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Engineered UK clays for production of low-carbon cements

Lead Research Organisation: Imperial College London
Department Name: Civil & Environmental Engineering

Abstract

Portland cement concrete is the most heavily used manufactured material on the planet after clean water, and it is integral to modern life. However, the production of 4 billion tonnes of Portland cement per year is responsible for 8% of global man-made greenhouse gas emissions. With the growing threat of climate change, there is an urgent need to decarbonise cement production. Currently, the most viable approach to reduce cement's carbon footprint involve the widespread use of supplementary cementitious materials (SCMs), such as fly ash from electricity generation and ground granulated blast furnace slag from steel manufacture. However, with decarbonisation of electricity and the decline of UK steel manufacture, these materials are becoming increasingly scarce. Therefore, we need to develop low-carbon alternatives, without disrupting construction practice nor compromising on long-term performance. This is the ultimate goal of this project.

Recently, there has been growing interest in using clays as cementitious materials in the production of low-carbon concrete because they are practical, affordable, and scalable. The UK has abundant clay resources that can be easily obtained from overburdens of existing quarries and infrastructure development projects, where they are currently regarded as wastes. However, most of the clay in the UK and globally are low grade and are less reactive compared to high purity kaolinite clays. Therefore, there is a need to develop focussed solutions based on these low-grade clay deposits, rather than to depend on the importation of alternatives from thousands of miles. This project is timely since increased infrastructure activity, e.g. Crossrail, HS2, as well as driving increased demand for cement and concrete, will also lead to higher production of construction spoils that contain waste clays. Thus, we will develop new low-carbon cements from locally sourced clay-bearing construction and mining spoils. Using these in concrete production is a highly sustainable and circular solution; turning waste clays into valuable resources.

The development of low-carbon cements is vital, but if these new materials are not translated from the laboratory to the construction site, then the necessary change will not arise. To achieve this, we will examine the performance of these new low-carbon cements from manufacture, through site practice to understanding long-term durability. The research team will work with industry from all along the supply chain to ensure that the newly developed materials satisfy industry requirements and are adopted as wide as possible to maximise carbon reductions of our built environment.

In summary, the research team and their industrial partners will develop new cements from locally sourced low-grade waste clays to significantly reduce the carbon footprint of concrete and ensure performance along the entire lifetime of infrastructure. This will help the UK to deliver on its plans to decarbonise and achieve a net-zero economy.
 
Description The key achievements derived from this project to-date are:
• Detailed field survey of the UK clay mineral resources, their properties, availability and potential to produce low-carbon cements.
• Development of processing protocols and new activation strategies to convert low-grade UK clays into reactive cementitious materials.
• Understanding of the reactivity, rheology and performance of UK clay blended cementitious materials.
• Life-cycle analysis and techno-economic assessment showing the viability of UK clays to produce low-carbon cements and to guide future commercial exploitation.
Exploitation Route This funding will generate the underpinning science and technical know-how to produce new affordable cements from abundant low-grade UK clays, which will be optimised to have equal performance to conventional cements, but with significantly less embodied carbon. The research will provide the fundamental understanding, processes and performance data required by the construction industry to adopt these materials confidently. This will enable a new transformative circular economy model where mineral wastes generated from infrastructure development are rapidly processed and re-used as valuable cements, thereby maximising local resources for sustainable construction. The work will also benefit other researchers working on developing low-carbon cements. For example, the developed processes and models can be translated to other clay resources worldwide, used as a guideline for screening clays, and identify suitable processing conditions to optimise their reactivity. The correlations between chemistry and mineralogy of low-grade clays, particularly from waste resources that have not been systematically studied until now, and their microstructure as a function of processing conditions (thermal, mechanical and chemical) will be used by others to develop new reactive cements, to optimise and blend these materials to produce concretes with the required properties for field applications at the lowest life-cycle impacts.
Sectors Chemicals

Construction

Education

Environment

Manufacturing

including Industrial Biotechology

 
Description Our research is generating a deep understanding of the range of clay resources available in the UK; their properties, processing, and viability to form low-carbon cement for construction applications. This has led to a substantial increase in interest from the industry, as evidenced by the large number of new project partners following our work and engaging with us, who will ultimately become users of the outputs arising from this research. Our findings are beginning to be adopted by the industry to inform their long-term planning and to make strategic decisions on commercial exploitation of UK clays as a valuable abundant resource to produce low-carbon sustainable construction materials.
First Year Of Impact 2025
Sector Construction,Education,Environment,Manufacturing, including Industrial Biotechology
Impact Types Societal

Economic

 
Description DESNZ and DEFRA project - Unlocking Resource Efficiency Phase 1 - Cement and Concrete Report
Geographic Reach National 
Policy Influence Type Contribution to a national consultation/review
URL https://assets.publishing.service.gov.uk/media/6564cae8888c06000dfa7dc2/unlocking-resource-efficienc...
 
Description CONTRABASS: zero-CO2 cemeNt ThRough cArBonation of cAlcium Silicates and aluminateS
Amount € 2,171,340 (EUR)
Funding ID 101119715 
Organisation European Commission 
Sector Public
Country Belgium
Start 01/2024 
End 12/2027
 
Description Carbon sequestration in the built environment
Amount £986,176 (GBP)
Organisation Department for Business, Energy & Industrial Strategy 
Sector Public
Country United Kingdom
Start 03/2023 
End 03/2025
 
Description Excavation Waste London Clay Utilisation in Concrete Applications ("Ex-Clay")
Amount £481,446 (GBP)
Funding ID 10117763 
Organisation Innovate UK 
Sector Public
Country United Kingdom
Start 04/2024 
End 05/2025
 
Description International PhD studentship - Low-carbon and reusable structural systems formed with eco-friendly materials for sustainable infrastructures
Amount £105,000 (GBP)
Organisation Kuwait Institute for Scientific Research 
Sector Public
Country Kuwait
Start 01/2023 
End 07/2026
 
Description International PhD studentship - Understanding the hydration of Portland cements blended with calcined clay
Amount £110,000 (GBP)
Organisation University of Leeds 
Sector Academic/University
Country United Kingdom
Start 03/2023 
End 10/2026
 
Description PhD studentship: Development of low-carbon cement and concrete materials from UK clays
Amount £89,000 (GBP)
Organisation Imperial College London 
Sector Academic/University
Country United Kingdom
Start 09/2023 
End 09/2027
 
Description Royce Industrial Collaboration Programme (ICP) - Investigating the scale-up potential of mechanochemical activation technology for low-purity clays
Amount £124,000 (GBP)
Funding ID EP/X527257/1 
Organisation Henry Royce Institute 
Sector Academic/University
Country United Kingdom
Start 09/2024 
End 02/2025
 
Title Database of UK clays 
Description Database of UK clay stockpiles, their location, accessibility, properties and potential for processing to form low-carbon cements. Compilation of the database is an ongoing activity and the results will be used to inform subsequent sampling and detailed characterisation work. 
Type Of Material Database/Collection of data 
Year Produced 2023 
Provided To Others? No  
Impact When completed, the database will be openly disseminated to guide future industrial exploitation. 
 
Description Belite-ye'elimite-ferrite cements from waste clay 
Organisation University of Jinan
Country China 
Sector Academic/University 
PI Contribution Collaboration to design, synthesise and assess BYF cements from waste clay.
Collaborator Contribution Provision of data.
Impact One conference paper published and one journal article in progress.
Start Year 2023
 
Description Cements from low-grade clays 
Organisation University of Suffolk
Department Suffolk Sustainability Institute
Country United Kingdom 
Sector Academic/University 
PI Contribution Provision of data and analyses
Collaborator Contribution Provision of samples and data.
Impact One journal publication is in progress.
Start Year 2022
 
Description Life cycle assessment and technoeconomic analysis of activated clays 
Organisation Central University of Las Villas
Country Cuba 
Sector Academic/University 
PI Contribution Knowledge and data exchanges, and publication of co-authored research outputs
Collaborator Contribution Knowledge and data exchanges, publication of co-authored research outputs, and research visits
Impact No outputs yet
Start Year 2023
 
Description Life cycle assessment and technoeconomic analysis of activated clays 
Organisation FLSmidth
Country Global 
Sector Private 
PI Contribution Knowledge and data exchanges, and publication of co-authored research outputs
Collaborator Contribution Knowledge and data exchanges, publication of co-authored research outputs, and research visits
Impact No outputs yet
Start Year 2023
 
Description New industry partners (affiliates) to EUREKA 
Organisation Aggregate Industries
Country United Kingdom 
Sector Private 
PI Contribution Carried out additional tests and analyses.
Collaborator Contribution Provision of samples, industry data and technical expertise.
Impact Additional research data and publications
Start Year 2022
 
Description New industry partners (affiliates) to EUREKA 
Organisation Balfour Beatty Vinci
Country United Kingdom 
Sector Private 
PI Contribution Carried out additional tests and analyses.
Collaborator Contribution Provision of samples, industry data and technical expertise.
Impact Additional research data and publications
Start Year 2022
 
Description New industry partners (affiliates) to EUREKA 
Organisation Costain Group
Country United Kingdom 
Sector Private 
PI Contribution Carried out additional tests and analyses.
Collaborator Contribution Provision of samples, industry data and technical expertise.
Impact Additional research data and publications
Start Year 2022
 
Description New industry partners (affiliates) to EUREKA 
Organisation FLSmidth
Country Global 
Sector Private 
PI Contribution Carried out additional tests and analyses.
Collaborator Contribution Provision of samples, industry data and technical expertise.
Impact Additional research data and publications
Start Year 2022
 
Description New industry partners (affiliates) to EUREKA 
Organisation High Speed Two (HS2) Ltd
Country United Kingdom 
Sector Public 
PI Contribution Carried out additional tests and analyses.
Collaborator Contribution Provision of samples, industry data and technical expertise.
Impact Additional research data and publications
Start Year 2022
 
Description New industry partners (affiliates) to EUREKA 
Organisation Lafarge Tarmac
Country United Kingdom 
Sector Private 
PI Contribution Carried out additional tests and analyses.
Collaborator Contribution Provision of samples, industry data and technical expertise.
Impact Additional research data and publications
Start Year 2022
 
Description New industry partners (affiliates) to EUREKA 
Organisation Manufacturing Technology Centre (MTC)
Country United Kingdom 
Sector Private 
PI Contribution Carried out additional tests and analyses.
Collaborator Contribution Provision of samples, industry data and technical expertise.
Impact Additional research data and publications
Start Year 2022
 
Description New industry partners (affiliates) to EUREKA 
Organisation Marshalls
Country United Kingdom 
Sector Private 
PI Contribution Carried out additional tests and analyses.
Collaborator Contribution Provision of samples, industry data and technical expertise.
Impact Additional research data and publications
Start Year 2022
 
Description New industry partners (affiliates) to EUREKA 
Organisation Mineral Products Association (MPA)
Country United Kingdom 
Sector Charity/Non Profit 
PI Contribution Carried out additional tests and analyses.
Collaborator Contribution Provision of samples, industry data and technical expertise.
Impact Additional research data and publications
Start Year 2022
 
Description New industry partners (affiliates) to EUREKA 
Organisation Mott Macdonald UK Ltd
Country United Kingdom 
Sector Private 
PI Contribution Carried out additional tests and analyses.
Collaborator Contribution Provision of samples, industry data and technical expertise.
Impact Additional research data and publications
Start Year 2022
 
Description New industry partners (affiliates) to EUREKA 
Organisation Saint-Gobain S.A.
Country France 
Sector Private 
PI Contribution Carried out additional tests and analyses.
Collaborator Contribution Provision of samples, industry data and technical expertise.
Impact Additional research data and publications
Start Year 2022
 
Description New industry partners (affiliates) to EUREKA 
Organisation Sibelco
Country Belgium 
Sector Private 
PI Contribution Carried out additional tests and analyses.
Collaborator Contribution Provision of samples, industry data and technical expertise.
Impact Additional research data and publications
Start Year 2022
 
Description Supplementary cementitious materials from low-grade Saudi clays 
Organisation King Fahd University of Petroleum and Minerals
Country Saudi Arabia 
Sector Academic/University 
PI Contribution Carried out reactivity and microstructural analyses of calcined low-grade Saudi clays to assess their potential as cement replacement materials.
Collaborator Contribution Provision of materials and data of low-grade Saudi clays
Impact One journal publication in progress
Start Year 2024
 
Description UK mineral industry operating companies 
Organisation Hanson Cement
Country United Kingdom 
Sector Private 
PI Contribution Characterisation of the mineralogical composition of clay samples. Data will be provided to the operating companies.
Collaborator Contribution Access to quarries and mines. Assistance in collection of samples..
Impact No outputs as yet.
Start Year 2022
 
Description UK mineral industry operating companies 
Organisation Ibstock Brick Limited
Country United Kingdom 
Sector Private 
PI Contribution Characterisation of the mineralogical composition of clay samples. Data will be provided to the operating companies.
Collaborator Contribution Access to quarries and mines. Assistance in collection of samples..
Impact No outputs as yet.
Start Year 2022
 
Description UK mineral industry operating companies 
Organisation Saint-Gobain S.A.
Country France 
Sector Private 
PI Contribution Characterisation of the mineralogical composition of clay samples. Data will be provided to the operating companies.
Collaborator Contribution Access to quarries and mines. Assistance in collection of samples..
Impact No outputs as yet.
Start Year 2022
 
Description UK mineral industry operating companies 
Organisation Tarmac Ltd
Country United Kingdom 
Sector Private 
PI Contribution Characterisation of the mineralogical composition of clay samples. Data will be provided to the operating companies.
Collaborator Contribution Access to quarries and mines. Assistance in collection of samples..
Impact No outputs as yet.
Start Year 2022
 
Description UK mineral industry operating companies 
Organisation Wienerberger
Country Austria 
Sector Private 
PI Contribution Characterisation of the mineralogical composition of clay samples. Data will be provided to the operating companies.
Collaborator Contribution Access to quarries and mines. Assistance in collection of samples..
Impact No outputs as yet.
Start Year 2022
 
Description Upcycling end-of-life bricks 
Organisation Brunel University London
Department School of Engineering and Design
Country United Kingdom 
Sector Academic/University 
PI Contribution Provision of data and analyses to investigate the potential of processing end-of-life waste clay bricks to form new cement and aggregate.
Collaborator Contribution Provision of samples and test data.
Impact One journal publication is currently under preparation.
Start Year 2022
 
Description Calcined Clay Workshop 
Form Of Engagement Activity Participation in an activity, workshop or similar
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Industry/Business
Results and Impact This one-day workshop was aimed at disseminating key research findings from this award, and from other associated research projects. The workshop brought together a range of stakeholders to discuss the findings.
Year(s) Of Engagement Activity 2023
 
Description Circular Chemistry; the enabler to help solve global challenges 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Professional Practitioners
Results and Impact Presentation on circular economy in cement and concrete sectors, highlighting research from within the ICEC-MCM, the development of calcined clays and other work from within the University of Leeds.
Year(s) Of Engagement Activity 2022
URL https://www.rsc.org/events/detail/74666/circular-chemistry
 
Description Clays and Construction 2023 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Professional Practitioners
Results and Impact Delivered an invited talk on the production of belite-ye'alimite-ferrite cements from London clay at the Clays Minerals Group Research meeting organised by the Mineralogical Society of the UK and Ireland, at University of Leeds, 18th May 2023
Year(s) Of Engagement Activity 2023
 
Description EUREKA Consortium Meetings 
Form Of Engagement Activity Participation in an activity, workshop or similar
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Industry/Business
Results and Impact Biannual open meetings that involve researchers, project partners and other participants to review progress, obtain feedback to plan next activities, and explore new opportunities.
Year(s) Of Engagement Activity 2022,2023,2024,2025
 
Description Exhibition at Imperial Lates 
Form Of Engagement Activity Participation in an open day or visit at my research institution
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Public/other audiences
Results and Impact Exhibited samples and research findings which generated interests and public awareness of the research.
Year(s) Of Engagement Activity 2025
URL https://www.imperial.ac.uk/be-inspired/lates/
 
Description Invited Lecture at Technologies for Low Carbon and Lean Construction (TLC2) launch at IIT-Madras 
Form Of Engagement Activity Participation in an activity, workshop or similar
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Postgraduate students
Results and Impact Delivered an invited lecture on circular economy and construction to ~150 Masters and PhD students, academics and industry partners at the launch of IIT-Madras' new TLC2 research centre. This 4-day event prompted significant discussion among the audience as to how best to achieve circular economy goals within different environments, i.e. comparing and contrasting work in the UK and India.
Year(s) Of Engagement Activity 2023
URL https://civil.iitm.ac.in/tlc/
 
Description Invited Talk - The 3?? International Workshop on Technologies for low carbon and lean construction at IIT Madras 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Postgraduate students
Results and Impact Yuvaraj Dhandapani was one of the invited speakers in The 3?? International Workshop on Technologies for low carbon and construction, organised by IIT Madras, Chennai, India.
Year(s) Of Engagement Activity 2024
 
Description Invited Talk - Gordon Research Conference - Advanced Materials for Sustainable Infrastructure Development 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Professional Practitioners
Results and Impact S. Bernal delivered one of the keynotes of this prestigious conference, showcasing the latests outcomes of our research linked to mechano-chemical activation of clay materials, which is a new area of research in the US, which is attracting signiticant interest.
Year(s) Of Engagement Activity 2024
URL https://www.grc.org/advanced-materials-for-sustainable-infrastructure-development-conference/2024/
 
Description Invited Talk - Gordon Research Conference - Advanced Materials for Sustainable Infrastructure Development 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Professional Practitioners
Results and Impact Yuvaraj Dhandapani presented his work on 'Challenges in characterising carbonation in hardened and end-of-life concrete: Implications on performance' during this conference. His presentation was considered one of the best of the event and sparked many comments and conversations regarding calculations of CO2 uptake in cements, particularly when using materials with calcined clays
Year(s) Of Engagement Activity 2024
URL https://www.grc.org/advanced-materials-for-sustainable-infrastructure-development-conference/2024/
 
Description Invited Talk during the Seminar "Calcined Clay UK Perspective" organized by the Institute of Concrete Technology 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Industry/Business
Results and Impact I was a speaker at the Institute of Concrete Technology (ICT) Seminar in London, where the UK perspective on calcined clays was discussed. I presented the findings of the EUREKA study, which explored the potential of locally sourced clays as sustainable cement replacements. The seminar gathered key industry partners and practitioners, fostering an engaging discussion on the opportunities and challenges of incorporating UK clays into low-carbon cement solutions. My presentation emphasized ongoing research, industry collaborations, and the scalability of this approach. The discussion that followed highlighted strong interest from industry stakeholders, further reinforcing the need for continued innovation and collaboration in this field.
Year(s) Of Engagement Activity 2024
 
Description Invited Talk/Presentation at International Workshop on Technologies for Low carbon and Lean Construction at IIT Madras 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Other audiences
Results and Impact Presentation titled "Transition towards Low Carbon Concrete - Persuading Parameters." was made in a session focusing on life cycle assessment and industrial ecology to an audience of about 250 -350 in total. The presentation was ion understanding the use of different technologies for calcination of clay and its associated environmental impacts. There were lot of questions raised by the audience on the use of the clay in production of clay and its potential to reduce the carbon footprint of cement.
Year(s) Of Engagement Activity 2024
URL https://tlc2.iitm.ac.in/tlc2-events/tlc2-week-2024/
 
Description Keynote - Symposium 'Low carbon cements' as part of the Spanish Congress of Materials 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Industry/Business
Results and Impact The keynote 'Decarbonising large infrastructure projects: the case of the HS2 in the United Kingdom' was presented in the Symposium 'Low carbon cements' as part of the Spanish Congress of Materials, Malaga, Spain, 24th-28th June, 2024. This presentation showcased the outcomes of ongoing collaborative projects between SCS Railways, ARUP and my team to realise the widespread uptake of calcined clays in the United Kingdom. This presentation was very well received by cement producers in Spain, and I received very positive comments as this is a great example of collaboration between industry and academia to deliver tangible outputs for the benefit of industry and society.
We received an invitation for submitting a feature article in the magazine 'Cemento y Hormigon', distributed among all cement and concrete producers in Spanich speaking countries, which is currently in preparation.
Year(s) Of Engagement Activity 2024
 
Description Professorial inaugural lecture 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Professional Practitioners
Results and Impact 300 people attended the lecture in person, and around a similar number of attendees online. The recording is available on YouTube which has been viewed >2k times.
Year(s) Of Engagement Activity 2024
URL https://www.youtube.com/watch?v=CFsHKf6eQbY&t=5s
 
Description Talk - 3?? International Workshop on Technologies for low carbon and lean construction 
Form Of Engagement Activity Participation in an activity, workshop or similar
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Postgraduate students
Results and Impact The talk 'Advances in characterising carbonation in low clinker and alternative cements' was presented at The 3?? International Workshop on Technologies for low carbon and lean construction, Chennai, India, 28-31 Jan 2024, where participant from different countries shared the latest research on sustainable construction materials and practices. This presentation attracted significant interest as there is ongoing debates about identifying the trade offs when using novel cementitious materials for decarbonising concrete, their CO2 uptake capacity (so they can ack as carbon sinks during service) and the ability of these novel cements to withstand the environmental service conditions, without losing their design properties.
Year(s) Of Engagement Activity 2024