR-led applications (e.g., Cardiff, Dundee, Edinburgh, Manchester, UCL, UEA, York, Warwick, HiPER and CAESR). The acquisition of the new spectrometer will thereby promote further CAESR's and the UK's scientific impact (both through publications and conferences), expanding the international visibility of UK analytical science in general and the research areas of CAESR's stakeholders in particular.
Our wide portfolio of research interests will have potential long-term impacts in areas as diverse as (i) the design of antibiotic and anti-cancer drugs, (ii) government policy on extremely low frequency magnetic fields, (iii) an understanding of basic bacterial cell biology relevant to pathogenesis, leading to design of therapeutic pathways, (iv) the understanding of how to harvest solar energy efficiently in arrays of dye molecules, leading to efficient photovoltaic cells, (v) the understanding of charge delocalisation in molecular wires, leading to new magneto-optical materials, (vi) the development of a new generation of MRI probes capable of generating contrast through binding to receptors, (viii) the design of future renewable energy technologies and (viii) the construction of the scientific underpinnings of the emerging quantum technologies industry.
Our track record proves our commitment to and ability at training highly skilled researchers. Our programme will expand to include an annual training day for the Integrated Magnetic Resonance Centre for Doctoral Training, providing young scientists with hands-on experience of UK-unique instrumentation and advertising the spectrometer's capabilities to students from a wide variety of research groups.
Through our close relationship with Bruker, we will ensure that our methodological developments will have immediate impact on the R&D sector of the spectrometer's manufacturer. With ESR becoming ever more important in the study of proteins and their complexes, our many commercial partners and sponsors will not only benefit from our ESR-driven progress through collaborative projects but they will also be encouraged to apply the techniques with other project partners or indeed within their own R&D departments.
Publications
Hiscock HG
(2017)
Disruption of Magnetic Compass Orientation in Migratory Birds by Radiofrequency Electromagnetic Fields.
in Biophysical journal
Nielsen C
(2017)
Ascorbic acid may not be involved in cryptochrome-based magnetoreception.
in Journal of the Royal Society, Interface
Foskolou IP
(2017)
Ribonucleotide Reductase Requires Subunit Switching in Hypoxia to Maintain DNA Replication.
in Molecular cell
Peeks MD
(2017)
Electronic Delocalization in the Radical Cations of Porphyrin Oligomer Molecular Wires.
in Journal of the American Chemical Society
Honarmand Ebrahimi K
(2017)
The radical-SAM enzyme Viperin catalyzes reductive addition of a 5'-deoxyadenosyl radical to UDP-glucose in vitro.
in FEBS letters
Richert S
(2017)
On the Influence of the Bridge on Triplet State Delocalization in Linear Porphyrin Oligomers.
in Journal of the American Chemical Society
Harding RT
(2017)
Spin Resonance Clock Transition of the Endohedral Fullerene ^{15}N@C_{60}.
in Physical review letters
Richert S
(2017)
On the Importance of Electronic Symmetry for Triplet State Delocalization.
in Journal of the American Chemical Society
Liou SH
(2017)
Putidaredoxin Binds to the Same Site on Cytochrome P450cam in the Open and Closed Conformation.
in Biochemistry
Carrington B
(2017)
Natural Conformational Sampling of Human TNFa Visualized by Double Electron-Electron Resonance.
in Biophysical journal
Duan H
(2017)
Hydrodeoxygenation of water-insoluble bio-oil to alkanes using a highly dispersed Pd-Mo catalyst.
in Nature communications
Richert S
(2017)
Constructive quantum interference in a bis-copper six-porphyrin nanoring.
in Nature communications
Kattnig DR
(2017)
The sensitivity of a radical pair compass magnetoreceptor can be significantly amplified by radical scavengers.
in Scientific reports
Hetzke T
(2017)
ELDOR-detected NMR at Q-Band
in Applied Magnetic Resonance
Richert S
(2017)
Quantifying the exchange coupling in linear copper porphyrin oligomers.
in Physical chemistry chemical physics : PCCP
Doyle LR
(2018)
Reversible coordination of N2 and H2 to a homoleptic S = 1/2 Fe(i) diphosphine complex in solution and the solid state.
in Chemical science
Richert S
(2018)
Probing the orientation of porphyrin oligomers in a liquid crystal solvent - a triplet state electron paramagnetic resonance study
in Molecular Physics
Kintzel B
(2018)
Molecular electronic spin qubits from a spin-frustrated trinuclear copper complex.
in Chemical communications (Cambridge, England)
Bowen AM
(2018)
A Structural Model of a P450-Ferredoxin Complex from Orientation-Selective Double Electron-Electron Resonance Spectroscopy.
in Journal of the American Chemical Society
Evans EW
(2018)
Vibrationally Assisted Intersystem Crossing in Benchmark Thermally Activated Delayed Fluorescence Molecules.
in The journal of physical chemistry letters
Weickert S
(2018)
Conformationally Unambiguous Spin Label for Exploring the Binding Site Topology of Multivalent Systems.
in The journal of physical chemistry letters
Willke P
(2018)
Hyperfine interaction of individual atoms on a surface.
in Science (New York, N.Y.)
Slota M
(2018)
Publisher Correction: Magnetic edge states and coherent manipulation of graphene nanoribbons.
in Nature
Liu J
(2018)
Electric field control of spins in molecular magnets
Goodwin DL
(2018)
Feedback control optimisation of ESR experiments.
in Journal of magnetic resonance (San Diego, Calif. : 1997)
Yang K
(2018)
Electrically controlled nuclear polarization of individual atoms.
in Nature nanotechnology
Lewis AM
(2018)
On the low magnetic field effect in radical pair reactions.
in The Journal of chemical physics
Bowen AM
(2018)
A Structural Model of a P450-Ferredoxin Complex from Orientation-Selective Double Electron-Electron Resonance Spectroscopy.
in Journal of the American Chemical Society
Abdiaziz K
(2019)
Protein film electrochemical EPR spectroscopy as a technique to investigate redox reactions in biomolecules.
in Chemical communications (Cambridge, England)
Liu J
(2019)
Electric Field Control of Spins in Molecular Magnets.
in Physical review letters
Grabarczyk DB
(2019)
Dioxygen controls the nitrosylation reactions of a protein-bound [4Fe4S] cluster.
in Dalton transactions (Cambridge, England : 2003)
Liu J
(2019)
Unconventional Field-Induced Spin Gap in an S=1/2 Chiral Staggered Chain.
in Physical review letters
Wili N
(2019)
ELDOR-detected NMR beyond hyperfine couplings: a case study with Cu(ii)-porphyrin dimers.
in Physical chemistry chemical physics : PCCP
Yao K
(2019)
A novel Pt(iv) mono azido mono triazolato complex evolves azidyl radicals following irradiation with visible light.
in Dalton transactions (Cambridge, England : 2003)
Moise G
(2019)
Spin Delocalization in the Radical Cations of Porphyrin Molecular Wires: A New Perspective on EPR Approaches.
in The journal of physical chemistry letters
Dal Farra MG
(2019)
Light-Induced Pulsed EPR Dipolar Spectroscopy on a Paradigmatic Hemeprotein.
in Chemphyschem : a European journal of chemical physics and physical chemistry
Warren R
(2019)
Controlling energy levels and Fermi level en route to fully tailored energetics in organic semiconductors.
in Nature communications
Yang K
(2019)
Coherent spin manipulation of individual atoms on a surface.
in Science (New York, N.Y.)
Kerpal C
(2019)
Chemical compass behaviour at microtesla magnetic fields strengthens the radical pair hypothesis of avian magnetoreception.
in Nature communications
Lombardi F
(2019)
Quantum units from the topological engineering of molecular graphenoids.
in Science (New York, N.Y.)
Righetto M
(2020)
The Elusive Nature of Carbon Nanodot Fluorescence: An Unconventional Perspective
in The Journal of Physical Chemistry C
Kesava S
(2020)
Azetidinium as cation in lead mixed halide perovskite nanocrystals of optoelectronic quality
in AIP Advances
Lombardi F
(2020)
Dynamical nuclear decoupling of electron spins in molecular graphenoid radicals and biradicals
in Physical Review B
Drummond B
(2020)
Selenium Substitution Enhances Reverse Intersystem Crossing in a Delayed Fluorescence Emitter
in The Journal of Physical Chemistry C
Avalos CE
(2020)
Enhanced Intersystem Crossing and Transient Electron Spin Polarization in a Photoexcited Pentacene-Trityl Radical.
in The journal of physical chemistry. A
Sharma N
(2020)
Exciton efficiency beyond the spin statistical limit in organic light emitting diodes based on anthracene derivatives
in Journal of Materials Chemistry C
Barendt TA
(2020)
The Green Box: An Electronically Versatile Perylene Diimide Macrocyclic Host for Fullerenes.
in Journal of the American Chemical Society
Description | The Centre for Advanced Electron Spin Resonance (CAESR) is a collaboration of researchers from the Oxford University Departments of Physics, Chemistry, Materials, Biochemistry, and Pathology. It was founded in 2006 with substantial support from EPSRC and the University to provide modern equipment and an academic focus for Oxford's multi-disciplinary research in electron spin resonance (ESR). The purpose of this grant was to augment CAESR's existing facilities with (i) up-to-date equipment, allowing us to continue at the cutting-edge in the development of ESR methodologies, and (ii) extra experimental capacity, allowing an increase in the volume of internationally leading and recognised multidisciplinary research conducted at the Centre. CAESR's key scientific findings are reported in the numerous peer-reviewed publications (listed at http://caesr-web.chem.ox.ac.uk/publications.aspx) of its users. There were about 90 such publications in international peer-reviewed research journals during the course of the grant, of which six were in the leading journals Science and Nature. In this period, CAESR has trained about 140 scientists PhD and post-doc level, and offered research experience in ESR to about 100 undergraduates. In addition to facilitating the scientific findings, the grant was pivotal in contributing to CAESR becoming an internationally-recognised and world-leading centre for ESR research: CAESR users engage in numerous national and international scientific collaborations; and CAESR hosted one of the key international research conferences in the subject (the 50th Annual International Meeting of the ESR Spectroscopy Group of the Royal Society of Chemistry, http://www.esr-group.org/conferences/2017-conference-oxford/). This in turn contributes to the UK's internationally-recognised excellence in the field of ESR. |
Exploitation Route | CAESR continues to offer world-leading research facilities and a concentration of expertise to academic and industrial users in Oxford, the UK, and internationally. The scientific outputs from CAESR continue to underpin international research in a wide range of scientific disciplines. |
Sectors | Chemicals Digital/Communication/Information Technologies (including Software) Education Electronics Energy Environment Healthcare Manufacturing including Industrial Biotechology Pharmaceuticals and Medical Biotechnology |
URL | http://caesr-web.chem.ox.ac.uk/home |
Title | CCDC 1451414: Experimental Crystal Structure Determination |
Description | Related Article: Laurence R. Doyle, Daniel J. Scott, Peter J. Hill, Duncan A. X. Fraser, William K. Myers, Andrew J. P. White, Jennifer C. Green, Andrew E. Ashley|2018|Chemical Science|9|7362|doi:10.1039/C8SC01841C |
Type Of Material | Database/Collection of data |
Year Produced | 2018 |
Provided To Others? | Yes |
URL | http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc1kq9td&sid=DataCite |
Title | CCDC 1565176: Experimental Crystal Structure Determination |
Description | Related Article: Jennifer J. Le Roy, Jonathan Cremers, Isabel A. Thomlinson, Michael Slota, William K. Myers, Peter H. Horton, Simon J. Coles, Harry L. Anderson, Lapo Bogani|2018|Chemical Science|9|8474|doi:10.1039/C8SC03762K |
Type Of Material | Database/Collection of data |
Year Produced | 2018 |
Provided To Others? | Yes |
URL | http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc1pjpkg&sid=DataCite |
Title | CCDC 1565177: Experimental Crystal Structure Determination |
Description | Related Article: Jennifer J. Le Roy, Jonathan Cremers, Isabel A. Thomlinson, Michael Slota, William K. Myers, Peter H. Horton, Simon J. Coles, Harry L. Anderson, Lapo Bogani|2018|Chemical Science|9|8474|doi:10.1039/C8SC03762K |
Type Of Material | Database/Collection of data |
Year Produced | 2018 |
Provided To Others? | Yes |
URL | http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc1pjplh&sid=DataCite |
Title | CCDC 1565178: Experimental Crystal Structure Determination |
Description | Related Article: Jennifer J. Le Roy, Jonathan Cremers, Isabel A. Thomlinson, Michael Slota, William K. Myers, Peter H. Horton, Simon J. Coles, Harry L. Anderson, Lapo Bogani|2018|Chemical Science|9|8474|doi:10.1039/C8SC03762K |
Type Of Material | Database/Collection of data |
Year Produced | 2018 |
Provided To Others? | Yes |
URL | http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc1pjpmj&sid=DataCite |
Title | CCDC 1565179: Experimental Crystal Structure Determination |
Description | Related Article: Jennifer J. Le Roy, Jonathan Cremers, Isabel A. Thomlinson, Michael Slota, William K. Myers, Peter H. Horton, Simon J. Coles, Harry L. Anderson, Lapo Bogani|2018|Chemical Science|9|8474|doi:10.1039/C8SC03762K |
Type Of Material | Database/Collection of data |
Year Produced | 2018 |
Provided To Others? | Yes |
URL | http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc1pjpnk&sid=DataCite |
Title | CCDC 1565180: Experimental Crystal Structure Determination |
Description | Related Article: Jennifer J. Le Roy, Jonathan Cremers, Isabel A. Thomlinson, Michael Slota, William K. Myers, Peter H. Horton, Simon J. Coles, Harry L. Anderson, Lapo Bogani|2018|Chemical Science|9|8474|doi:10.1039/C8SC03762K |
Type Of Material | Database/Collection of data |
Year Produced | 2018 |
Provided To Others? | Yes |
URL | http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc1pjppl&sid=DataCite |
Title | CCDC 1565181: Experimental Crystal Structure Determination |
Description | Related Article: Jennifer J. Le Roy, Jonathan Cremers, Isabel A. Thomlinson, Michael Slota, William K. Myers, Peter H. Horton, Simon J. Coles, Harry L. Anderson, Lapo Bogani|2018|Chemical Science|9|8474|doi:10.1039/C8SC03762K |
Type Of Material | Database/Collection of data |
Year Produced | 2018 |
Provided To Others? | Yes |
URL | http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc1pjpqm&sid=DataCite |
Title | CCDC 1565182: Experimental Crystal Structure Determination |
Description | Related Article: Jennifer J. Le Roy, Jonathan Cremers, Isabel A. Thomlinson, Michael Slota, William K. Myers, Peter H. Horton, Simon J. Coles, Harry L. Anderson, Lapo Bogani|2018|Chemical Science|9|8474|doi:10.1039/C8SC03762K |
Type Of Material | Database/Collection of data |
Year Produced | 2018 |
Provided To Others? | Yes |
URL | http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc1pjprn&sid=DataCite |
Title | CCDC 1565183: Experimental Crystal Structure Determination |
Description | Related Article: Jennifer J. Le Roy, Jonathan Cremers, Isabel A. Thomlinson, Michael Slota, William K. Myers, Peter H. Horton, Simon J. Coles, Harry L. Anderson, Lapo Bogani|2018|Chemical Science|9|8474|doi:10.1039/C8SC03762K |
Type Of Material | Database/Collection of data |
Year Produced | 2018 |
Provided To Others? | Yes |
URL | http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc1pjpsp&sid=DataCite |
Title | CCDC 1565184: Experimental Crystal Structure Determination |
Description | Related Article: Jennifer J. Le Roy, Jonathan Cremers, Isabel A. Thomlinson, Michael Slota, William K. Myers, Peter H. Horton, Simon J. Coles, Harry L. Anderson, Lapo Bogani|2018|Chemical Science|9|8474|doi:10.1039/C8SC03762K |
Type Of Material | Database/Collection of data |
Year Produced | 2018 |
Provided To Others? | Yes |
URL | http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc1pjptq&sid=DataCite |
Title | CCDC 1565185: Experimental Crystal Structure Determination |
Description | Related Article: Jennifer J. Le Roy, Jonathan Cremers, Isabel A. Thomlinson, Michael Slota, William K. Myers, Peter H. Horton, Simon J. Coles, Harry L. Anderson, Lapo Bogani|2018|Chemical Science|9|8474|doi:10.1039/C8SC03762K |
Type Of Material | Database/Collection of data |
Year Produced | 2018 |
Provided To Others? | Yes |
URL | http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc1pjpvr&sid=DataCite |
Title | CCDC 1565186: Experimental Crystal Structure Determination |
Description | Related Article: Jennifer J. Le Roy, Jonathan Cremers, Isabel A. Thomlinson, Michael Slota, William K. Myers, Peter H. Horton, Simon J. Coles, Harry L. Anderson, Lapo Bogani|2018|Chemical Science|9|8474|doi:10.1039/C8SC03762K |
Type Of Material | Database/Collection of data |
Year Produced | 2018 |
Provided To Others? | Yes |
URL | http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc1pjpws&sid=DataCite |
Title | CCDC 1565187: Experimental Crystal Structure Determination |
Description | Related Article: Jennifer J. Le Roy, Jonathan Cremers, Isabel A. Thomlinson, Michael Slota, William K. Myers, Peter H. Horton, Simon J. Coles, Harry L. Anderson, Lapo Bogani|2018|Chemical Science|9|8474|doi:10.1039/C8SC03762K |
Type Of Material | Database/Collection of data |
Year Produced | 2018 |
Provided To Others? | Yes |
URL | http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc1pjpxt&sid=DataCite |
Title | CCDC 1565188: Experimental Crystal Structure Determination |
Description | Related Article: Jennifer J. Le Roy, Jonathan Cremers, Isabel A. Thomlinson, Michael Slota, William K. Myers, Peter H. Horton, Simon J. Coles, Harry L. Anderson, Lapo Bogani|2018|Chemical Science|9|8474|doi:10.1039/C8SC03762K |
Type Of Material | Database/Collection of data |
Year Produced | 2018 |
Provided To Others? | Yes |
URL | http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc1pjpyv&sid=DataCite |
Title | CCDC 1963000: Experimental Crystal Structure Determination |
Description | Related Article: Daniel W. N. Wilson, Mauricio P. Franco, William K. Myers, John E. McGrady, Jose M. Goicoechea|2020|Chemical Science|11|862|doi:10.1039/C9SC05969E |
Type Of Material | Database/Collection of data |
Year Produced | 2019 |
Provided To Others? | Yes |
URL | http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc23wnl8&sid=DataCite |
Title | CCDC 1963001: Experimental Crystal Structure Determination |
Description | Related Article: Daniel W. N. Wilson, Mauricio P. Franco, William K. Myers, John E. McGrady, Jose M. Goicoechea|2020|Chemical Science|11|862|doi:10.1039/C9SC05969E |
Type Of Material | Database/Collection of data |
Year Produced | 2019 |
Provided To Others? | Yes |
URL | http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc23wnm9&sid=DataCite |
Title | CCDC 1963002: Experimental Crystal Structure Determination |
Description | Related Article: Daniel W. N. Wilson, Mauricio P. Franco, William K. Myers, John E. McGrady, Jose M. Goicoechea|2020|Chemical Science|11|862|doi:10.1039/C9SC05969E |
Type Of Material | Database/Collection of data |
Year Produced | 2019 |
Provided To Others? | Yes |
URL | http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc23wnnb&sid=DataCite |
Title | CCDC 1963003: Experimental Crystal Structure Determination |
Description | Related Article: Daniel W. N. Wilson, Mauricio P. Franco, William K. Myers, John E. McGrady, Jose M. Goicoechea|2020|Chemical Science|11|862|doi:10.1039/C9SC05969E |
Type Of Material | Database/Collection of data |
Year Produced | 2019 |
Provided To Others? | Yes |
URL | http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc23wnpc&sid=DataCite |
Title | CCDC 1963004: Experimental Crystal Structure Determination |
Description | Related Article: Daniel W. N. Wilson, Mauricio P. Franco, William K. Myers, John E. McGrady, Jose M. Goicoechea|2020|Chemical Science|11|862|doi:10.1039/C9SC05969E |
Type Of Material | Database/Collection of data |
Year Produced | 2019 |
Provided To Others? | Yes |
URL | http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc23wnqd&sid=DataCite |
Title | CCDC 1963005: Experimental Crystal Structure Determination |
Description | Related Article: Daniel W. N. Wilson, Mauricio P. Franco, William K. Myers, John E. McGrady, Jose M. Goicoechea|2020|Chemical Science|11|862|doi:10.1039/C9SC05969E |
Type Of Material | Database/Collection of data |
Year Produced | 2019 |
Provided To Others? | Yes |
URL | http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc23wnrf&sid=DataCite |
Title | CCDC 1963006: Experimental Crystal Structure Determination |
Description | Related Article: Daniel W. N. Wilson, Mauricio P. Franco, William K. Myers, John E. McGrady, Jose M. Goicoechea|2020|Chemical Science|11|862|doi:10.1039/C9SC05969E |
Type Of Material | Database/Collection of data |
Year Produced | 2019 |
Provided To Others? | Yes |
URL | http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc23wnsg&sid=DataCite |
Title | CCDC 2008628: Experimental Crystal Structure Determination |
Description | Related Article: Kezi Yao, Arnau Bertran, Jacques Morgan, Charlotte Greenhalgh, Katharina Edkins, Alice M. Bowen, Nicola J. Farrer|2021|Eur.J.Inorg.Chem.|2021|1397|doi:10.1002/ejic.202100041 |
Type Of Material | Database/Collection of data |
Year Produced | 2021 |
Provided To Others? | Yes |
URL | http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc25f4g7&sid=DataCite |
Title | CCDC 2025224: Experimental Crystal Structure Determination |
Description | Related Article: Daniel W. N. Wilson, William K. Myers, Jose M. Goicoechea|2020|Dalton Trans.|49|15249|doi:10.1039/D0DT03174G |
Type Of Material | Database/Collection of data |
Year Produced | 2020 |
Provided To Others? | Yes |
URL | http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc25zdtd&sid=DataCite |
Title | CCDC 2025225: Experimental Crystal Structure Determination |
Description | Related Article: Daniel W. N. Wilson, William K. Myers, Jose M. Goicoechea|2020|Dalton Trans.|49|15249|doi:10.1039/D0DT03174G |
Type Of Material | Database/Collection of data |
Year Produced | 2020 |
Provided To Others? | Yes |
URL | http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc25zdvf&sid=DataCite |
Title | CCDC 2025226: Experimental Crystal Structure Determination |
Description | Related Article: Daniel W. N. Wilson, William K. Myers, Jose M. Goicoechea|2020|Dalton Trans.|49|15249|doi:10.1039/D0DT03174G |
Type Of Material | Database/Collection of data |
Year Produced | 2020 |
Provided To Others? | Yes |
URL | http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc25zdwg&sid=DataCite |
Title | CCDC 2025227: Experimental Crystal Structure Determination |
Description | Related Article: Daniel W. N. Wilson, William K. Myers, Jose M. Goicoechea|2020|Dalton Trans.|49|15249|doi:10.1039/D0DT03174G |
Type Of Material | Database/Collection of data |
Year Produced | 2020 |
Provided To Others? | Yes |
URL | http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc25zdxh&sid=DataCite |
Title | CCDC 2025228: Experimental Crystal Structure Determination |
Description | Related Article: Daniel W. N. Wilson, William K. Myers, Jose M. Goicoechea|2020|Dalton Trans.|49|15249|doi:10.1039/D0DT03174G |
Type Of Material | Database/Collection of data |
Year Produced | 2020 |
Provided To Others? | Yes |
URL | http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc25zdyj&sid=DataCite |
Title | CCDC 2025229: Experimental Crystal Structure Determination |
Description | Related Article: Daniel W. N. Wilson, William K. Myers, Jose M. Goicoechea|2020|Dalton Trans.|49|15249|doi:10.1039/D0DT03174G |
Type Of Material | Database/Collection of data |
Year Produced | 2020 |
Provided To Others? | Yes |
URL | http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc25zdzk&sid=DataCite |
Title | CCDC 2025230: Experimental Crystal Structure Determination |
Description | Related Article: Daniel W. N. Wilson, William K. Myers, Jose M. Goicoechea|2020|Dalton Trans.|49|15249|doi:10.1039/D0DT03174G |
Type Of Material | Database/Collection of data |
Year Produced | 2020 |
Provided To Others? | Yes |
URL | http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc25zf0m&sid=DataCite |
Title | CCDC 2025231: Experimental Crystal Structure Determination |
Description | Related Article: Daniel W. N. Wilson, William K. Myers, Jose M. Goicoechea|2020|Dalton Trans.|49|15249|doi:10.1039/D0DT03174G |
Type Of Material | Database/Collection of data |
Year Produced | 2020 |
Provided To Others? | Yes |
URL | http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc25zf1n&sid=DataCite |
Title | CCDC 2025232: Experimental Crystal Structure Determination |
Description | Related Article: Daniel W. N. Wilson, William K. Myers, Jose M. Goicoechea|2020|Dalton Trans.|49|15249|doi:10.1039/D0DT03174G |
Type Of Material | Database/Collection of data |
Year Produced | 2020 |
Provided To Others? | Yes |
URL | http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc25zf2p&sid=DataCite |
Title | CCDC 2063252: Experimental Crystal Structure Determination |
Description | Related Article: Ying Kai Loh, Petra Vasko, Caitilín McManus, Andreas Heilmann, William K. Myers, Simon Aldridge|2021|Nat.Commun.|12|7052|doi:10.1038/s41467-021-27104-y |
Type Of Material | Database/Collection of data |
Year Produced | 2021 |
Provided To Others? | Yes |
URL | http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc277zj0&sid=DataCite |
Title | CCDC 2063253: Experimental Crystal Structure Determination |
Description | Related Article: Ying Kai Loh, Petra Vasko, Caitilín McManus, Andreas Heilmann, William K. Myers, Simon Aldridge|2021|Nat.Commun.|12|7052|doi:10.1038/s41467-021-27104-y |
Type Of Material | Database/Collection of data |
Year Produced | 2021 |
Provided To Others? | Yes |
URL | http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc277zk1&sid=DataCite |
Title | CCDC 2063254: Experimental Crystal Structure Determination |
Description | Related Article: Ying Kai Loh, Petra Vasko, Caitilín McManus, Andreas Heilmann, William K. Myers, Simon Aldridge|2021|Nat.Commun.|12|7052|doi:10.1038/s41467-021-27104-y |
Type Of Material | Database/Collection of data |
Year Produced | 2021 |
Provided To Others? | Yes |
URL | http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc277zl2&sid=DataCite |
Title | CCDC 2090406: Experimental Crystal Structure Determination |
Description | Related Article: Richard R. Surgenor, Xiangqian Liu, Morgan J. H. Keenlyside, William Myers, Martin D. Smith|2022|Nature Chemistry|15|357|doi:10.1038/s41557-022-01095-9 |
Type Of Material | Database/Collection of data |
Year Produced | 2022 |
Provided To Others? | Yes |
URL | http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc2857g5&sid=DataCite |
Title | Raw Data supporting article: Protein film electrochemical EPR spectroscopy as a technique to investigate redox reactions in biomolecules |
Description | See the file 'Metadata' for a detailed description of the dataset. The research project these data have originated from, the research and data collection methods, and results of the research project are described in: Kaltum Abdiaziz, Enrico Salvadori, Katarzyna P. Sokol, Erwin Reisner, Maxie M. Roessler, Chemical Communications, 2019. Methods: Electron paramagnetic resonance spectroscopy, protein film electrochemistry, electrochemical impedance spectroscopy, UV-Vis spectroscopy. |
Type Of Material | Database/Collection of data |
Year Produced | 2020 |
Provided To Others? | Yes |
URL | https://www.repository.cam.ac.uk/handle/1810/314813 |
Title | Research data supporting "Vibrationally Assisted Intersystem Crossing in Benchmark Thermally Activated Delayed Fluorescence Molecules" |
Description | Raw data for manuscript titled 'Vibrationally-assisted intersystem crossing in benchmark thermally activated delayed fluorescence molecules.' Data includes absorption and photoluminescence spectra for 2CzPN and 4CzIPN (Fig1b_Abs_2CzPN, Fig1b_Abs_4CzIPN, Fig1b_PL_2CzPN, Fig1b_PL_4CzIPN); transient electron spin resonance spectra for 2CzPN and 4CzIPN (Fig2c_2CzPN_0p4us, Fig2d_4CzIPN_0p4us); probability distributions for zero-field splitting in 2CzPN and 4CzIPN (Fig3a_2CzPN_ZFS_probability_distribution, Fig3b_4CzIPN_ZFS_probability_distribution); plots of zero-field splitting as a function of overlap index in 2CzPN and 4CzIPN (Fig3c_2CzPN_ZFS_overlap_idx, Fig3d_4CzIPN_ZFS_overlap_idx); and density plots (field versus time) of transient electron spin resonance spectra of 2CzPN and 4CzIPN (FigS1_TrESR_2CzPN_420nm_exc, FigS1_TrESR_4CzIPN_460nm_exc). |
Type Of Material | Database/Collection of data |
Year Produced | 2018 |
Provided To Others? | Yes |
URL | https://www.repository.cam.ac.uk/handle/1810/277932 |
Title | Research data supporting 'Reversible spin-optical interface in luminescent organic radicals' |
Description | Contains data from optical spectroscopy, electron spin resonance, optically detected magnetic resonance, and theoretical calculations. |
Type Of Material | Database/Collection of data |
Year Produced | 2023 |
Provided To Others? | Yes |
URL | https://www.repository.cam.ac.uk/handle/1810/354250 |