Understanding structure, property, composition relationship for electromagnetic absorbing materials made in flow reactors

Lead Research Organisation: University College London
Department Name: Chemistry

Abstract

The research will investigate how the structure and composition of nanomaterials affects the properties in industrial applications for radiation absorbers (RFID security taggants, stealth coatings for wind turbines etc). These nanomaterials will be synthesised using UCL's continuous hydrothermal flow reactors. The nanomaterials will be designed with specific compositions and surface coatings in order to affect their properties in the desired applications. The work will be principally experimental, involving synthesis and the use of key analytical methods for inorganic materials and importantly to measure the relevant magnetic and dielectric properties that will allow some view as to their likely performance for radiation absorbers in the future. The lead materials that are obtained will be scaled up and then tested as coatings with support from the industry partner. To find out more about research at UCL in Clean Materials Technology Research Group see http://chemb125.chem.ucl.ac.uk/

Key objectives
Develop a novel synthesis approach to manufacture libraries of nanomaterials of various metals and metal oxides that can be used to absorb electromagnetic radiation
Develop faster screening methods to characterise the dielectric and magnetic properties of the materials
Define the applications space for the materials according to the above properties
Try to elucidate general design rules and build structure, property, compositional relationships.
Coat nanoparticles to alter their properties and enhance electromagnetic absorption at specific frequencies.
Scale-up of lead materials and coating of them onto artefacts to assess if they are capable to absorb the relevant frequencies (e.g. radar waves, i.e. microwaves in a certain region)

Novelty
In the approach for synthesis of large number of nanomaterials using flow hydrothermal reactors
Novelty is to bring understanding and knowledge of any rules for designing radiation absorber materials that are enhanced in specific wavelengths
Adding coatings to the particles to improve their absorbing properties
Novelty will be in the ability to manufacture larger amounts of materials and retaining the same properties as materials made on the lab scale.
Other novelty will arise from the control of the process and the ability to control quality of materials from batch to batch which is currently a problem.

Publications

10 25 50

Studentship Projects

Project Reference Relationship Related To Start End Student Name
EP/N509577/1 01/10/2016 24/03/2022
1785245 Studentship EP/N509577/1 01/10/2016 30/09/2019 Charles Footer
 
Description Development of novel synthesis approac using CHFS to produce a large num,ber of samples never before attempted using the synthesis method in order to compile a large library and acssociated set of data with respect to their compsoition and electromagnetic absorbance properties.

Developed screening, development and improvement method to cater to a rapid materials discovery method, a novel system developed taking large sets of samples down to one lead sample with improved characteristics.

Defined potential application areas for the electromagnetic characteristics observed in the synthesised nanoparticles for application specific development.

Structural property relationship investigated in depth and trends highlighted, work ongoing as many factors at play.

Coating of nano particles using novel methods in order to tailor electromagnetic responses for certain applications, a considerable task which required many steps to arrange allowing increased performance at certain frequencies.

Scale-up of delivered material from low grams to 100s allowing further application based testing of materials in larger setups.
Exploitation Route New PhD taking discoveries from PhD further

Development of knowledge from PhD within industry partner with view to commercialise

Synthesis knowledge widely used within research group
Sectors Aerospace, Defence and Marine,Chemicals,Electronics,Energy,Environment,Manufacturing, including Industrial Biotechology,Security and Diplomacy

 
Description Knowledge relating to the synthesis of new materials via CHFS used to tailor materials and have led to work within the funding body regarding coating of nano particles as well as application techniques. Understanding used to develop an economic case for the scale up and development of materials with respect to their becoming a product in the future with further development. Successful areas of interest to be taken forward twards a continuation PhD.
First Year Of Impact 2016
Sector Aerospace, Defence and Marine,Chemicals,Energy,Manufacturing, including Industrial Biotechology
 
Title QinetiQ RF laboratories 
Description One of a kind equipment located at QinetiQ headquarters 
Type Of Material Improvements to research infrastructure 
Provided To Others? No  
Impact Specialist data production and specialist environmental tetsing 
 
Title Formation of specialist database of all synthesised materials (over 1000) 
Description Formation of specialist sample library allowing desired behaviours to be found in the samples within the database. 
Type Of Material Data handling & control 
Year Produced 2017 
Provided To Others? No  
Impact Industrial benefit and knowhow for future application needs