Calixarenes: Metal-Organic Frameworks and Discrete Superstructures

Lead Research Organisation: University of Edinburgh
Department Name: Sch of Chemistry

Abstract

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Publications

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Coletta M (2020) With complements of the ligands: an unusual S-shaped [Mn7]2 assembly from tethered calixarenes. in Dalton transactions (Cambridge, England : 2003)

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Coletta M (2016) Investigations into cluster formation with alkyl-tethered bis-calix[4]arenes in Supramolecular Chemistry

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Coletta M (2020) A Brucite-Like Mixed-Valent Cluster Capped by [MnIIIp-tBu-calix[4]arene]- Moieties in Chemistry

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Coletta M (2017) The remarkable influence of N,O-ligands in the assembly of a bis-calix[4]arene-supported [MnMnMn] cluster. in Dalton transactions (Cambridge, England : 2003)

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Coletta M (2017) A New Family of 3d-4f Bis-Calix[4]arene-Supported Clusters. in Chemistry (Weinheim an der Bergstrasse, Germany)

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Coletta M (2020) Magneto-structural studies of an unusual [MnIIIMnIIGdIII(OR)4]4- partial cubane from 2,2'-bis-p-tBu-calix[4]arene. in Dalton transactions (Cambridge, England : 2003)

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Coletta M (2016) Bis-Calix[4]arenes: From Ligand Design to the Directed Assembly of a Metal-Organic Trigonal Antiprism. in Chemistry (Weinheim an der Bergstrasse, Germany)

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Fairbairn RE (2012) Calixarene-supported rare-earth clusters: heteroatom bridge influences cluster composition. in Chemical communications (Cambridge, England)

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Fairbairn RE (2014) Oxacalix[4]arene-supported di-, tetra- and undecanuclear copper(II) clusters. in Dalton transactions (Cambridge, England : 2003)

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Martínez-Lillo J (2014) A family of cationic oxime-based hexametallic manganese(III) single-molecule magnets. in Dalton transactions (Cambridge, England : 2003)

 
Description Synthesised a range of covalent organic nanocapsules with appropriate functionality for the controlled combination with C[4]-supported polynuclear metal cluster motifs. Synthesised a range of multi-calixarene building blocks with appropriate functionality for the controlled combination with C[4]-supported polynuclear metal cluster motifs. Utilised nanometre scale building blocks to form novel families of polymeric metal-organic frameworks and discrete metal-organic superstructures.
Exploitation Route Fundamental chemistry and physics with potential future application in materials.
Sectors Chemicals
URL http://www.chem.ed.ac.uk/staff/academic-staff/professor-euan-k-brechin