Soft NanoPhotonics Programme Grant (sNaP)
Lead Research Organisation:
University of Cambridge
Department Name: Physics
Abstract
Visible light can be made to interact with new solids in unusual and profoundly different ways to normal if the solids are built from tiny components assembled together in intricately ordered structures. This hugely expanding research area is motivated by many potential benefits (which are part of our research programme) including enhanced solar cells which are thin, flexible and cheap, or surfaces which help to identify in detail any molecules travelling over them. This combination of light and nanoscale matter is termed NanoPhotonics.Until now, most research on NanoPhotonics has concentrated on the extremely difficult challenge of carving up metals and insulators into small chunks which are arranged in patterns on the nanometre scale. Much of the effort uses traditional fabrication methods, most of which borrow techniques from those used in building the mass-market electronics we all use, which is based on perfectly flat slabs of silicon. Such fabrication is not well suited to three-dimensional architectures of the sizes and materials needed for NanoPhotonics applications, and particularly not if large-scale mass-production of materials is required.Our aim in this programme is to bring together a number of specialists who have unique expertise in manipulating and constructing nanostructures out of soft materials, often organic or plastic, to make Soft NanoPhotonics devices which can be cheap, and flexible. In the natural world, many intricate architectures are designed for optical effects and we are learning from them some of their tricks, such as irridescent petal colours for bee attraction, or scattering particular colours of light from butterfly wings to scare predators. Here we need to put together metal and organics into sophisticated structures which give novel and unusual optical properties for a whole variety of applications.There are a number of significant advantages from our approach. Harnessing self-assembly of components is possible where the structures just make themselves , sometimes with a little prodding by setting up the right environment. We can also make large scale manufacturing possible using our approach (and have considerable experience of this), which leads to low costs for production. Also this approach allows us to make structures which are completely impossible using normal techniques, with smaller nanoscale features and highly-interconnected 3D architectures. Our structures can be made flexible, and we can also exploit the plastics to create devices whose properties can be tuned, for instance by changing the colour of a fibre when an electrical voltage is applied, or they are stretched or exposed to a chemical. More novel ideas such as electromagnetic cloaking (stretching light to pass around an object which thus remains invisible) are also only realistic using the sort of 3D materials we propose.The aim of this grant is bring together a set of leading researchers with the clear challenge to combine our expertise to create a world-leading centre in Soft NanoPhotonics. This area is only just emerging, and we retain an internationally-competitive edge which will allow us to open up a wide range of both science and application. The flexibility inherent in this progamme grant would allow us to continue the rapid pace of our research, responding to the new opportunities emerging in this rapidly progressing field.
Organisations
- University of Cambridge (Lead Research Organisation)
- Defence Science & Technology Laboratory (DSTL) (Collaboration)
- Base4 Innovation (Collaboration)
- Nokia Research Centre Cambridge (Collaboration)
- 3M (United States) (Collaboration)
- Renishaw (United Kingdom) (Collaboration)
- German Plastic Institute (Collaboration)
Publications
Abate A
(2019)
Halogen-bond driven self-assembly of perfluorocarbon monolayers on silicon nitride
in Journal of Materials Chemistry A
Abo-Hamed EK
(2014)
Highly active metastable ruthenium nanoparticles for hydrogen production through the catalytic hydrolysis of ammonia borane.
in Small (Weinheim an der Bergstrasse, Germany)
Ahmad S
(2015)
Strong Photocurrent from Two-Dimensional Excitons in Solution-Processed Stacked Perovskite Semiconductor Sheets.
in ACS applied materials & interfaces
Ahmad S
(2018)
Photo-Rechargeable Organo-Halide Perovskite Batteries.
Ahmad S
(2018)
Photo-Rechargeable Organo-Halide Perovskite Batteries.
in Nano letters
Ahmad S
(2013)
Structural tunability and switchable exciton emission in inorganic-organic hybrids with mixed halides
in Journal of Applied Physics
Ahmad S
(2014)
In situ intercalation dynamics in inorganic-organic layered perovskite thin films.
in ACS applied materials & interfaces
Ahmad S.
(2012)
Fabrication of excitonic luminescent inorganic-organic hybrid nano and microcrystals
in 2012 International Conference on Fiber Optics and Photonics, PHOTONICS 2012
Aitchison H
(2017)
Analytical SERS: general discussion.
in Faraday discussions
Description | A very large number of new ideas and configurations for changing the coupling of light with soft nanomaterials based on assembling metals, dielectrics and in/organic components. High impact papers, and many interactions with companies. |
Exploitation Route | Tuneable structural colour for security, sensing, health, decorative coatings, textiles. Discussions and funded partnerships with Nokia, 3M, Renishaw, DSTL and others ongoing. Patents filed on a number of the key advances. |
Sectors | Chemicals Digital/Communication/Information Technologies (including Software) Electronics Energy Environment Healthcare Pharmaceuticals and Medical Biotechnology Security and Diplomacy |
URL | http://www.np.phy.cam.ac.uk/publications |
Description | This grant concentrated on new ways to create nanostructured materials which have unusual light-matter interactions that can potentially be exploited. The focus was on developing new routes to create these materials which do not rely on costly, difficult and low yield lithographic technologies but instead utilise developments in self- and directed-nanoconstruction. In particular the combination of soft and hard materials in these structures has opened new opportunities, which have delivered an extensive and expanding range of outputs from the research. Four areas have been our main focus: Metallo-dielectric nanomaterials and metamaterials, Biomimetically-inspired photonics, Microcavities, and Plasmonics. The outputs also exemplify how work across these emphatically interdisciplinary boundaries yield new directions. In the first theme of research, our optics and soft matter groups teamed up to investigate a series of routes to nanomaterials. Using a sacrificial underlayer method to float large-area elastomeric bilayers onto a water surface allowed the use of roll-up and origami folding, techniques to create metallo-dielectric multilayers with unusual properties. We were the first to explore this strategy to large-area metamaterials, which attracted the interest and subsequent funding from Mars, Nokia, and 3M, as well as other companies who are collaborating in this area. Another route has used polystyrene/polyethylacrylate core-shell polymer nanoparticles grown in bulk solution for shear-assembly into opal films. These are the largest photonic crystals ever made, with film lengths so far up to 1km, proven to be single-domain (set by the shearing direction) and thousands of unit cells thick in an fcc lattice. Our unique fabrication route (which we have patented) led to commercial tests for pilot-scale-up with a major UK manufacturing company (Smith & Nephew). We were inundated with interest about these polymer opals (over 70 companies on our contact list), and they were exhibited in the 2012 Paris Fashion Show, as well as a Science Museum exhibit 'Trash Fashion' in 2011. Our students eventually founded a startup, Phomera, which is producing coatings for buildings (and also 'beetle' iridescent backpacks). The last research domain on which we have strongly focussed is plasmonics, with noble metal nanoparticles (Au,Ag) coupled together to produce intense optical fields tightly confined close to the metallic surfaces. We explored how stretching elastomeric plasmonics devices allows direct nanoscale tuning of the resonant wavelength, which led to funding from Nokia and a patent on our techniques to make single nanoparticle close-packed plasmonic mats. We have used an alternative void-like geometry supporting localised plasmons for producing a new (patented) solar cell which we showed has 4-fold enhanced efficiency. We have also pioneered the use of rigid cucurbituril (CB) molecules to glue together Au nanoparticles with nanoscale gaps producing aggregates with strong reliable plasmonic resonances. This system is particularly interesting because molecules can be sequestered inside CBs in the optimal high-field locations, allowing robust Raman sensing (patented). This has continued to develop, with discussions in translation to a new home sensing device, the 'Intelligent Toilet', with medical units and instrumentation companies. This grant brought in £1.1M of industrial funding (through Nokia, 3M, Renishaw, DSTL, Base4, Mars and others) leveraging our EPSRC investment. We focussed on how to exploit the nanomaterial systems created, working with Cambridge Enterprise (CE) to protect early stage IP. This led to eight patents in the grant which are brought into several portfolios, with over 50 companies engaged so far on these (with NDAs). In addition we leveraged the Programme grant to bring in £3.2M of EU funding, including an ERC Advanced award on various specific topics around this area, as well as two British Council grants with India. Together this forms a record of >100% leverage, showing the success of this investment. |
First Year Of Impact | 2013 |
Sector | Chemicals,Digital/Communication/Information Technologies (including Software),Environment,Healthcare,Manufacturing, including Industrial Biotechology,Pharmaceuticals and Medical Biotechnology,Security and Diplomacy |
Impact Types | Societal Economic |
Description | 3M Minnesota |
Amount | £133,131 (GBP) |
Funding ID | RG64515 |
Organisation | 3M |
Sector | Private |
Country | United States |
Start |
Description | EPSRC |
Amount | £123,369 (GBP) |
Funding ID | EP/H027130/1 |
Organisation | Engineering and Physical Sciences Research Council (EPSRC) |
Sector | Public |
Country | United Kingdom |
Start |
Description | EPSRC |
Amount | £397,636 (GBP) |
Funding ID | EP/H007024/1 |
Organisation | Engineering and Physical Sciences Research Council (EPSRC) |
Sector | Public |
Country | United Kingdom |
Start |
Description | EPSRC Programme grant (NOtCH) |
Amount | £6,013,126 (GBP) |
Funding ID | EP/L027151/1 |
Organisation | Engineering and Physical Sciences Research Council (EPSRC) |
Sector | Public |
Country | United Kingdom |
Start |
Description | ERC Advanced Investigator |
Amount | £1,666,666 (GBP) |
Funding ID | 320503 |
Organisation | European Research Council (ERC) |
Sector | Public |
Country | Belgium |
Start |
Description | European Commission (EC) |
Amount | £174,195 (GBP) |
Funding ID | FP7-PEOPLE-2011-IEF 298012 |
Organisation | European Commission |
Sector | Public |
Country | European Union (EU) |
Start |
Description | European Commission (EC) |
Amount | £174,195 (GBP) |
Funding ID | FP7-PEOPLE-2011-IEF 298012 |
Organisation | European Commission |
Sector | Public |
Country | European Union (EU) |
Start |
Description | Impact Accelaration Award EPSRC (opals) |
Amount | £58,000 (GBP) |
Organisation | Engineering and Physical Sciences Research Council (EPSRC) |
Sector | Public |
Country | United Kingdom |
Start | 09/2014 |
End | 12/2015 |
Description | Leverhulme visiting Prof |
Amount | £122,984 (GBP) |
Funding ID | VP1-2013-011 |
Organisation | The Leverhulme Trust |
Sector | Charity/Non Profit |
Country | United Kingdom |
Start |
Description | NanoSciEra+ |
Amount | £397,636 (GBP) |
Funding ID | EP/H007024/1 |
Organisation | Engineering and Physical Sciences Research Council (EPSRC) |
Sector | Public |
Country | United Kingdom |
Start |
Description | Nokia |
Amount | £523,373 (GBP) |
Funding ID | RG61446 |
Organisation | Nokia |
Sector | Private |
Country | Global |
Start |
Description | Nokia |
Amount | £523,373 (GBP) |
Funding ID | RG61446 |
Organisation | Nokia |
Sector | Private |
Country | Global |
Start |
Description | RDA Follow on funding |
Amount | £20,650 (GBP) |
Organisation | East of England Development Agency |
Sector | Public |
Country | United Kingdom |
Start | 11/2009 |
End | 07/2010 |
Title | Research data supporting "Electrically controlled nano and micro actuation in memristive switching device with on-chip gas encapsulation" |
Description | Data related to plots and figures in associated publication. Datasets are provided as comma-separated values files, containing the raw data from experimental measurements. Raw image files are also provided for the images included in the publication figures. |
Type Of Material | Database/Collection of data |
Year Produced | 2018 |
Provided To Others? | Yes |
Title | Research data supporting "Laser-Induced Reduction and In-situ Optical Spectroscopy of Individual Plasmonic Copper Nanoparticles for Catalytic Reactions" |
Description | Author: Giuliana Di Martino email: gd392@cam.ac.uk Principal Investigator: Jeremy J. Baumberg email of PI: jjb12@cam.ac.uk Institute: NanoPhotonics Centre, Department of Physics, Cavendish Laboratory, University of Cambridge The data files contain optical spectra of the experimental and simulated data. Details on the acquisition method are included in the main manuscript. Igor Pro has been used to acquire and plot the data. PovRay and PowerPoint has been used to create Fig.1. File formats: - raw data files are supplied as .txt files - images are supplied as .png or .pdf files |
Type Of Material | Database/Collection of data |
Year Produced | 2017 |
Provided To Others? | Yes |
Title | Research data supporting "Retrieving the co-assembly pathway of composite cellulose nanocrystal photonic films from their angular optical response" |
Description | |
Type Of Material | Database/Collection of data |
Year Produced | 2020 |
Provided To Others? | Yes |
URL | https://www.repository.cam.ac.uk/handle/1810/301118 |
Title | Research data supporting "Thermo-Responsive Actuation of a DNA Origami Flexor" |
Description | Research data supporting Thermo-Responsive Actuation of a DNA Origami Flexor |
Type Of Material | Database/Collection of data |
Year Produced | 2000 |
Provided To Others? | Yes |
Title | Research data supporting [Mapping nanoscale hotspots with single-molecule emitters assembled into plasmonic nanocavities using DNA origami] |
Description | Experimental and simulation data is collected at NanoPhotonics center, University of Cambridge. |
Type Of Material | Database/Collection of data |
Year Produced | 2017 |
Provided To Others? | Yes |
Description | Collaboration with 3M |
Organisation | 3M |
Country | United States |
Sector | Private |
PI Contribution | 3M funded project on exploring potential of optical scattering from colloidal particles. Funded project to study scattering from films. |
Start Year | 2011 |
Description | Renishaw Diagnostic Ltd |
Organisation | Renishaw PLC |
Department | Renishaw Diagnostics Ltd |
Country | United Kingdom |
Sector | Private |
PI Contribution | CASE studentship |
Start Year | 2008 |
Description | Signed exploitation agreement with DKI |
Organisation | German Plastic Institute |
Country | Germany |
Sector | Private |
PI Contribution | Our technology partner has signed agreements with us, so that we jointly commercialise with Cambridge Enterprise leading. Long term collaboration developed. |
Start Year | 2006 |
Description | base4innovation |
Organisation | Base4 Innovation |
Country | United Kingdom |
Sector | Private |
PI Contribution | research project |
Start Year | 2008 |
Description | collaboration with DSTL |
Organisation | Defence Science & Technology Laboratory (DSTL) |
Country | United Kingdom |
Sector | Public |
PI Contribution | joint research on UV SERS |
Collaborator Contribution | background on need and current technologies |
Impact | see publications on UV SERS |
Start Year | 2011 |
Description | collaboration with Nokia |
Organisation | Nokia Research Centre Cambridge |
Country | United Kingdom |
Sector | Private |
PI Contribution | research collaboration |
Start Year | 2010 |
Company Name | Base4 |
Description | Base4 has developed nanopore technology that enables single molecule analysis, pathogen detection and DNA sequencing. |
Year Established | 2007 |
Impact | second tranche of funding, having hit milestones |
Website | http://www.base4.co.uk |
Company Name | Phomera |
Description | Commercialising our technology for polymer opals |
Year Established | 2015 |
Impact | established company in China |
Company Name | Astrileux |
Description | commercialising a new route to high density lithography |
Year Established | 2015 |
Impact | Aims to develop lithography tools for next generation Intel chips |
Description | BBC Horizon interview |
Form Of Engagement Activity | A talk or presentation |
Part Of Official Scheme? | No |
Geographic Reach | National |
Primary Audience | Public/other audiences |
Results and Impact | filming labs and interviews for BBC Horizon programme on our synthetic biology project on making structural colours from squid genes. limited feedback from public. |
Year(s) Of Engagement Activity | 2011 |
Description | Dara O'Brian Science Club BBC |
Form Of Engagement Activity | A talk or presentation |
Part Of Official Scheme? | No |
Geographic Reach | National |
Primary Audience | Public/other audiences |
Results and Impact | Produced interviews and experiments for an "Future Fantastic" episode of Dara O'Brian Science Club BBC, aired on 15 Aug 2013. Contacted by various members of public. |
Year(s) Of Engagement Activity | 2013 |
Description | Materials movie, "The Secret Life of Materials" |
Form Of Engagement Activity | A broadcast e.g. TV/radio/film/podcast (other than news/press) |
Part Of Official Scheme? | No |
Geographic Reach | International |
Primary Audience | Public/other audiences |
Results and Impact | JJB in Materials movie, "The Secret Life of Materials", Mimicking Nature, selected for Pariscience and the Goethe science film festivals receiving awards in the International Film Festival in Athens and in the Life Sciences Film festival in Prague so far... |
Year(s) Of Engagement Activity | 2015 |
URL | https://youtu.be/SVGMhGualU0?list=PLmQdDYjAqXUk5jp7_xLYLFfIeH53Gl-bg&t=1 |
Description | Naked Scientist interview |
Form Of Engagement Activity | A broadcast e.g. TV/radio/film/podcast (other than news/press) |
Part Of Official Scheme? | No |
Geographic Reach | International |
Primary Audience | Public/other audiences |
Results and Impact | interview on our work recorded with Naked Scientist |
Year(s) Of Engagement Activity | 2015 |
Description | Pacific Grove Museum of Natural History exhibit |
Form Of Engagement Activity | Participation in an activity, workshop or similar |
Part Of Official Scheme? | No |
Geographic Reach | International |
Primary Audience | Public/other audiences |
Results and Impact | built polymer opal exhibit for Pacific Grove Museum of Natural History good feedback from museum. |
Year(s) Of Engagement Activity | 2011 |
Description | Paris fashion show |
Form Of Engagement Activity | Participation in an activity, workshop or similar |
Part Of Official Scheme? | No |
Geographic Reach | International |
Primary Audience | Public/other audiences |
Results and Impact | Working with a London fashion designer who developed our polymer opals nanomaterials into clothes, these were shown at the Paris Fashion show. Many designers asked us for sample material to use. |
Year(s) Of Engagement Activity | 2012 |
Description | Royal Society Summer Exhibition: Dress to Impress |
Form Of Engagement Activity | Participation in an activity, workshop or similar |
Part Of Official Scheme? | Yes |
Geographic Reach | National |
Primary Audience | Public/other audiences |
Results and Impact | 12000 members of the public came by the stand and saw the exhibit, sparking many discussions, demonstrations, ideas, etc. We had enquiries from very many schools about our work, which is highly visual nanotechnology. |
Year(s) Of Engagement Activity | 2011 |
Description | SET for Parliment |
Form Of Engagement Activity | Participation in an activity, workshop or similar |
Part Of Official Scheme? | No |
Geographic Reach | National |
Primary Audience | Policymakers/politicians |
Results and Impact | Laura Brooks represented our work at SET in Parliment, won 2nd prize |
Year(s) Of Engagement Activity | 2016 |
Description | Science Society talk |
Form Of Engagement Activity | A talk or presentation |
Part Of Official Scheme? | No |
Geographic Reach | Local |
Primary Audience | Undergraduate students |
Results and Impact | Talk for the Cambridge University Science Society |
Year(s) Of Engagement Activity | 2015 |
Description | Stoner lecture, Leeds |
Form Of Engagement Activity | A talk or presentation |
Part Of Official Scheme? | No |
Geographic Reach | Regional |
Primary Audience | Public/other audiences |
Results and Impact | JJB gave the Stoner lecture on translating research |
Year(s) Of Engagement Activity | 2017 |
Description | Trash Fashions exhibit at Science Museum |
Form Of Engagement Activity | Participation in an activity, workshop or similar |
Part Of Official Scheme? | Yes |
Geographic Reach | International |
Primary Audience | Public/other audiences |
Results and Impact | Trash Fashions, showcased new ideas for clothers based on technologies. We provided an exhibit based on our polymer opal materials. Many schools and clothers designers asked us for sample materials to test and create new clothes with. It caught the imagination well. |
Year(s) Of Engagement Activity | 2010 |
Description | Wired 8 page spread on our work |
Form Of Engagement Activity | A magazine, newsletter or online publication |
Part Of Official Scheme? | No |
Geographic Reach | International |
Primary Audience | Public/other audiences |
Results and Impact | With their journalists, we produced an 8 page article of images and text in the international magazine Wired. Many people contacted us as a result. |
Year(s) Of Engagement Activity | 2013 |
URL | http://www.wired.com/wiredscience/2013/11/weird-nanophotonic-materials/ |
Description | exibit in Cambridge Science Museum |
Form Of Engagement Activity | A broadcast e.g. TV/radio/film/podcast (other than news/press) |
Part Of Official Scheme? | No |
Geographic Reach | Regional |
Primary Audience | Public/other audiences |
Results and Impact | built polymer opals exhibit as part of Cambridge Science Museum display |
Year(s) Of Engagement Activity | 2016 |