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Resolving climate sensitivity associated with shallow mixed phase cloud in the oceanic mid- to high-latitudes (M-Phase)

Lead Research Organisation: University of Leeds
Department Name: School of Earth and Environment

Abstract

Clouds containing a mixture of ice and water (mixed-phase clouds) are likely to change in response to climate change. It is expected that warming will cause an increase in the amount of water and a decrease in the amount of ice in these clouds. Because water droplets reflect more solar radiation than ice crystals (and cause less precipitation), the clouds are expected to become brighter, thereby causing a cooling effect (or negative feedback) on the climate system at mid- to high-latitudes.

The magnitude of the cloud-phase feedback is very uncertain. If the feedback is strong then global temperatures will increase more slowly in future, but if it is weak then temperatures will increase more rapidly. It was recently shown that adjusting the ratio of ice and water in a climate model to match satellite observations could increase Earth's equilibrium climate sensitivity (warming with a doubling of CO2) by 1.5 degrees; hence, Earth may warm faster than thought. The feedback process is further complicated by the fact that the special particles, ice nucleating particles (INPs), which trigger ice production, may be more abundant in a warmer world where INP sources, such as glacial valleys, will be covered in ice and snow for less time. Increased INP concentrations would mean more ice in clouds and lead to a positive feedback. These two opposing feedbacks contribute to what we refer to as the cloud-phase feedback.

This proposal will improve our understanding of how ice particles form in clouds and how this affects the cloud-phase feedback. Ice formation is the key process that controls this feedback. The problem can be broken down into two parts:
First, we will address the open questions related to the chain of processes that link initial ice formation to the reflectivity of the clouds and how the reflectivity will change with warming. We have designed an aircraft campaign targeted at conditions of most relevance to the cloud feedback problem: moderately cold clouds that will be most sensitive to changes in temperature, and where high INP concentrations are likely to influence large regions of the N Atlantic. These cold-air outbreaks clouds provide an ideal meteorological situation for studying the formation and evolution of the kinds of shallow mixed-phase clouds which are important for cloud feedbacks.
Second, we will address the paucity of knowledge on the sources, distribution and seasonal cycles of INPs at the mid- to high-latitudes. Our strategy is to use measurements to identify sources of INPs and use this information to inform the inclusion of mid- to high-latitude sources in our global model of INPs. We will perform new long-term measurements through a whole year and ship borne measurements through the key source regions in the Arctic. We have built a substantial network of Partners who will contribute INP data across the northern and southern mid- to high-latitudes which will allow us to expand our study to the globe.

The new knowledge on cloud processes and INP will be used to improve the representation of mixed-phase clouds in the Met Office weather and climate model. The model will be run at very high spatial resolution so that the individual clouds in the cold-air outbreaks can be simulated. The model will be tested and improved by comparing it to our measurements as well as against satellite observations. We will then extend this study to contrasting cases from the Southern Ocean and the other side of the Atlantic. We anticipate the new knowledge will lead to a greatly improved representation of these climatically critical clouds. We will then perform a sensitivity analysis on selected cases in order to test how these cloud systems will respond to climate change. Finally, we will use the new knowledge to develop a plan for improving how mixed-phase clouds are treated in global climate models so that this work can be carried out in a follow-on project.

Planned Impact

M-Phase is focused on reducing the uncertainty associated with equilibrium climate sensitivity through improving the representation of the cloud-phase feedback. This will lead to impact in several areas:

Climate prediction
The value of reducing uncertainties in climate sensitivity has been estimated to be in the trillions of dollars (Hope, 2014, doi:doi:10.1098/rsta.2014.0429). Climate predictions using a range of models from around the world underpin international agreements to tackle climate change. At the same time more and more national governments are using regional climate predictions to help plan mitigation measures at the country scale, as for example outlined in the National Adaptation Programme by the UK government. The impact of these predictions on society is large, ranging from changes in energy production, development of strategies and counter-measures to deal with extreme weather, to food security and spread of disease. These efforts are predicated on accurate future predictions of the climate. Therefore achieving our goal of reducing uncertainty in climate prediction will benefit all of these stakeholders.

Weather forecasting
The operational implementation of the improved representation of mixed-phase clouds will lead to more accurate weather forecasts both for polar applications (e.g. commercial shipping, community resupply) and also at mid-latitudes through demonstrable links to lower latitudes. Cold-air outbreaks have a significant impact on the UK and Europe and are associated with disruptive snow events. Forecasts underpin the weather warning system used by emergency services, infrastructure professionals, local and national government to safeguard lives, livelihoods and property. Therefore, improving weather forecast in terms of accuracy in the immediate future and extending the lead time for which useful and skilful forecasts are available has a direct impact upon different organisations ability to plan ahead and deliver more effective services. Also, forecasts at the high latitudes are likely to become more important in the future as Arctic shipping is forecast to increase with retreating sea ice. Improving the representation of Cold Air Outbreaks will improve the forecasting of situations that contain high winds (>=Beaufort force 7) and supercooled water conditions that can lead to extreme riming of superstructures

Instrument innovation and commercialisation
Murray is in the process of commercialising the PINE (Portable Ice Nucleation Experiment) chamber https://www.noell.bilfinger.com/pine/ which was developed during his ERC consolidator fellowship. This is the first portable semi-autonomous instrument for quantifying ice nucleation based on the expansion principle. It is being commercialised in partnership with Karlsruhe Institute of Technology and Bilfinger Noell GMBH. PINE will be deployed as part of the cruise. While the PINE chamber has been deployed to several land based atmospheric observatories, this will be the first time the PINE chamber has been deployed on a ship. Hence, M-Phase will help to establish the utility of PINE for autonomous INP measurements. Murray's vision for PINE is that it will become a standard instrument in all GAW style atmospheric observatories. This will not only benefit society through providing the fundamental data required to underpin climate modelling, but it will also yield significant economic impact.

Re-application of new knowledge
The M-Phase team also has a track record of using discoveries in atmospheric science and re-applying them in other areas. A good example of this is Murray's discovery that a particular mineral in desert dust is extremely effective at nucleating ice. In conjunction with Asymptote Ltd. (now part of General Electric, GE) he patented the use of this mineral for the control of ice nucleation in the cryopreservation of biological samples. This work is at the stage where it is attracting investment from GE.
 
Description 1. We published a paper on cloud phase feebacks where we set out the link between ice-nucleating particles and
2. We have found that river water input into the sea is a source of ice nucleating partilcles in the mid-high latitudes.
3. we are currently on the first field campaign and have the other planned. We have done a great deal of work preparing for these campaigns and getting our instrumentation and techniques ready.
Exploitation Route Too early to make statements on this
Sectors Environment

URL https://cloudsense.ac.uk/
 
Description PINE: M-Phase has contributed to the Portable Ice Nucleation Experiment (PINE) project where we are commercialing our ice nucleating particle counter. The instrument is for sale via Bilfinger and was developed in combination between Leeds and KIT (Karlsruhe of Technology). M-Phase has contributed by drawing on data from 20 seperate field campaigns run by PINE users (people who have bought PINE) around the world to create a global dataset (Herbert et al. ESSD Discussions). This work highlight the power and utility of PINE and will aid the uptake of PINE by the global INP measurement community.
First Year Of Impact 2025
Sector Environment,Other
Impact Types Economic

 
Title Data for the publication "Measurement report: The ice-nucleating activity of lichen sampled in a northern European boreal forest" 
Description This repository contains the data and plotting scripts for the paper: Authors: Ulrike Proske, Michael P. Adams, Grace C. E. Porter, Mark Holden, Jaana Bäck, and Benjamin J. Murray Titel: Measurement report: The ice-nucleating activity of lichen sampled in a northern European boreal forest Date: 2024 
Type Of Material Database/Collection of data 
Year Produced 2024 
Provided To Others? Yes  
URL https://zenodo.org/doi/10.5281/zenodo.8355809
 
Title Data for the publication "Measurement report: The ice-nucleating activity of lichen sampled in a northern European boreal forest" 
Description This repository contains the data and plotting scripts for the paper: Authors: Ulrike Proske, Michael P. Adams, Grace C. E. Porter, Mark Holden, Jaana Bäck, and Benjamin J. Murray Titel: Measurement report: The ice-nucleating activity of lichen sampled in a northern European boreal forest Date: 2024 
Type Of Material Database/Collection of data 
Year Produced 2024 
Provided To Others? Yes  
URL https://zenodo.org/doi/10.5281/zenodo.13886560
 
Title Data from the Portable Ice Nucleation Experiment (PINE) during the M-Phase 2022 research cruise 
Description Ice-nucleating particle (INP) measurements were taken using the Portable Ice Nucleation Experiment (PINE) chamber (Möhler et al., 2021) throughout the M-Phase research cruise in May-June 2022 aboard the Royal Research Ship (RRS) Discovery. The cruise started from Reykjavík, Iceland, with the track including the Labrador Sea and the Davis Strait, ending at Southampton, United Kingdom. PINE was located within the University of Leeds IcePod mobile laboratory (https://environment.leeds.ac.uk/dir-record/facilities-environment/1512/icepod) that was located on the foredeck of the ship. Aerosol was sampled through a heated total suspended particulate (TSP) sampling head at a flow rate of 33.33 L/min and into the IcePod laboratory, where the sampled air was split into four lines to monitor aerosols using multiple instruments; PINE was connected to one of these lines and operated at a flow rate of 2 L/min. PINE was run in constant temperature mode with the chamber nominally cooled to -28 °C, but was warmed briefly to 18 °C daily to prevent icing of the inlet in Arctic conditions. A new PINE operation was started every 1-4 days, with the operation folder names labelled as the date the operation started in the YY/MM/DD format. The raw PINE data is provided here for each operation ("operation setup", "raw_Data", and Level 0 data ("L0_Data")). The raw data was processed using the PINE INP Analysis (PIA) software version 2.0.2 to derive time series data (Level 1, "L1_Data") and temperature spectra (Level 2, "L2_Data") of INP concentrations, as per Büttner and Fösig (2023) (https://zenodo.org/records/15592786). Further details of the design and operation of PIA can be found here: https://pia.readthedocs.io/en/stable/. GPS coordinates are provided for the ship cruise track during the M-Phase 2022 campaign. Original GPS files are provided in a folder, while a CSV file provides GPS data on a minute-by-minute basis. 
Type Of Material Database/Collection of data 
Year Produced 2025 
Provided To Others? Yes  
URL https://zenodo.org/doi/10.5281/zenodo.17378346
 
Title Data from the Portable Ice Nucleation Experiment (PINE) during the M-Phase 2022 research cruise 
Description Ice-nucleating particle (INP) measurements were taken using the Portable Ice Nucleation Experiment (PINE) chamber (Möhler et al., 2021) throughout the M-Phase research cruise in May-June 2022 aboard the Royal Research Ship (RRS) Discovery. The cruise started from Reykjavík, Iceland, with the track including the Labrador Sea and the Davis Strait, ending at Southampton, United Kingdom. PINE was located within the University of Leeds IcePod mobile laboratory (https://environment.leeds.ac.uk/dir-record/facilities-environment/1512/icepod) that was located on the foredeck of the ship. Aerosol was sampled through a heated total suspended particulate (TSP) sampling head at a flow rate of 33.33 L/min and into the IcePod laboratory, where the sampled air was split into four lines to monitor aerosols using multiple instruments; PINE was connected to one of these lines and operated at a flow rate of 2 L/min. PINE was run in constant temperature mode with the chamber nominally cooled to -28 °C, but was warmed briefly to 18 °C daily to prevent icing of the inlet in Arctic conditions. A new PINE operation was started every 1-4 days, with the operation folder names labelled as the date the operation started in the YY/MM/DD format. The raw PINE data is provided here for each operation ("operation setup", "raw_Data", and Level 0 data ("L0_Data")). The raw data was processed using the PINE INP Analysis (PIA) software version 2.0.2 to derive time series data (Level 1, "L1_Data") and temperature spectra (Level 2, "L2_Data") of INP concentrations, as per Büttner and Fösig (2023) (https://zenodo.org/records/15592786). Further details of the design and operation of PIA can be found here: https://pia.readthedocs.io/en/stable/. GPS coordinates are provided for the ship cruise track during the M-Phase 2022 campaign. Original GPS files are provided in a folder, while a CSV file provides GPS data on a minute-by-minute basis. 
Type Of Material Database/Collection of data 
Year Produced 2025 
Provided To Others? Yes  
URL https://zenodo.org/doi/10.5281/zenodo.17378345
 
Title Dataset associated with "Volcanic ash ice-nucleating activity can be enhanced or depressed by ash-gas interaction in the eruption plume" 
Description Volcanic ash can trigger ice nucleation when immersed in supercooled water, impacting several processes in the eruption plume/cloud and the wider atmosphere upon ash dispersal. The experimental study associated with this dataset explores how interaction with magmatic gases in the hot eruption plume, which inevitably alters the surface properties of ash, may affect the ice-nucleating activity (INA) of ash. We show that the INA of tephra is raised by exposure to H2O(g) mixed with SO2(g) at 800-400 °C, but is substantially reduced by exposure to H2O(g) alone or mixed with HCl(g) at the same temperatures. In contrast, the INA of K-feldspar and quartz is reduced by all three treatments. A decrease in INA after heating with H2O(g) might relate to a loss of ice-active sites by surface dehydroxylation and/or oxidation. On the tephra surfaces, metal chloride or sulphate salts form in the presence of HCl(g) or SO2(g), respectively. While NaCl and CaCl2 seem to have no effect on the tephra INA, CaSO4 is inferred to create ice-active sites, potentially through a particular combination of surface chemistry and topography. Together, these findings suggest a complex interplay of bulk mineralogy and surface alteration in influencing ice nucleation by volcanic ash, and highlight the general sensitivity of ash INA to interaction with gases at high temperatures in the eruption plume. 
Type Of Material Database/Collection of data 
Year Produced 2020 
Provided To Others? Yes  
URL https://archive.researchdata.leeds.ac.uk/745/
 
Title Dataset for manuscript "Gaps in our understanding of ice-nucleating particle sources exposed by global simulation of the UK Earth System Model" 
Description Datasets and Jupyterlab python script for plotting all figures relevant to the mansucript "Gaps in our understanding of ice-nucleating particle sources exposed by global simulation of the UK Earth System Model" by Herbert et al. https://egusphere.copernicus.org/preprints/2024/egusphere-2024-1538/ Data needs to be unzipped and paths (input and output) updated in the jupyterlab python script. 
Type Of Material Database/Collection of data 
Year Produced 2024 
Provided To Others? Yes  
URL https://zenodo.org/doi/10.5281/zenodo.10568793
 
Title Dataset for manuscript "Gaps in our understanding of ice-nucleating particle sources exposed by global simulation of the UK Earth System Model" 
Description Datasets and Jupyterlab python script for plotting all figures relevant to the mansucript "Gaps in our understanding of ice-nucleating particle sources exposed by global simulation of the UK Earth System Model" by Herbert et al. https://egusphere.copernicus.org/preprints/2024/egusphere-2024-1538/ Data needs to be unzipped and paths (input and output) updated in the jupyterlab python script. 
Type Of Material Database/Collection of data 
Year Produced 2024 
Provided To Others? Yes  
URL https://zenodo.org/doi/10.5281/zenodo.13902401
 
Title Ice-nucleating particle measurements from the M-Phase 2022 flight campaign 
Description Ice-nucleating particle (INP) measurements were taken during the M-Phase flight campaign over the Labrador Sea in October-November 2022, including during cold air outbreaks (CAOs). Aerosol particles were collected onto polytetrafluoroethylene (PTFE) membrane filters with 1.2 µm pores (47 mm diameter, Sartorius) onboard the Facility for Airborne Atmospheric Measurements (FAAM) aircraft during flights. The filters were then analysed via droplet freezing assays performed directly on the PTFE filters, as per Price et al. (2018) and Raif et al. (2024): 2 µL droplets of purified water were pipetted in an array onto a PTFE filter atop a hydrophobic glass slide on an EF600 cyrocooler cold stage, then the temperature of the stage cooled at a rate of 1 °C/min to -40 °C, with the droplet freezing events recorded using a webcam. Handling blanks were taken throughout the campaign by inserting PTFE filters into the FAAM aircraft inlet system but not collecting any sample, then processing the filter as normal. Polycarbonate (PC) track-etched membrane filters with 0.4 µm pores (47 mm diameter, Whatman) were collected simultaneous to the PTFE filters for potential processing via different methods. 
Type Of Material Database/Collection of data 
Year Produced 2025 
Provided To Others? Yes  
URL https://zenodo.org/doi/10.5281/zenodo.14781198
 
Title Ice-nucleating particle measurements from the M-Phase 2022 flight campaign 
Description Ice-nucleating particle (INP) measurements were taken during the M-Phase flight campaign over the Labrador Sea in October-November 2022, including during cold air outbreaks (CAOs). Aerosol particles were collected onto polytetrafluoroethylene (PTFE) membrane filters with 1.2 µm pores (47 mm diameter, Sartorius) onboard the Facility for Airborne Atmospheric Measurements (FAAM) aircraft during flights. The filters were then analysed via droplet freezing assays performed directly on the PTFE filters, as per Price et al. (2018) and Raif et al. (2024): 2 µL droplets of purified water were pipetted in an array onto a PTFE filter atop a hydrophobic glass slide on an EF600 cyrocooler cold stage, then the temperature of the stage cooled at a rate of 1 °C/min to -40 °C, with the droplet freezing events recorded using a webcam. Handling blanks were taken throughout the campaign by inserting PTFE filters into the FAAM aircraft inlet system but not collecting any sample, then processing the filter as normal. Polycarbonate (PC) track-etched membrane filters with 0.4 µm pores (47 mm diameter, Whatman) were collected simultaneous to the PTFE filters for potential processing via different methods. 
Type Of Material Database/Collection of data 
Year Produced 2025 
Provided To Others? Yes  
URL https://zenodo.org/doi/10.5281/zenodo.14781199
 
Title The role of surface-active macromolecules in the ice nucleating ability of lignin, Snomax, and agricultural soil extracts 
Description This dataset contains the data associated with the article titled "The role of surface-active macromolecules in the ice nucleating ability of lignin, Snomax, and agricultural soil extracts". The data is provided in the form of csv files containing the raw data; including the freezing temperatures from droplet freezing assays performed using the Freezing Ice Nucleation Counter (FINC) and the surface tension measurements taken using an optical contact angle tensiometer. The raw data provided also includes the organic carbon concentrations for each analysed solution from which the active site density per mass of carbon (n_m) was calculated. 
Type Of Material Database/Collection of data 
Year Produced 2024 
Provided To Others? Yes  
URL https://archive.researchdata.leeds.ac.uk/1424/
 
Description Leeds-Met Office ice nucleation on FAAM 
Organisation Meteorological Office UK
Country United Kingdom 
Sector Academic/University 
PI Contribution We have worked with Met Office staff during our M-Phase aircraft field campaigns and the analysis and interpretation of the resulting data. A contribution of ours was in making filter based ice nucleating particle measurements.
Collaborator Contribution Met Office staff took part in the FAAM campaigns and are also anaysing and making data available. This includes producing datasets for the liquid and ice water contents from the Nevzerov probe.
Impact We are working on joint publications.
Start Year 2020