SuperSTEM: National Research Facility for Advanced Electron Microscopy
Lead Research Organisation:
University of Leeds
Department Name: Chemical and Process Engineering
Abstract
This proposal requests funding for the provision of SuperSTEM, the EPSRC National Research Facility for Advanced Electron Microscopy (AdvEM), for 5 years from 14 March 2022, together with additional capital funding for a unique, next-generation instrument with capabilities tailored for the study of quantum materials and phenomena.
Since its inception 20 years ago, and since 2011 as the EPSRC NRF for AdvEM, SuperSTEM, has become an internationally renowned user centre. It offers access to world-leading scanning transmission electron microscopy (STEM) instrumentation and expertise for the direct imaging of atomic structures and the determination of chemical composition, bonding and vibrational properties, with a focus on single-atom precision and sensitivity. The NRF enables the elucidation of structure-property relationships in materials and devices for the benefit of a community drawn from over 30 EPSRC Research Areas, both academic and industrial, in fields as diverse as catalysis, energy conversion and storage, bio-materials, organic and inorganic chemistry, mineralogy, planetary science, nuclear materials, condensed matter physics and quantum materials.
The requested funding will provide 5 more years of continued support at a guaranteed service capacity for the worldwide scientific community to access these unique microscopes and expertise not available at institutional level. It will support dedicated collaborative research and training in the interpretation and analysis of AdvEM data. While the Facility's most recent instrument currently boasts internationally leading energy resolutions, this proposal also includes a visionary plan and funding request for a next-generation instrument with transformative capabilities. In particular, the ability to observe samples at liquid helium temperatures in a magnetic-field-free sample environment, while maintaining ultra-high energy and spatial resolution would be world-unique.
This new QuantumSTEM instrument will enable the study of the electronic structure of materials across phase or state transitions, as well as the vibrational fingerprinting of soft matter (such as single molecules, biomaterials, molecular crystals, etc...), bringing to bear the benefits of monochromation on a wider range of systems where low temperature observation can help mitigate beam damage or induce novel physical phenomena. Combined with external sample stimulation by varying the magnetic field materials experience within the microscope, or subjecting them to controlled electrothermal stimuli, the spectroscopic signature of quantum phenomena, e.g. quasiparticles beyond phonons (gauge bosons, magnons), will become accessible at the atomic scale. These themes are central to the emerging field of quantum materials, an area of strategic importance for UK research investment. QuantumSTEM will expand electron microscopy into experimental territory associated with resonant inelastic X-ray scattering at a fraction of the cost and with orders of magnitude higher spatial resolution and detection efficiency.
Since its inception 20 years ago, and since 2011 as the EPSRC NRF for AdvEM, SuperSTEM, has become an internationally renowned user centre. It offers access to world-leading scanning transmission electron microscopy (STEM) instrumentation and expertise for the direct imaging of atomic structures and the determination of chemical composition, bonding and vibrational properties, with a focus on single-atom precision and sensitivity. The NRF enables the elucidation of structure-property relationships in materials and devices for the benefit of a community drawn from over 30 EPSRC Research Areas, both academic and industrial, in fields as diverse as catalysis, energy conversion and storage, bio-materials, organic and inorganic chemistry, mineralogy, planetary science, nuclear materials, condensed matter physics and quantum materials.
The requested funding will provide 5 more years of continued support at a guaranteed service capacity for the worldwide scientific community to access these unique microscopes and expertise not available at institutional level. It will support dedicated collaborative research and training in the interpretation and analysis of AdvEM data. While the Facility's most recent instrument currently boasts internationally leading energy resolutions, this proposal also includes a visionary plan and funding request for a next-generation instrument with transformative capabilities. In particular, the ability to observe samples at liquid helium temperatures in a magnetic-field-free sample environment, while maintaining ultra-high energy and spatial resolution would be world-unique.
This new QuantumSTEM instrument will enable the study of the electronic structure of materials across phase or state transitions, as well as the vibrational fingerprinting of soft matter (such as single molecules, biomaterials, molecular crystals, etc...), bringing to bear the benefits of monochromation on a wider range of systems where low temperature observation can help mitigate beam damage or induce novel physical phenomena. Combined with external sample stimulation by varying the magnetic field materials experience within the microscope, or subjecting them to controlled electrothermal stimuli, the spectroscopic signature of quantum phenomena, e.g. quasiparticles beyond phonons (gauge bosons, magnons), will become accessible at the atomic scale. These themes are central to the emerging field of quantum materials, an area of strategic importance for UK research investment. QuantumSTEM will expand electron microscopy into experimental territory associated with resonant inelastic X-ray scattering at a fraction of the cost and with orders of magnitude higher spatial resolution and detection efficiency.
Publications
Bugnet M
(2022)
Imaging the Spatial Distribution of Electronic States in Graphene Using Electron Energy-Loss Spectroscopy: Prospect of Orbital Mapping.
in Physical review letters
Cardillo-Zallo I
(2024)
Atomic-Scale Time-Resolved Imaging of Krypton Dimers, Chains and Transition to a One-Dimensional Gas.
in ACS nano
Del-Pozo-Bueno D
(2023)
Comparative of machine learning classification strategies for electron energy loss spectroscopy: Support vector machines and artificial neural networks.
in Ultramicroscopy
Ekren D
(2022)
Controlling the Thermoelectric Behavior of La-Doped SrTiO3 through Processing and Addition of Graphene Oxide.
in ACS applied materials & interfaces
Feng C
(2024)
Amorphous 1-D nanowires of calcium phosphate/pyrophosphate: A demonstration of oriented self-growth of amorphous minerals.
in Journal of colloid and interface science
Jordan JW
(2023)
Host-Guest Chemistry in Boron Nitride Nanotubes: Interactions with Polyoxometalates and Mechanism of Encapsulation.
in Journal of the American Chemical Society
Kashtiban RJ
(2023)
Picoperovskites: The Smallest Conceivable Isolated Halide Perovskite Structures Formed within Carbon Nanotubes.
in Advanced materials (Deerfield Beach, Fla.)
Lawrence RA
(2022)
Effects of Multiple Local Environments on Electron Energy Loss Spectra of Epitaxial Perovskite Interfaces.
in The journal of physical chemistry. C, Nanomaterials and interfaces
Liu X
(2023)
High Power Factor Nb-Doped TiO2 Thermoelectric Thick Films: Toward Atomic Scale Defect Engineering of Crystallographic Shear Structures.
in ACS applied materials & interfaces
Livi KJT
(2023)
Surface Site Density of Synthetic Goethites and Its Relationship to Atomic Surface Roughness and Crystal Size.
in Langmuir : the ACS journal of surfaces and colloids
Martí-Sánchez S
(2022)
Sub-nanometer mapping of strain-induced band structure variations in planar nanowire core-shell heterostructures.
in Nature communications
Michez L
(2022)
Unveiling the atomic position of C in Mn 5 Ge 3 C x thin films
in Physical Review Materials
Mitchell S
(2022)
Automated Image Analysis for Single-Atom Detection in Catalytic Materials by Transmission Electron Microscopy
in Journal of the American Chemical Society
Mosberg AB
(2023)
Focused ion beam lithography for position-controlled nanowire growth.
in Nanotechnology
Rigby O
(2022)
Structure and electronic properties of domain walls and stacking fault defects in prospective photoferroic materials bournonite and enargite
in Journal of Applied Physics
Stephen N
(2023)
Dislocation and strain mapping in metamorphic parabolic-graded InGaAs buffers on GaAs.
in Journal of materials science
Ten A
(2023)
Bimetallic copper palladium nanorods: plasmonic properties and palladium content effects.
in Nanoscale advances
Thøgersen A
(2022)
Plasmonic properties of aluminium nanowires in amorphous silicon.
in Journal of physics. Condensed matter : an Institute of Physics journal
Tippireddy S
(2022)
Local structural distortions and reduced thermal conductivity in Ge-substituted chalcopyrite
in Journal of Materials Chemistry A
Wang S
(2023)
Segregation of Yttrium at the Mg/MgO interface in an Mg-0.5Y Alloy
in Acta Materialia
Wang Y
(2022)
Manipulating Nucleation Potency of Substrates by Interfacial Segregation: An Overview
in Metals