Chemistry and physics of conjugated coordination nanosheets and two-dimensional conjugated polymers
Lead Research Organisation:
University of Cambridge
Department Name: Physics
Abstract
The optoelectronic properties of conjugated polymers have improved to levels of performance that now enable industrial applications in large-area electronics, displays, bioelectronics and photovoltaics. However, the one-dimensional (1D) nature of charge transport along the backbone of a conventional conjugated polymer still imposes fundamental limits on the achievable charge carrier mobilities and electronic properties. In the proposed project we aim to develop a novel class of 2-dimensional (2D) conjugated polymers and coordination nanosheets (CONASHs), which have recently become synthetically accessible through coordination chemistry and promise to overcome the traditional limitations of 1D polymers. The aim of the proposed project is to investigate the fundamental chemistry and physics of these novel materials, in particular investigate the molecular structure - charge transport relationships, explore their fundamental, exotic physical transport properties and develop them as high performance materials for energy and electronic applications, in particular in thermoelectrics, energy storage, light-emission and chemical and biological sensors. The project will establish a close, interdisciplinary network between internationally leading chemistry and physics groups in this field (Nishihara - University of Tokyo, Sirringhaus -University of Cambridge, Feng - Technical University of Dresden, Zhu/Zhang - Chinese Academy of Sciences, Beijing).
Planned Impact
In contrast to other 2D materials such as graphene or metal chalcogenides coordination nanosheets can be grown in a controlled manner by a bottom-up chemical synthesis reacting metal ion precursors and organic molecules that progresses under mild conditions and gives access to a wide variety of chemical structures and porous geometric structures by combining different metal ions and organic ligands. This allows tailored design of materials for specific physical, chemical and mechanical properties. These materials exhibit very interesting physical and chemical properties, including redox, photo and catalytic functionality, and might even exhibit exotic physical properties, such as topological insulator behavior. The chemistry, physics and electronics of these materials is a rapidly expanding international research field and the future development of these materials would greatly benefit from a close international research collaboration that is the aim of this proposal. In the proposed research exchange we will advance the development of CONASHs and 2D polymers by bringing together leading international researchers from different disciplines across chemistry, physics and materials science. We see significant potential for creating a new functional materials platform with enhanced levels of device performance for a broad range of applications, including electronics, optoelectronics, energy storage, thermoelectrics as well as chemical and biological sensing.
While the focus of the network is primarily on academic collaboration all five senior investigators have extensive experience in collaborating with industry and in exploiting opportunities for transfering fundamental materials inventions to industry. Prof. Sirringhaus, for example, is cofounder and Chief Scientist of Plastic Logic/FlexEnable, a spin-off company commercialising flexible electronics, and cofounder of Eight 19, which is commercialising organic solar cell technology. The five senior investigators will continuously monitor and assess potential application opportunities for conjugated coordination nanosheets and 2D conjugated polymers and will take appropriate steps to protect arising intellectual property. For this the partners will enter into a collaboration agreement that will set out the terms for filing and exploitation of intellectual property generated within the network. After protection of the IP they will explore different commercialisation paths, including collaboration with industrial companies or the formation of spin-off companies. All four partners have effective technology transfer organisations, such as Cambridge Enterprise at the University of Cambridge, which will work together and follow best practice in commercialisation when such opportunities arise.
The most important impact from the project is however likely to be the training of a cohort of young scientific researchers who will learn to undertake interdisciplinary and collaborative science at the highest international level. Many of these young researchers will in due course lead their own research initiatives and will become proponents of an open science system that seeks to advance scientific knowledge effectively by making optimum use of complementary skills available in different countries and institutions and to share scientific knowledge widely for the benefit of mankind.
While the focus of the network is primarily on academic collaboration all five senior investigators have extensive experience in collaborating with industry and in exploiting opportunities for transfering fundamental materials inventions to industry. Prof. Sirringhaus, for example, is cofounder and Chief Scientist of Plastic Logic/FlexEnable, a spin-off company commercialising flexible electronics, and cofounder of Eight 19, which is commercialising organic solar cell technology. The five senior investigators will continuously monitor and assess potential application opportunities for conjugated coordination nanosheets and 2D conjugated polymers and will take appropriate steps to protect arising intellectual property. For this the partners will enter into a collaboration agreement that will set out the terms for filing and exploitation of intellectual property generated within the network. After protection of the IP they will explore different commercialisation paths, including collaboration with industrial companies or the formation of spin-off companies. All four partners have effective technology transfer organisations, such as Cambridge Enterprise at the University of Cambridge, which will work together and follow best practice in commercialisation when such opportunities arise.
The most important impact from the project is however likely to be the training of a cohort of young scientific researchers who will learn to undertake interdisciplinary and collaborative science at the highest international level. Many of these young researchers will in due course lead their own research initiatives and will become proponents of an open science system that seeks to advance scientific knowledge effectively by making optimum use of complementary skills available in different countries and institutions and to share scientific knowledge widely for the benefit of mankind.
People |
ORCID iD |
Henning Sirringhaus (Principal Investigator) |
Publications
Zhang J
(2023)
Wavy Two-Dimensional Conjugated Metal-Organic Framework with Metallic Charge Transport
in Journal of the American Chemical Society
Zhang Y
(2023)
Transmission-based charge modulation microscopy on conjugated polymer blend field-effect transistors.
in The Journal of chemical physics
Selezneva E
(2021)
Strong Suppression of Thermal Conductivity in the Presence of Long Terminal Alkyl Chains in Low-Disorder Molecular Semiconductors.
in Advanced materials (Deerfield Beach, Fla.)
Tan C
(2024)
Lateral Heterometal Junction Rectifier Fabricated by Sequential Transmetallation of Coordination Nanosheet**
in Angewandte Chemie
Tan C
(2024)
Lateral Heterometal Junction Rectifier Fabricated by Sequential Transmetallation of Coordination Nanosheet**
in Angewandte Chemie International Edition
Kang K
(2019)
Investigation of the thermoelectric response in conducting polymers doped by solid-state diffusion
in Materials Today Physics
Selezneva E
(2019)
Investigation of the effect of microstructural changes on thermal transport in semicrystalline polymer semiconductors
in APL Materials
Description | Identification of two-dimensional, conjugated metal organic framework as a promising material class for thermoelectric applications. Development of a new family of conjugated metal organic frameworks that contain more than one transition metal species which provides a new approach to tuning of the electrial, thermoelectric properties of these materials. |
Exploitation Route | Further optimisation of materials and improvement of performance is needed before exploitation opportunities can be considered. |
Sectors | Energy |
Description | Invited talk at the Centre for Science and Policy (CSaP), Cambridge, UK |
Geographic Reach | National |
Policy Influence Type | Influenced training of practitioners or researchers |
Impact | The talk and discussion contributed to a better understanding of the opportunities and challenges associated with the development of advanced materials for the energy transition. |
URL | https://www.csap.cam.ac.uk/network/policy-fellowship/1326-647e22e882cabf877d9457b1f6c54a5fd23fc0de/ |
Title | Small research facility for thermoelectric characterisation |
Description | With support from the grant we have maintained and optimized a measurement system for characterising thermoelectric materials that is part of the Henry Royce Institute @ Cambridge. |
Type Of Material | Improvements to research infrastructure |
Year Produced | 2019 |
Provided To Others? | No |
Impact | The optimized measurement protocols and methods that allow more accurate measurements of thermoelectric coefficients are being made available to all users of this facility. |
Title | Research data supporting Improving OFF-State Bias-Stress Stability in High-Mobility Conjugated Polymer Transistors with an Antisolvent Treatment |
Description | Data to accompany "Improving OFF-State Bias-Stress Stability in High-Mobility Conjugated Polymer Transistors with an Antisolvent Treatment" by Nguyen et al. The zip folder contains subfolders labelled with the figure numbers that can be referred to in the paper. All the subfolders contain raw data either in a .txt or .csv format. The imAFM data from Figure 4 is in .imp (intermodulation) format. Data analysis was carried out using python as described in methods and figure captions of the paper. |
Type Of Material | Database/Collection of data |
Year Produced | 2023 |
Provided To Others? | Yes |
URL | https://www.repository.cam.ac.uk/handle/1810/349080 |
Description | Collaboration with Chinese Academy of Sciences |
Organisation | Chinese Academy of Sciences |
Country | China |
Sector | Public |
PI Contribution | Evaluation of charge transport properties of novel organic semiconductors |
Collaborator Contribution | Synthesis of materials |
Impact | Identification of promising materials targets for next generation materials |
Start Year | 2019 |
Description | Technical University of Dresden |
Organisation | Technical University of Dresden |
Country | Germany |
Sector | Academic/University |
PI Contribution | Evaluation of charge transport properties of two-dimensional metal organic frameworks |
Collaborator Contribution | Synthesis of materials |
Impact | Identification of promising materials targets for next generation materials |
Start Year | 2019 |
Description | University of Tokyo |
Organisation | University of Tokyo |
Country | Japan |
Sector | Academic/University |
PI Contribution | Evaluation of materials provided by collaborators in Tokyo |
Collaborator Contribution | Synthesis of 2-dimensional metal organif framework precursors |
Impact | Exchange of several visiting students between Tokyo and Cambridge |
Start Year | 2019 |
Description | Organisation of International Workshop on two-dimensional conjugated coordination nanosheets (CONASHs), Cambridge, UK |
Form Of Engagement Activity | Participation in an activity, workshop or similar |
Part Of Official Scheme? | No |
Geographic Reach | International |
Primary Audience | Professional Practitioners |
Results and Impact | We organised an International Workshop on two-dimensional conjugated coordination nanosheets (CONASHs), Cambridge, UK, on March 8-9, which was attended by scientists from UK, Japan and Germany. |
Year(s) Of Engagement Activity | 2023 |
Description | Organisation of International Workshop on two-dimensional conjugated coordination nanosheets (CONASHs), Dresden, Germany |
Form Of Engagement Activity | Participation in an activity, workshop or similar |
Part Of Official Scheme? | No |
Geographic Reach | International |
Primary Audience | Professional Practitioners |
Results and Impact | We organised an International Workshop on two-dimensional conjugated coordination nanosheets (CONASHs) in Dresden, Germany, on December 11-12, 2023. It was attended by scientists from Japan, UK, and Germany. |
Year(s) Of Engagement Activity | 2023 |
Description | Two-day international workshop on chemistry and physics of two-dimensional metal organic frameworks |
Form Of Engagement Activity | Participation in an activity, workshop or similar |
Part Of Official Scheme? | No |
Geographic Reach | International |
Primary Audience | Postgraduate students |
Results and Impact | Two-day international workshop on chemistry and physics of two-dimensional metal organic frameworks held in Cambridge, attended by 30 researchers from UK, Japan and Germany |
Year(s) Of Engagement Activity | 2019 |
Description | Two-day international workshop on chemistry and physics of two-dimensional metal organic frameworks |
Form Of Engagement Activity | Participation in an activity, workshop or similar |
Part Of Official Scheme? | No |
Geographic Reach | International |
Primary Audience | Postgraduate students |
Results and Impact | Two-day international workshop on chemistry and physics of two-dimensional metal organic frameworks held in Tokyo, Japan, attended by researchers from Japan, UK and China |
Year(s) Of Engagement Activity | 2019 |