Ferroelectric, Ferroelastic and Multiferroic Domain Walls: a New Horizon in Nanoscale Functional Materials
Lead Research Organisation:
University of Cambridge
Department Name: Earth Sciences
Abstract
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Organisations
Publications
Salje E
(2020)
Ferroelastic domain walls as templates for multiferroic devices
in Journal of Applied Physics
Chen Y
(2022)
Acoustic emission spectra and statistics of dislocation movements in Fe40Mn40Co10Cr10 high entropy alloys
in Journal of Applied Physics
Fernandez-Posada C
(2022)
Magnetoelastic properties of multiferroic hexagonal ErMnO3
in Journal of Magnetism and Magnetic Materials
Chen Y
(2021)
Real-time monitoring dislocations, martensitic transformations and detwinning in stainless steel: Statistical analysis and machine learning
in Journal of Materials Science & Technology
Yokota H
(2020)
Enhancement of polar nature of domain boundaries in ferroelastic Pb3(PO4)2 by doping divalent-metal ions.
in Journal of physics. Condensed matter : an Institute of Physics journal
Zhang L
(2020)
Coupling between phase transitions and glassy magnetic behaviour in Heusler alloy Ni50Mn34In8Ga8.
in Journal of physics. Condensed matter : an Institute of Physics journal
Fernandez-Posada CM
(2021)
Order-disorder, ferroelasticity and mobility of domain walls in multiferroic Cu-Cl boracite.
in Journal of physics. Condensed matter : an Institute of Physics journal
Beirau T
(2018)
Locally preserved a ? ß phase transition in natural radiation-damaged titanite (CaTiSiO5): evidence from laser-induced photoluminescence and dielectric measurements.
in Journal of physics. Condensed matter : an Institute of Physics journal
Carpenter MA
(2021)
Strain relaxation dynamics of multiferroic orthorhombic manganites.
in Journal of physics. Condensed matter : an Institute of Physics journal
Wang L
(2021)
Cracking of human teeth: An avalanche and acoustic emission study.
in Journal of the mechanical behavior of biomedical materials
Description | We have identified unique combinations of microstructures in crystals which undergo phase transitions - with a focus on vortices and twin walls in materials including BaTiO3, ferroelectric tungsten bronzes, multiferroic orthorhombic perovskites, pnictide superconductors. This work has expanded greatly in terms of the range of domain wall materials that we have investigated successfully, and in terms of our successful collaborations with other members of the network group. More specifically, domain wall switching and the internal wall structure has been shown to divide into two categories: wild and mild. Wild switching results in highly correlated movements with power law statistics. This means that this switching is scale invariant in time and space and hence allows for high frequency applications in mobile phones etc. Mild switching is thermally activated and dominates in the deformation of wires, bio-mineralisation and some medical applications. Here the choice of the optimal frequency in key and applications rely not only on the amplitude of the switching process but also on the time span and hence the frequency of the pertubation. Ferroelectric switching, such as in BaTiO3, was shown to be history dependent and the nature of the morphotropic boundary in the commonly used material PZT was identified. It consists of highly correlated clusters of ferroelectric domains which act as units rather than splitting into individual domain walls. The same effect was found in cryogenic SrTiO3 near the quantum critical point where all domain movements become fully coherent. These effects dominate the mechanical properties (like the elasticity) of the material and generate piezoelectricity in nominally cubic materials. In theory, we have clarified wall-wall interactions in the bulk and in thin films, the interaction between domain boundaries with surfaces and the role of percolation in domain wall movements. We predicted weak magnetic signals when moving ferroelastic wall even without any magnetic atoms in the bulk. We identified the mixing properties of movements of different origin (like twin walls, dislocations, atomic defect displacements etc) during acoustic emission experiment which enlarges the way such techniques can now be used. |
Exploitation Route | We are expecting that the scientific progress we have made with respect to understanding the structure, dynamics and properties of domain walls will be of significant assistance to the electronics industry involved in the development of new nanoscale devices. Our work has been on fundamental aspects of the ways in which domain walls arising at phase transitions evolve, interact with each other and interact with strain fields. It forms the basis for ongoing research focussed more specifically on "Materials for neuromorphic circuits", a Marie-Curie network funded by the EU. |
Sectors | Electronics |